东南沿海地震活动特征量

1970年以来,东南沿海地区经历了上世纪末以来明显的第Ⅴ活跃幕(或轮回)平静和活跃时段,本文通过分析研究这两个时段地震活动在时空强上的差异性,定量提取其活动演化过程参量,为该区未来地震活动期判定提供相对定量的参考依据。     

武山铜矿北矿带黄铁矿的成因矿物学研究

武山铜矿是长江中下游铁、金成矿带一个重要组成部分，通过对武山铜矿北矿带的成因矿物学研究，可将其划分为沉积成因系列与热液成因系列两大类，从而进一步证明武山铜矿北矿带为在正常沉积基础上，由燕山期岩浆热液叠加改造的层控矿床。     

Laboratory investigations of the role of biofilms on stream-bed surfaces in debris-flow runout

Debris-flow runout is a fascinating process to understand due to its implications for downstream alluvial fans. Based on the propagation-deposition behaviors of the Dongyuege (DYG) debris flow, in Yunnan, the effect of biofilms on channel surfaces on debris-flow runout is investigated in laboratory flumes with two different internal surfaces: surfaces are lined with granite slabs (Model I) and gravel (Model II), respectively. Our results show that biofilms can significantly reduce frictional resistance to flows. They increase flow velocities, slow down the deceleration of the snouts, prolong runout distances, and subsequently extend the areas covered with resulting deposits, thus greatly assisting the propagation of experimental debris flows. Slippery biofilms consisting mainly of diatoms and their extracellular mucus (ECM) reduce the contact friction between the flume-beds and the overlying fluids, and greatly promote the propagation of tested flows. Well-developed biofilms are found on the underwater channel surfaces of the DYG Creek. Acting as lubricating layers, they likely played a key role in the DYG debris-flow runout. Most of the debris transported during the DYG event was deposited on overbanks, and the sediment that caused the disaster was transported to the populated fan region through the stream-bed clad in the thick biofilms. Owing to their impacts on the development and width of the temporary debris dam breach, the stream-bed covered with biofilms became a direct contributor to the debris-flow hazard. Because of the ubiquitous presence of biofilms on mountain stream-bed surfaces, the development of perennial streamflows can be viewed as an indicator of gully susceptibility to debris flows threatening creek fans. The underwater areas of pre-event channel cross-sections should be regarded as slip or low-friction boundaries, and the parts above stream-levels can be viewed as no-slip boundaries. © 2019 John Wiley & Sons, Ltd.     

基于GIS的个旧花岗岩凹陷带空间信息成矿预测模型

基于GIS技术,对云南个旧花岗岩凹陷带进行数字矿床空间信息成矿预测模型的研究。在了解个旧矿田地质的基础上,通过工作区信息统计单元的划分、预测区地质信息(包括地层、构造、岩浆岩、矿化蚀变以及物、化、遥异常等)变量的确定以及编码和赋值,采用特征分析法确定空间网格单元成矿异常有利度模型,从成矿预测单元中最终圈定了找矿优选靶区。结果表明了信息统计单元结合特征分析数学方法是可行的。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

注水诱发地震的成因及影响因素探讨

根据胜利油田东营凹陷深井注水所监测到的破裂信号特征分析,结合位于同一凹陷内的角7井注水诱发地震特征,对注水诱发地震的成因进行了探讨.注水过程中地层有无先存破裂面对所诱发的地震产生较大影响,认为诱发地震的震级与注采比和注水井的构造位置密切相关.     

Paleocene deep-water sediments and radiolarian faunas: Implications for evolution of Yarlung-Zangbo foreland basin, southern Tibet

Only a few Paleocene radiolarian assemblages have been reported, while the Early Paleocene zonal schemes remain poorly delineated. The Early Paleocene on-land radiolarians were described in the Hidaka melange belt of Japan and the North Island of New Zeal…     

PPGIS在城市规划决策中的应用

在介绍PPGIS概念的基础上,给出了基于PPGIS城市规划决策系统的框架,分析了基于元数据的分布式空间数据库的数据组织方式,提出了公众参与城市规划决策系统中公众冲突的解决机制,并在传统适宜性分析模型的基础上建立了公众参与的适宜性分析模型。     

局地水汽异常引起的非绝热加热对2016/2017年中国南方暖冬的影响

基于NCEP/NCAR再分析资料, 利用气温异常的倾向方程分析2016/2017年中国华北地区(100~115 °E, 35~45 °N)、西南地区(85~102 °E, 22~33 °N)和南方地区(108~118 °E, 22~33 °N)的暖冬事件。结果表明西南和华北地区的平流作用占主导地位, 而2016/2017年冬季中国南方暖冬主要是非绝热加热引起的。进一步通过水汽收支平衡的分析表明, 局地水汽异常对2016/2017年中国南方暖冬有重要贡献, 而其中土壤的水汽贡献约占50%。可能的机制如下:大气中正的水汽异常引起辐射加热增多, 导致气温升高, 土壤的感热增大, 土壤温度升高, 潜热通量变大, 从而向大气的水汽输送增多, 更多的水汽将导致更高的温度。