添加纳米TiO2的氯醚树脂的XPS分析

在紫外线老化前后,利用光电子能谱(XPS)研究了分别添加金红石型和锐钛型纳米TiO2的氯醚树脂。研究发现,氯醚树脂中氯、氧元素具有表面富积现象——趋肤效应,而钛和碳元素在内层聚集;添加颜料粒子越小,在表面含量越大;金红石型纳米二氧化钛紫外屏蔽性好,减缓树脂老化;而锐钛型纳米二氧化钛具有显著的光催化活性,加速树脂老化。因此,金红石型纳米二氧化钛将是一种有前途的紫外线吸收剂。     

Summer distribution and geochemical composition of suspended-particulate matter in the east china sea

The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The spatial variability of SPM distribution (0.3–6.5 mg l⁻¹) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water (mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations were highly significant. Particulate CaCO₃ distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total area of 0.45 × 10⁶ km² of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate that continental sources and cross-shelf transport modulate ECS particulate matter in summer.     

星载SAR浅海水下地形和水深测量模拟仿真──水下地形高度、坡度和方向与可测水深分析

根据星载合成孔径雷达(SAR)浅海水下地形和水深成像机理,建立了浅海水下地形和水深雷达后向散射截面仿真模型.利用该模型模拟并分析了不同地形条件下,浅海水下地形的雷达后向散射截面.分析结果表明,水下地形高度越高,SAR可测量的水深越深;水下地形坡度越大,越易被SAR所观测.水下地形的星载SAR测量还与水下地形的方向有关,与卫星飞行方向平行的水下地形最易被SAR观测,与卫星飞行方向垂直的水下地形最不易被SAR观测.     

鱼类消化道细菌及其作用研究Ⅱ.鲻鱼

本文报道了从鲻鱼消化道分离的好气性异养细菌数量为（1．5×108±0．4×108～6.4×108±2.0×108）个／g，共分离220株细菌。其种群组成为弧菌、气单胞菌、不动细菌、假单胞菌、微球菌、黄杆菌、葡萄糖细菌、纤维单胞菌、节细菌和棒状杆菌。测定其生化特性，表明该类菌对有机质的分解能力比较强，这些特性有利于鱼类对营养物质的消化和吸收，并进一步促进其生长和发育。     

利用卫星遥感监测南极海冰的研究和进展

本文是根据南极“八五”国家攻关课题中的“南极海冰监测和预报”的考核目标，实现为南极考察船在 冰区中航行提供精确和清晰的冰图和预报。     

南极冰藻类囊体膜光系统研究进展

南极冰藻是南大洋碳流和能量流的重要组成部分,在该区域的生态系统中发挥着极其重要的作用.低温、低光照和高盐度对类囊体膜光系统的伤害必将影响冰藻对光能的吸收、传递和转换,从而影响冰藻的正常生长繁殖.事实上,冰藻为了能够在这寒冷骤变的环境中生存、繁衍,类囊体膜光系统在生理、代谢和遗传上进行了复杂的适应性改变,冰藻在低光照条件下保持很高的光合效率.因此研究南极冰藻类囊体膜光系统具有重要的理论意义.综述了南极冰藻类囊体膜光系统的研究进展,以期为进一步了解南极冰藻光系统作用机理提供依据.     

Determination of the Critical Value of Deflection for Embedded Cylindrical Structures

An embedded cylinder is a large-diameter cylinder embedded in a soil foundation. The state of failure of such an embedded cylindrical structure shows large deflection instead of slide and overturn of the traditional gravity type of structure placed on a rubble base or foundation base. The critical value of deflection of the embedded cylindrical structure, which is the maximum allowable deflection for stability calculation of the cylinder, is a vital control value. Through investigation on deflection and soil pressures on an embedded cylinder by model experiments, the variations of the angle of rotation θ of a cylinder with effective anti-overturning ratio η and moment MH of thrust are discussed. On the basis of experimental study, the critical value of deflection of the cylindrical structure is proposed in the paper. Meanwhile, the formulas for calculating deflection of cylinders are derived.     

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

网箱养鱼诱发有机物污染的生物监测

介绍三种通过底栖动物群落结构的变化对有机物污染监测和评价的方法,并分别对澳大利亚塔斯马尼亚州Nubeena鳟鱼养殖场内由高密度网箱养鱼诱发的有机物污染进行了检测。结果表明:距网箱垂线0m处为严重污染区域,10m处为中度污染区域,30m为过渡类型,其有机物对该处底栖生物仍具有害影响,60m处为轻度有机物富集区,但该处有机物对底栖生物的总效应是有益的,60m以外为正常区域。本文还对三种方法的适用性进行了讨论。