Study of the properties of artificial composite materials for permeable geochemical barriers

We study the filtering and sorption parameters of laboratory-produced composite materials, such as sand-gels, sand-gels with an FeS activating additive, peat-gels, and commercial sorbents on the basis of cellulose coated with MnO₂, which can be used for production of permeable geochemical barriers. The carry over and the efficiency of consumption of the active component are estimated for materials with activating additives. It is shown that all the materials under study can be used as fillers for a permeable geochemical barrier, but each of them has its own limitations.     

Petroleum-related hydrocarbons in deep and subsurface sediments from South-Western Barents Sea

Subsurface sediments from a pockmark area in South-Western Barents Sea have been earlier found to contain elevated levels of petroleum-related polycyclic aromatic hydrocarbons. This work describes a comprehensive analysis of various biomarkers, including the highly source-specific hopanes, in a 4.5?m long gravity core from the same area, together with subsurface sediment samples from other areas in the region without pockmarks present ("background samples"). A clear difference between the pockmark gravity core and the background sediment cores was found, both with regard to genesis and the level of transformation of organic matter. A number of indicator parameters, such as methylphenanthrene index (MPI-1), point towards a significantly higher maturity of hydrocarbons in the pockmark core throughout its length as compared to the other sampled locations. Higher contents of microbial hopanoids (hopenes) may indicate the former presence of petroleum. These findings confirm the hypothesis of a natural hydrocarbon source in the deeper strata present in the studied location with pockmarks.     

Freshwater stromatolites with the cone-in-cone structure from the Neogene lacustrine sediments of Vietnam

Morphological features of the columnar-stratiform stromatolites, which resemble the cone-in-cone structure, from Neogene lacustrine sediments of northern Vietnam are analyzed. Their structural-textural peculiarities and interrelations with the host terrigenous sediments of a stromatolitic buildup are discussed. It is shown that stages of the growth of columns are recorded in the succession of vertically oriented carbonate plates, which form stromatolites, and in the serrate surface protrusions of the plates at their contacts with host sediments. It is established that replacement of the columnar stromatolites by the stratiform varieties in the section can be related to variations in the intensity of terrigenous material influx to the sedimentation basin. Stratiform stromatolites were formed during relatively slow accumulation of sedimentary material. Appearance of the columnar varieties is attributed to intensification of sedimentation.     

Solar and geomagnetic activity effects on heart rate variability

Investigation into possible space weather hazards on cardiovascular system has been performed. A group of 14 healthy volunteers was examined in the spring of 2009 and 2 healthy persons performed electrocardiograph records for a period of 1 year everyday in the morning and in the evening. Results revealed that heart rate variability (HRV) parameters of the group varied strongly from the day before till 3 days after the registered weak storms during the time of investigation. Blood pressure and subjective psychophysiological complaints increased statistically significantly from 0 day till +2nd day. Heart rate (HR) of the group showed a trend for decrease. It was established that morning measurements were more sensitive to space weather variations in comparison with evening measurements. Both persons with prolonged registrations for a period of year did not reveal graded response to geomagnetic storms with different intensities. Both of them decreased HR during moderate storms, but they increased HR during major storms and on the days before and after these storms. HRV parameters varied significantly on these days.     

The concentration and composition of polyaromatic hydrocarbons in small rivers in the drainage area of the eastern Gulf of Finland

The results of examining the concentrations of 16 major polycyclic aromatic hydrocarbons are given. The examined samples were taken in the territory of Leningrad province and in the eastern Gulf of Finland in different seasons. Two seasonal natural profiles of polycyclic aromatic hydrocarbons were constructed, conventionally, for the spring and the autumn. The dominating effect on the formation of the profile of polycyclic aromatic hydrocarbons is exerted by pyrogenous pollution sources in winter and petrogenic pollution sources in summer.     

Space charge generation in the atmosphere and the density of mechanical transfer current to the ground

The correlation of mechanical transfer current from the atmosphere to the ground with the process of space charge formation as a result of conductivity current divergence near ground is under discussion in this research. Experimental data of conductivity current and mechanical transfer current acquired at three observation points for different meteorological conditions are analyzed. In particular, the peculiarities of mechanical charge transfer to ground under different stratifications of the surface layer are under discussion.     

On the dynamics and structure of Earth’s oscillations in December 2004 from seismic gravimeter observations in St. Petersburg

The paper describes phenomena of large-scale deformations, in particular, long-term deformation, observed on the planet during December 1–12, 2004, before a cycle of enhanced seismic activity. The spectrum of seismic vibrations with periods of 1 to 9 hr is calculated. A high correlation is established between the frequency distribution of significant vibrations recognizable in this spectrum and vibrations that should be excited most frequently in accordance with the statistical spectrum of the seismogravitational oscillations of the Earth.     

Interaction of particles in the near field and opposition effects in regolith-like surfaces

The explanation of the opposition effects observed in brightness and polarization in different celestial bodies and laboratory samples is still far from being complete. The shadow hiding and coherent backscattering mechanisms are mentioned most frequently in this connection. In the present work, we consider one more scattering mechanism—the interaction of particles in the near field—and its influence on the brightness and polarization of light scattered by ensembles of particles at small phase angles. First, we analyze two manifestations of this mechanism: the field inhomogeneity in the vicinity of the scatterers and the shielding of particles by each other at distances compared with their sizes. Then, we use the model regolith described as an ensemble of clusters as constituents and compare the contributions of the coherent backscattering and the near-field effect to the intensity and polarization of light when the porosity of the ensemble is varied. The modeling confirms that the phase dependences of the intensity and polarization of light scattered by complex structures in the backscattering domain is mainly caused by these two mechanisms. The coherent backscattering works more effectively in sparse media, while the near-field effect manifests itself in more compact ensembles of wavelength-sized particles. However, it is difficult to distinguish quantitatively their contributions, even in models of simple structures. A number of observations, especially of moderate- and low-albedo objects, can be explained only by invoking the near-field effect.     

Organic matter in the bottom sediments of the Ob Bay: Distribution,nature, and sources

The lateral variability of main geochemical parameters of dispersed organic matter (DOM) in the bottoms sediments of the Ob Bay was studied using materials of areal geological survey. It was found that they correspond to background compositions of estuarine-delta facies of the Western Arctic shelf, being mainly determined by the influx of river run-off and coastal abrasion. The distribution of DOM and its components is controlled by the hydrodynamic regime of the water area and grain-size composition of sediments. The molecular composition of hydrocarbon markers (n-alkanes, cyclanes, and arenes) confirms the dominant role of terrigenous humic material in the formation of DOM of the bottom sediments, while temporal stability of quantitative and qualitative geochemical characteristics indicates the stability of the Ob Bay ecosystem.     

Peculiarities of accessory zircon from the carter seamount tuffs (Sierra Leone Rise in the East Atlantic)

In volcanic tuffs, dredged during Cruise 23 of the R/V Akademik Nikolaj Strakhov, accessory zircon was found; except for the mineral-forming components, there were ∼2% of ThO₂ and 0.75% of Ce₂O₃ in zircon. During rapid uplift of magmatic masses to the ocean bottom surface, admixture elements isolated into specific minerals. As a result, destruction structures were formed in the rim parts of primary zircon crystals, and the new-formed association of zircon + thorite + cerite + thoriante + baddeleyite appeared.