Biogenic and lithogenic magnetic minerals in Atlantic and Pacific deep sea sediments and their paleomagnetic significance

The carrier of the natural magnetization of deep sea sediments was characterized by mineralogical, electron microscopic, and rock magnetic investigations. Magnetic single domain (SD) and pseudo single domain (PSD) particles which are most important for the stable remanent magnetization were separated from the magnetic »coarse fraction« and concentrated as magnetic »fine fraction«. The magnetic coarse fraction consists of lithogenic magnetite and titanomagnetite, which often contains exsolution-lamellae of ilmenite. Both minerals are partially maghematized and occur isolated in the sediment or embedded in rock particles, in regionally different concentrations. The magnetic fine fraction consists of lithogenic magnetite and titanomagnetite and biogenic magnetite (magnetofossils = fossil bacterial magnetosomes), the latter generally maghematized.A graphical method is described which allows the classification and characterization of the magnetic fine fraction by demagnetization of the anhysteretic remanent magnetization (ARM) of whole sediment samples. Three groups with different magnetic properties can be distinguished, characterized by three ARM type-curves: Type A curves are associated with sediments from abyssal plaines. They show nearly identical ARM properties and are typical for magnetofossils.Type B curves are produced by sediments from the vicinity of volcanic regions. Their shapes are variable to a certain degree and indicate two lithogenic magnetic phases.Type C curves are found for sediments from submarine ridges and regions with input of terrigenous detritus. These curves have the largest deviations among each other indicating a magnetic multi-phase assemblage including magnetofossils.

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Zusammenfassung Die Träger der Magnetisierung von Tiefseesedimenten wurden mineralogisch, elektronenmikroskopisch und gesteinsmagnetisch untersucht. Magnetische Eindomänen (SD) und Pseudo-Eindomänen (PSD) Partikel, die für eine stabile remanente Magnetisierung wichtig sind, wurden als magnetische »Feinfraktion« von der magnetischen »Grobfraktion« abgetrennt. Die magnetische Grobfraktion besteht aus lithogenem Titanomagnetit und Magnetit die teilweise maghemitisiert sind und teilweise auch Ilmenit-Entmischungslamellen aufweisen. In regional unterschiedlichen Konzentrationen liegen sie frei im Sediment oder in silikatischer Matrix eingebettet vor. Die magnetische Feinfraktion besteht sowohl aus lithogenem Titanomagnetit und Magnetit, als auch aus biogenem Magnetit (Magnetofossilien = fossile bakterielle Magnetosomen); letzterer ist größtenteils maghemitisiert.Es wird eine grafische Darstellungsmethode beschrieben, die anhand von Untersuchungen der anhysteretischen remanenten Magnetisierung (ARM) von Sedimentproben eine Charakterisierung der magnetischen Feinfraktion erlaubt. Es lassen sich dadurch drei Gruppen mit unterschiedlichen magnetischen Eigenschaften unterscheiden, die durch drei Gruppen von ARM-Kurventypen charakterisiert sind.Kurventyp A wird bei Sedimenten aus Tiefsee-Ebenen beobachtet. Die ARM-Daten sind nahezu identisch und zeigen ein Verhalten, wie es für Magnetofossilien typisch ist. Kurventyp B tritt bei Sedimenten aus dem Einzugsbereich vulkanischer Gebiete auf. Er zeigt eine größere Variation und die Form der Kurven spricht für ein System aus zwei lithogenen magnetischen Komponenten.Kurventyp C gehört zu Sedimenten aus submarinen Rücken und dem Einzugsgebiet terrigener Schüttungen. Die Kurvenverläufe sind uneinheitlich und sprechen für ein magnetisches Mehrkomponenten-System mit Beteiligung von Magnetofossilien.

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Résumé Les minéraux porteurs du magnétisme dans les sédiments de mer profonde ont été explorés par les méthodes de la minéralogie, de la microscopie électronique et du magnétisme des roches. Les particules qui correspondent à un domaine magnétique unique (SD) et pseudo-unique (PSD), significatives pour un magnétisme rénanent stable, ont été concentrées comme «fraction magnétique fine» après séparation de la «fraction magnétique grossière». Cette dernière consiste en magnétite et titanomagnétite lithogéniques, qui renferment souvent des lamelles d'exsolution d'ilménite. Ces deux minéraux sont partiellement maghémitisés; ils se présentent isolés ou inclus dans des fragments de roches, avec des concentrations régionales diverses. La fraction magnétique fine consiste en magnétite et titanomagnétite lithogéniques, ainsi qu'en magnétite biogénique (magnétofossile = magnétosome fossile bactérien), cette dernière ordinairement maghemitisée.Les auteurs présentent une méthode graphique qui permet de caractériser la fraction magnétique fine à partir de l'examen du magnétisme rémanent anhystérique (ARM) de l'échantillon de sédiment. Cette méthode permet de distinguer trois groupes de propriétés magnétiques différentes, caractérisés par trois types de courbes ARM. Les courbes de type A caractérisent les sédiments de plaines abyssales; elles montrent des propriétés ARM presque identiques et sont typiques pour les magnétofossiles. Les courbes de types B sont fournies par les sédiments voisins des régions volcaniques; leurs formes varient dans une certaine mesure et indiquent un système à deux composants magnétiques lithogéniques. Les courbes de type C correspondent aux sédiments des crêtes sous-marines et des régions à apports terrigènes; ces courbes présentent entre elles des différences plus marquées, ce qui indique un système magnétique à composants multiples, comportant des magnétofossiles.

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Magnetostratigraphy in the vicinity of the cretaceous-tertiary boundary in Limhamn,southern Sweden

Summary A magnetostratigraphic subdivision of the Danian and Upper Maastrichtian at Limhamn, souternmost Sweden, based upon 63 samples from drill cores (only up and down is known), is proposed. The boundary between the Maastrichtian and the Danian — situated in chron 29R — was determined by means of nanofossils. It is marked by a hardground surface indicating a hiatus with an estimated duration of 100 ka. The presence of chron 28R at the top of the Limhamn rock sequence and chron 30R in the Maastrichtian is indicated by single samples with reversed polarity. Net sedimentation rates have been calculated on the basis of the proposed magnetochronozones. the highest net sedimentation rate is found in the Danian part of chron 29R.     

Simulating the global transport of nitrogen oxides emissions from aircraft

With the atmosphere general circulation model ECHAM the passive transport of NO_x emitted from global subsonic air traffic and the NO_x concentration change due to these emissions are investigated. The source of NO_x is prescribed according to an aircraft emission data base. The sink of NO_x is parameterized as an exponential decay process with globally constant lifetime. Simulations in perpetual January and July modes are performed. Both the resulting mean and the standard deviation of the NO_x mass mixing ratio are analysed. In January horizontal dispersion is more pronounced and vertical mixing is smaller than in July. In both cases the resulting quasi-stationary fields of the mass mixing ratio display a pronounced zonal asymmetry. The variability accounts up to 30% of the mean field.     

Behaviour of auroras during the Spörer minimum (1450-1550)

It is shown that such data that exist on auroral activity in the period between 1450 and 1550 do not provide conclusive evidence that some authors have claimed for the existence of the so-called “Spörer minimum” in solar activity during this interval.     

Geochemistry of waters and brines from the Salinas Grandes basin,Córdoba,Argentina. I. Geomorphology and hydrochemical characteristics

This paper reports on hydrochemical features of diluted waters in the source areas and the brine end-members dominant in the playa of the Salinas Grandes Basin, Córdoba, Argentina. Special emphasis was placed on the study of the relationship between geomorphology and the resulting hydrochemical fractionation. Inflow is from springs and mountain streams which disappear before reaching the saline complex. The playa and intermittent saline lakes are mainly fed by groundwater flow and a few moderately saline and perennial springs. Conversely, ephemeral lakes are fed by atmospheric precipitation and groundwater, whereas small ponds are only fed by atmospheric precipitation. The absence of a clear linkage between geomorphological units and water types was evident in the source areas. Up to four types of water were recognized in a given geomorphological unit. From the sandflat downward towards the playa, the correspondence between geomorphological units and water types was clear, coinciding with a decreased hydrochemical heterogeneity. In this subenvironment, I have recognized two dominant types of water (SO ₄ ^2– –Cl^––HCO ₃ ^– –Na⁺ and Cl^––SO ₄ ^2– –HCO ₃ ^– –Na⁺), which can be considered the original members of the neutral brine in the playa (Cl^––SO ₄ ^2– –Na⁺ where Ca²⁺+Mg²⁺ do not surpass 5 meq per cent), and an intermediate type in the mudflat (Cl^––SO ₄ ^2– –Na⁺ where the contribution of Ca²⁺+Mg²⁺ reaches up to 15 meq per cent). It seems evident that in the zone between the source areas and the sandflat, hydrochemistry is governed by chemical weathering. In stream floodplains and in the distal alluvial plain, close to the saline complex, the increase in water types as well as the increase of HCO ₃ ^– with respect to SO ₄ ^2– , were explained by the mixture of aquifers controlled by the Salinas Grandes-Salinas de Ambargasta fracture. In the saline complex, the more concentrated end-members are the result of evaporation of the two more frequent water-types in the sandflat subenvironment, and salt dissolution of ancient evaporite deposit.     

Application of the telluric and magnetotelluric methods in selection of sites for nuclear plants

The paper deals with the application of the telluric method and of magnetotelluric soundings including experimental and model data on the localization of tectonic disturbances in connection with the selection of appropriate sites for nuclear plants.     

Studies on hydrothermal alteration by acid solutions dominated by SO4 2−: Formation of the alteration products of the Gleichenberg latitic rock (Styria,Austria)—Experimental evidence

Summary The latitic rock mined at the Gossendorf open pit in the Gleichenberg Volcanic Area of Styria, Austria, has in places been completely altered to various associations of the secondary minerals opal-C/-CT, alunite, kaolinite and montmorillonite. These associations occur in a zonal arrangement, in which the innermost part has been totally altered to opal and moreover has retained its original latitic structure. The results of experimental alteration tests on the latitic rock in open hydrological systems suggest that these secondary minerals and some of the associations observed in the field as well as their zonal distribution, may have been formed by an originally strongly acid solution rich in SO₄ ^2– which, undergoing progressive chemical variation by reaction with the rock, exhibits a chemical gradient. Some of the mineral associations, however, may not be explained by a single alteration process, but must be regarded as the result of multi-stage alteration in which alteration products from weak leaching are super-imposed on alteration products from intense leaching.

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Untersuchungen zur hydrothermalen Umwandlung unter dem Einfluß saurer SO₄ ^2–-Lösungen: Diskussion der Bildungsbedingungen der Umwandlungsprodukte der Latite von Gleichenberg, Steiermark, Österreich anhand experimenteller Umwandlungen.

Zusammenfassung Latitische Gesteine sind im Tagbau Gossendorf des Gleichenberger Vulkangebietes, Steiermark, Österreich, z. T. vollständig in verschieden zusammengesetzte Kombinationen der Mineralneubildungen Opal-C/-CT, Alunit, Kaohnit und Montmorillonit umgewandelt. Diese Kombinationen treten in einer zonaren Anordnung auf, wobei der zentrale Bereich vollständig in Opal umgewandelt ist und darüberhinaus noch das ehemalige Latitgefüge aufweist. Experimentelle Umwandlungsversuche mit dem latititschen Gestein im offenen System haben gezeigt, daß diese Neubildungen und einige der beobachteten Kombinationen sowie deren zonare Anordnung durch den Einfluß einer ursprünglich stark sauren SO₄ ^2–-Lösung entstehen können, die sich durch die Reaktion mit dem Gestein chemisch ständig ändert, d. h. einen chemischen Gradienten aufweist. Einige der auftretenden Kombinationen sind jedoch nicht durch ein Umwandlungsgeschehen zu erklären, sondern nur als Ergebnis einer mehraktigen Umwandlung, wodurch sich Umwandlungsprodukte einer starken Auslaugung und die einer schwachen Auslaugung überlagern können.

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With 9 Figures     

Archaean tonalitic gneiss of Finnish Lapland revisited: zircon ion-microprobe ages

We report single grain and grain-domain U–Pb zircon ages for the Tojottamanselkä tonalitic gneiss previously investigated by the whole-rock Rb–Sr, Pb–Pb and Sm–Nd methods, by conventional U–Pb zircon density/size fraction analysis and by Hf-isotopes (Kröner et al. 1981; Patchett et al. 1981; Jahn et al. 1984) and established as one of the oldest known rocks of the Baltic shield. Our data confirm the intrusive age as 3115±29 Ma (standard error), but we also found slightly older xenocrystic zircon cores with ²⁰⁷Pb/²⁰⁶Pb ages between 3161±19 and 3248±10 Ma that may either be derived from earlier phases of the tonalite melt or from pre-tonalite sialic crust. New magmatic zircon growth, probably during a metamorphic event that led to migmatization, is recorded by an age of 2836±30 Ma and may be coeval with widespread tonalite emplacement elsewhere in the northern Baltic shield at about this time.