The weathering and element fluxes from active volcanoes to the oceans: a Montserrat case study

The eruptions of the Soufrière Hills volcano on Montserrat (Lesser Antilles) from 1995 to present have draped parts of the island in fresh volcaniclastic deposits. Volcanic islands such as Montserrat are an important component of global weathering fluxes, due to high relief and runoff and high chemical and physical weathering rates of fresh volcaniclastic material. We examine the impact of the recent volcanism on the geochemistry of pre-existing hydrological systems and demonstrate that the initial chemical weathering yield of fresh volcanic material is higher than that from older deposits within the Lesser Antilles arc. The silicate weathering may have consumed 1.3% of the early CO₂ emissions from the Soufrière Hills volcano. In contrast, extinct volcanic edifices such as the Centre Hills in central Montserrat are a net sink for atmospheric CO₂ due to continued elevated weathering rates relative to continental silicate rock weathering. The role of an arc volcano as a source or sink for atmospheric CO₂ is therefore critically dependent on the stage it occupies in its life cycle, changing from a net source to a net sink as the eruptive activity wanes. While the onset of the eruption has had a profound effect on the groundwater around the Soufrière Hills center, the geochemistry of springs in the Centre Hills 5 km to the north appear unaffected by the recent volcanism. This has implications for the potential risk, or lack thereof, of contamination of potable water supplies for the island’s inhabitants.     

AGU新出版地球系统模拟杂志

美国地球物理联合会（AGU）很高兴地宣布,AGU不久将成为《地球系统模拟进展杂志》（Journal of Advances in Modeling Earth Systems,JAMES）新的出版机构。JAMES是一份同行评议、开放获取、全电子化的杂志,通过提供高质量的学术研究论文推动地球系统模拟科学的发展。     

Investigation of three‐dimensional wind flow behaviour over coastal dune morphology under offshore winds using computational fluid dynamics (CFD) and ultrasonic anemometry

The behaviour of offshore‐directed winds over coastal dune and beach morphology was examined using a combination of modelling (3‐D computational fluid dynamics (CFD)) and field measurement. Both model simulations and field measurements showed reversal of offshore flows at the back beach and creation of an onshore sediment transport potential. The influence of flow reversals on the beach‐dune transport system and foredune growth patterns has previously received little attention. Detailed wind flow measurements were made using an extensive array of mast‐mounted, 3‐D ultrasonic anemometers (50 Hz), arranged parallel to the dominant incident wind direction. Large eddy simulation (LES) of the offshore wind flow over the dune was conducted using the open‐source CFD tool openFOAM. The computational domain included a terrain model obtained by airborne LiDAR and detailed ground DGPS measurements. The computational grid (~22 million cells) included localized mesh refinement near the complex foredune terrain to capture finer details of the dune morphology that might affect wind flows on the adjacent beach. Measured and simulated wind flow are presented and discussed. The CFD simulations offer new insights into the flow mechanics associated with offshore winds and how the terrain steering of wind flow impacts on the geomorphological behaviour of the dune system. Simulation of 3‐D wind flows over complex terrain such as dune systems, presents a valuable new tool for geomorphological research, as it enables new insights into the relationship between the wind field and the underlying topography. The results show that offshore and obliquely offshore winds result in flow reversal and onshore directed winds at distances of up to 20 m from the embryo dune toe. The potential geomorphological significance of the findings are discussed and simple calculations show that incoming offshore and obliquely offshore winds with mean velocities over 13 m s^?1 and 7 m s^?1, respectively, have the potential to create onshore‐directed winds at the back beach with mean velocities above 3.3 m s^?1. These are above the threshold of movement for dry sand and support previous conclusions about the significance of offshore winds in dune and beach budget calculations. Copyright © 2011 John Wiley & Sons, Ltd.     

Concentration trends and water-level fluctuations at underground storage tank sites

Concentration trends of monitor wells utilized in monitored natural attenuation at petroleum underground storage tank sites can be used to predict achievement of regulatory standards if the data approximate a first-order decline trend. However, declining concentration trends often display seasonal and other fluctuations that complicate trend interpretation. Seasonal correlations between concentration and water-level elevation, including in-phase and inverse relationships, constitute one of the most common types of variation. The in-phase fluctuations are most common for monitor wells located in or near the source area of the release. This relationship may be the result of increased contact with the smear zone in the source area during periods of high water table. Conversely, inverse trends of water-level elevation and concentration are most common in downgradient wells beyond the limit of the source area. In a year long study of short-term fluctuations in BTEX and other parameters in a downgradient monitor well, the data suggest that the winter/spring recharge event significantly controls the concentration trends of BTEX as well as inorganic compounds in the well. Recharge and associated water table rise began in late fall and were soon followed by a slug of inorganic ions strongly influenced by road salt application. This slug of recharge diluted the concentrations of petroleum compounds and alkalinity (bicarbonate). Electron acceptors including oxygen, nitrate, and sulfate, which is a component of road salt, are also contributed to the water table during recharge. Oxygen and nitrate were not detected in the monitor well samples and were most likely consumed quickly in biodegradation reactions at the top of the contaminant plume. Sulfate peaked during winter/spring recharge and then slowly declined during the summer and fall, along with redox potential. Alkalinity (bicarbonate) increased during this period, which may represent the coupled oxidation of organic carbon to CO₂ with sulfate as the electron acceptor. BTEX concentrations peaked in the fall probably due to the lack of diluting recharge. The slow changes in concentration over the summer and fall months, interpreted to be caused by biodegradation, contrast with the rapid changes associated with dilution during the recharge event.     

Origin of the Lower Cambrian phosphatic bed at Vassbo, Sweden

An extensive phosphatic bed characterized by a black apatite-cemented sandstone is developed in the uppermost part of the Lower Cambrian formation over the entire Vassbo area, Sweden. The thickness of the layer is generally 0.1 m, increasing in places to 0.2 m. The lower boundary of the bed is transitional to a sandstone; the upper boundary displays a contact that is both sharp and irregular with a Middle Cambrian bituminous black shale.
The phosphatic bed was diagenetically formed by inorganic in situ precipitation of apatite in a sandstone at a depth of about 0.2 m below the sediment-water interface, where reducing conditions were developed, as a result of oxygen consumption during the degradation of organic matter. Sulphur isotope data from associated pyrite suggest that organic processes, such as bacterial sulphate reduction, were also involved in the formation of the phosphatic bed. The depositional environment of the bed was a marine shelf with a zero to very low sedimentation rate. The upper part of the apatite-cemented sandstone was partly reworked by bottom currents as demonstrated by a board containing numerous pebbles. Sedimentological as well as chemical data confirm a southern hemisphere position of the Baltic Shield in the early Cambrian in which an oceanic upwelling and high organic productivity was the probable source of the phosphorus along the palaeo-west-coast.     

Supernova 1993k — first photometric results

The 61 cm Lowell telescope at Perth Observatory has been automated by the Perth Astronomy Research Group (PARG) for the detection, confirmation and follow-up studies of supernovae and other transient events. This search program complements similar searches operating in the Northern Hemisphere, such as the Berkeley Supernova Search. The first supernova found by our search program, SN 1993k, was discovered on March 28, 1993 (IAUC 5733). The discovery has been made with the telescope in fully automated mode, including automated image analysis. We are currently imaging some 80 galaxies per night. Photometric methods for the analysis of lightcurves are at present being implemented.     

The photoabsorption coefficients of CO and CO2 in the region 350 to 650Å

The photoabsorption coefficients of CO and CO₂ have been measured to ± 3% accuracy in the 350–650 Å spectral region.     

New perspectives on Titan's upper atmosphere from a reanalysis of the Voyager 1 UVS solar occultations

We have reanalyzed the Voyager 1 UVS solar occultations by Titan to expand upon previous analyses and to resolve inconsistencies that have been noted in the scientific literature. To do so, we have developed a detailed model of the UVS detector and improved both the data reduction methods and retrieval techniques. In comparison to the values previously determined by Smith et al. (1982, J. Geophys. Res. 87, 1351-1359) we find N₂ densities that are 25-60% higher, CH₄ densities that are smaller by a factor of 3-7, and C₂H₂ densities that are roughly two orders of magnitude smaller. Our values for the thermospheric temperature are 153-158 K, which are approximately 20-40 K colder than previous estimates. We also report the first-ever determination from Voyager UVS data of density profile information for C₂H₄, HCN, and HC₃N. Finally, we present a simple engineering model that is consistent with our new results in the upper atmosphere and merges smoothly with the model of Yelle et al. (1997, in: HUYGENS Science, Payload and Mission, in: ESA SP, vol. 1177, pp. 243-256) in the lower atmosphere. Our results provide improved constraints for photochemical models and offer scientists a better understanding of Titan's upper atmosphere as we head into the Cassini era in the exploration of the saturnian system.