NH4Cl水溶液的微观结构和宏观物性研究

通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH₄Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm_-1^和3100 cm_-1^{附近出现了明显的}N-H作用峰,且随着质量分数的升高,NH₄Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH₄Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH₄₊^-Cl_-^{接触离子对开始成为主要微观作用形式。对}NH₄Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH₄Cl水溶液质量分数的增加而增大。作者推断,NH₄Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH₄₊^-Cl_-^{接触离子对},是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。     

Multiyear simulation of the African climate using a regional climate model (RegCM3) with the high resolution ERA-interim reanalysis

This study examines the ability of the latest version of the International Centre for Theoretical Physics (ICTP) regional climate model (RegCM3) to reproduce seasonal mean climatologies, annual cycle and interannual variability over the entire African continent and different climate subregions. The new European Center for Medium Range Weather Forecast (ECMWF) ERA-interim reanalysis is used to provide initial and lateral boundary conditions for the RegCM3 simulation. Seasonal mean values of zonal wind profile, temperature, precipitation and associated low level circulations are shown to be realistically simulated, although the regional model still shows some deficiencies. The West Africa monsoon flow is somewhat overestimated and the Africa Easterly Jet (AEJ) core intensity is underestimated. Despite these biases, there is a marked improvement in these simulated model variables compared to previous applications of this model over Africa. The mean annual cycle of precipitation, including single and multiple rainy seasons, is well captured over most African subregions, in some cases even improving the quality of the ERA-interim reanalysis. Similarly, the observed precipitation interannual variability is well reproduced by the regional model over most regions, mostly following, and sometimes improving, the quality of the ERA-interim reanalysis. It is assessed that the performance of this model over the entire African domain is of sufficient quality for application to the study of climate change and climate variability over the African continent.     

New water quality indices for the era of sustainable development in China

Considering the concept of cost-of-remediation (COR), water indices such as a quality index, a hazard index and a risk index are established to describe the water pollution in China. Sustainability analysis associated with water pollution is also addressed. The spatial variations of these indices in different provinces and the related reasons are considered. It is obvious that water pollution is mainly caused by the economic development, though economic development does not always bring higher risks.     

全球变化背景下北方泥炭地释放溶解有机碳的驱动机制

泥炭地（peatland）是一类储碳效率很高的特殊陆地生态系统,其碳储量约占全球土壤碳库的近1／3,对全球碳循环有着举足轻重的作用。有证据表明在过去20余年,北半球大范围的天然水体中溶解有机碳的浓度呈显著增升趋势。普遍认为与全球变化背景下北方泥炭地大规模释放溶解有机碳有关,但其驱动机制尚不十分清楚。已经提出的具有代表性...     

鄂西南岩溶地貌遗迹类型与特征分析

岩溶地貌是整个鄂西南地区综合价值最高、数量最丰富、可代表全区地质遗迹典型特色的地质遗迹类型,具有重要保护与开发利用价值。基于全省重要地质遗迹调查项目,按照地质遗迹调查标准有关要求,通过对前人成果系统收集整理并开展补充调查,筛选汇总鄂西南全区重要岩溶地貌地质遗迹25处。本文将岩溶地质遗迹分为地表类型、过渡类型、地下类型三种类型,结合典型地质遗迹点对岩溶地貌的形态特征和成因进行分析,为鄂西南地区地质旅游产业高质量发展提供依据。     

关于Mckenzie沉积盆地初始沉降公式的修正

根据Airy均衡原理对Mckenzie沉积盆地初始沉降公式进行了修正,并导出了公式的正确表达式 S=(a[(ρ_o-ρ_c)t_c/a(1-(aT_1t_c)/(2a))-(aT_1ρ_o)/2](1-1/β))/(ρ_o(1-aT_1)-ρ_w)     

双巷三维并行电法数值及物理模型试验研究

电法勘探是一种以研究地下探测目标体与周围介质之间的电性差异的地球物理探测方法,通常采用的二维电法勘探只能得到一条垂直于测线的视电阻率剖面,如果不能确定测线位置正好在异常体的正上方,这时就难给出较准确的结论。三维电阻率法采集数据量大,可获得三维电性数据体,而且可方便地根据需要实现水平及垂直切片,有着二维电法探测不能比拟的优点,实现对目标体的准确定位及全面透视。通过对构建的三维地质模型体进行数值模拟和物理模拟,表明双巷并行三维电法对地质异常体可以进行有效的探查并获得良好的探测效果。     

地统计学方法在土壤学中的应用

地统计学目前在土壤科学中得到广泛的应用和发展,成为认识土壤特征的一个重要工具.地统计学的空间变异函数和克里格插值等方法是土壤性状分析的主要手段,空间变异函数主要用于描述土壤理化性状空间变异特性,不同的插值方法可优化田间试验设计和田间采样方案,克里格插值方法则特别适用于未测量点土壤属性值的估测等.近年插值方法又被广泛应用于确定区域土壤环境容量和土壤质量标准,随机模拟则用于对土壤特性进行不确定性估计等.因而,地统计学方法对我国大量土壤学资料的整合与分析具有极大的应用前景.     

利用激光雷达资料分析兰州远郊气溶胶光学特性

利用2007年1～4月兰州大学半干旱气候与环境观测站激光雷达资料,反演了晴空无云典型日和沙尘过程大气气溶胶消光系数和光学厚度。结果表明,兰州远郊榆中地区,1km以下大气气溶胶消光系数较大,为0.01～0.1km-1;平均气溶胶光学厚度〈0.5,光学厚度日变化呈双峰型,峰值分别出现在12：00和20：00。采暖期与非采暖...