Characterization of deep saline aquifers in the Bécancour area,St. Lawrence Lowlands,Québec,Canada: implications for CO2 geological storage

The present paper provides a case study of the assessment of the potential for CO₂ storage in the deep saline aquifers of the Bécancour region in southern Québec. This assessment was based on a hydrogeological and petrophysical characterization using existing and newly acquired core and well log data from hydrocarbon exploration wells. Analyses of data obtained from different sources provide a good understanding of the reservoir hydrogeology and petrophysics. Profiles of formation pressure, temperature, density, viscosity, porosity, permeability, and net pay were established for Lower Paleozoic sedimentary aquifers. Lateral hydraulic continuity is dominant at the regional scale, whereas vertical discontinuities are apparent for most physical and chemical properties. The Covey Hill sandstone appears as the most suitable saline aquifer for CO₂ injection/storage. This unit is found at a depth of more than 1 km and has the following properties: fluid pressures exceed 14 MPa, temperature is above 35 °C, salinity is about 108,500 mg/l, matrix permeability is in the order of 3 × 10^?16 m² (0.3 mDarcy) with expected higher values of formation-scale permeability due to the presence of natural fractures, mean porosity is 6 %, net pay reaches 282 m, available pore volume per surface area is 17 m³/m², rock compressibility is 2 × 10^?9 Pa^?1 and capillary displacement pressure of brine by CO₂ is about 0.4 MPa. While the containment for CO₂ storage in the Bécancour saline aquifers can be ensured by appropriate reservoir characteristics, the injectivity of CO₂ and the storage capacity could be limiting factors due to the overall low permeability of aquifers. This characterization offers a solid basis for the subsequent development of a numerical hydrogeological model, which will be used for CO₂ injection capacity estimation, CO₂ injection scenarios and risk assessment.     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Fluvial incisions in the North‐Western Pyrenees (Aspe Valley): Dissection of a former planation surface and some tectonic implications

Dissected remnants of a high elevation low relief surface (HELRS) are encountered all along the Pyrenean range. All authors agree that the HELRS was shaped during the post‐shortening evolution of the belt, but doubt remains on its original elevation. Notably, whether a post‐shortening uplift event occurred after the generation of the Pyrenean planation surface is still debated. Based on a geomorphological study of the entrenchment of the Aspe River in the North‐Western Pyrenees, we describe a post‐Oligocene multi‐stage dissection of the HELRS linked to a regional post‐shortening uplift. Each incision stage is recorded by erosional triangular facets and associated stepped remnants of former smooth topographies. Compared analysis of patterns of incision in the Axial Zone and its northern border allows to evidence differential vertical motions. We discuss the forcing mechanism(s) that controlled this morphological evolution.     

Backward modeling of the rifting kinematics in the Upper Rhine Graben: insights from an elastic-perfect contact law on the restoration of a multi-bloc domain

This paper addresses the problem of volume restoration for 3-D sedimentary basin kinematic deformation. The primary purpose is methodological and concerns the use of contact mechanics with the finite element method, in order to deform a geological multi-bloc domain. This approach is applied to backward model the later stage of rifting of a segment of the southern Upper Rhine Graben (France–Germany border). Preliminary results from our modeling demonstrate the ability of the method not only to handle complex geometries, but also to successfully perform retro-deformation of a complex geological domain. In addition, they provide or confirm crucial information on the rifting evolution and tectonic features of this segment of the Upper Rhine Graben, such as the distribution of deformation, the asymmetry of the graben and a significant left-lateral strike-slip component of displacement.     

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.     

A brief history of the solar oblateness. A review

We hereby present a review on solar oblateness measurements. By emphasizing historical data, we illustrate how the discordance between experimental results can lead to substantial improvements in the building of new technical apparatus as well as to the emergence of new ideas to develop new theories. We stress out the need to get accurate data from space to enhance our knowledge of the solar core in order to develop more precise ephemerids and ultimately build possible new gravitational theories.     

Site effects of the Roio basin, L��Aquila

During the microzonation studies of the April 6th, 2009 L??Aquila earthquake, we observed local seismic amplifications in the Roio area??a plane separated from L??Aquila city center by mount Luco. Six portable, digital instruments were deployed across the plain from 15 April to mid-May 2009. This array recorded 152 aftershocks. We analyzed the ground motion from these events to determine relative site amplification within the plain and on surrounding ridges. Horizontal over vertical spectral ratio on noise data (HVSRN), aftershock recordings (HVEQ) and standard spectral ratio (SSR) showed amplifications at 1.3 and 4.0?Hz on quaternary deposits. Seismic amplifications in the frequency range of 4 and 6?Hz were also observed on a carbonate ridge of Colle di Roio, on the northwestern border of the plateau. A small amplification was noticed near the top of mount Luco, another rocky site. Large discrepancies in the amplification levels between methods have been observed for these sites, but the HVSRN, HVEQ and SSR gave similar results at the stations located in the Roio plain. On the rocky sites, the SSR was more reliable than the HVSRN at estimating the transfer function of the site, even if the resonance frequency seemed to be well detected by the latter method.     

Influence of compound bedforms on hydraulic roughness in a tidal environment

The effect exerted by the seabed morphology on the flow is commonly expressed by the hydraulic roughness, a fundamental parameter in the understanding and simulation of hydro- and sediment dynamics in coastal areas. This study quantifies the hydraulic roughness of large compound bedforms throughout a tidal cycle and investigates its relationship to averaged bedform dimensions. Consecutive measurements with an acoustic Doppler current profiler and a multibeam echosounder were carried out in the Jade tidal channel (North Sea, Germany) along large compound bedforms comprising ebb-oriented primary bedforms with superimposed smaller secondary bedforms. Spatially averaged velocity profiles produced log-linear relationships which were used to calculate roughness lengths. During the flood phase, the velocity profiles were best described by a single log-linear fit related to the roughness created by the secondary bedforms. During the ebb phase, the velocity profiles were segmented, showing the existence of at least two boundary layers: a lower one scaling with the superimposed secondary bedforms and an upper one scaling with the ebb-oriented primary bedforms. The drag induced by the primary bedform during the ebb phase is suggested to be related to flow expansion, separation, and recirculation on the downstream side of the bedform. Three existing formulas were tested to predict roughness lengths from the local bedform dimensions. All three predicted the right order of magnitude for the average roughness length but failed to predict its variation over the tidal cycle.     

Active channel width as a proxy of sediment supply from mining sites in New Caledonia

Although the channel morphology of upland fluvial systems is known to be strongly controlled by sediment supply from hillslopes, it is still difficult to isolate this effect from the other controlling factors of channel forms, such as the sediment transport capacity (depending notably on the size of the catchment) and local conditions (e.g. confinement, riparian vegetation, valley-floor slope). The rivers in New Caledonia offer an interesting field laboratory to isolate the morphological effect of contrasted sediment supply conditions. Some of these rivers are known to be highly impacted by the coarse sediment waves induced by the mining of nickel deposits that started in the early 1870s, which was particularly intensive between the 1940s and 1970s. The propagation of the sediment pulses from the mining sites can be traced by the presence of wide and aggraded active channels along the stream network of nickel-rich peridotite massifs. A first set of 63 undisturbed catchments in peridotite massifs distributed across the Grande Terre was used to fit a classic scaling law between active channel width and drainage area. A second set of 86 impacted sites, where the presence of sediment waves was clearly attested by recent aerial imagery, showed systematically wider active channels, with a width ratio around 5 (established from the intercept ratio of width–area power laws). More importantly, this second set of disturbed sites confirmed that the residual of active channel widths, computed from the scaling law of undisturbed sites, is statistically positively related to the catchment-scale relative area of major mining sediment sources. It is therefore confirmed that the characterization of sediment supply conditions is crucial for the understanding of spatial patterns of active channel width, and this should be more thoroughly considered in morphological studies of rivers draining environments with contrasted geomorphic activities on hillslopes. © 2018 John Wiley & Sons, Ltd.