The La Unión Au ± Cu prospect,Camagüey District,Cuba: fluid inclusion and stable isotope evidence for ore-forming processes

The Camagüey district, Cuba, is known for its epithermal precious metal deposits in a Cretaceous volcanic arc setting. Recently, the La Unión prospect was discovered in the southern part of the district, containing gold and minor copper mineralization interpreted as porphyry type. Mineralization is hosted in a 73.0 ± 1.5 Ma calc–alkaline I-type oxidized porphyry quartz diorite intrusive within volcanic and volcaniclastic rocks of the early Cretaceous Guáimaro Formation. The porphyry is affected by propylitic alteration and crosscut by a network of quartz and carbonate veinlets and veins. Chlorite, epidote, sericite, quartz, and pyrite are the main minerals in the early veins which are cut by late carbonate and zeolite veins. Late barite pseudomorphously replaces pyrite. Gold is associated with pyrite as disseminations in the altered quartz diorite and in the veins, occurring as inclusions or filling fractures in pyrite with 4 g/t Au in bulk samples, and up to 900 ppm Au in in pyrite. Fluid inclusion and oxygen isotope data are consistent with a H₂O–NaCl–(KCl) mineralizing fluid, derived from the quartz diorite magma, and trapped at least at 425°C and 1.2 kbar. This primary fluid unmixed into two fluid phases, a hypersaline aqueous fluid and a low-salinity vapor-rich fluid. Boiling during cooling may have played an important role in metal precipitation. Pyrite δ³⁴S values for the La Unión prospect range between 0.71‰ and 1.31‰, consistent with a homogeneous magmatic sulfur source. The fluids in equilibrium with the mineralized rocks have estimated δ¹⁸O values from 8‰ to 11.8‰, calculated for a temperature range of 480–505°C. The tectonic environment of the La Unión prospect, its high gold and low copper contents, the physical–chemical characteristics of the mineralizing fluids and the isotopic signature of the alteration minerals and fluids indicate that the La Unión gold mineralization is similar to the porphyry gold type, even though the ore-related epidote–chlorite alteration can be classified as propylitic and not the classic potassic and/or phyllic alteration. The low copper contents in the prospect could be due to a mineralizing fluid previously saturated in copper, which is indicated by trapped chalcopyrite crystals in high-temperature fluid inclusions. The low-temperature paragenesis, represented by carbonate, zeolite and barite, indicates epithermal overprint. The study shows the potential for other gold porphyry-type deposits in the Cretaceous volcanoplutonic arc of Cuba.     

Cenozoic granitoids in the Dinarides of southern Serbia: age of intrusion,isotope geochemistry,exhumation history and significance for the geodynamic evolution of the Balkan Peninsula

Two age groups were determined for the Cenozoic granitoids in the Dinarides of southern Serbia by high-precision single grain U–Pb dating of thermally annealed and chemically abraded zircons: (1) Oligocene ages (Kopaonik, Drenje, Željin) ranging from 31.7 to 30.6 Ma (2) Miocene ages (Golija and Polumir) at 20.58–20.17 and 18.06–17.74 Ma, respectively. Apatite fission-track central ages, modelling combined with zircon central ages and additionally, local structural observations constrain the subsequent exhumation history of the magmatic rocks. They indicate rapid cooling from above 300°C to ca. 80°C between 16 and 10 Ma for both age groups, induced by extensional exhumation of the plutons located in the footwall of core complexes. Hence, Miocene magmatism and core-complex formation not only affected the Pannonian basin but also a part of the mountainous areas of the internal Dinarides. Based on an extensive set of existing age data combined with our own analyses, we propose a geodynamical model for the Balkan Peninsula: The Late Eocene to Oligocene magmatism, which affects the Adria-derived lower plate units of the internal Dinarides, was caused by delamination of the Adriatic mantle from the overlying crust, associated with post-collisional convergence that propagated outward into the external Dinarides. Miocene magmatism, on the other hand, is associated with core-complex formation along the southern margin of the Pannonian basin, probably associated with the W-directed subduction of the European lithosphere beneath the Carpathians and interfering with ongoing Dinaridic–Hellenic back-arc extension.     

Graphical design of world map projections

The design of new map projections has up until now required mathematical and cartographic expertise that has limited this activity to a small group of specialists. This article introduces the background mathematics for a software-based method that enables cartographers to easily design new small-scale world map projections. The software is usable even by those without mathematical expertise. A new projection is designed interactively in an iterative process that allows the designer to graphically and numerically assess the graticule, the representation of the continents, and the distortion properties of the new projection. The method has been implemented in Flex Projector, a free and open-source application enabling users to quickly create new map projections and modify existing projections. We also introduce new tools that help evaluate the distortion properties of projections, namely a configurable acceptance index to assess areal and angular distortion, a derived acceptance visualization, and interactive profiles through the distortion space of a projection. To illustrate the proposed method, a new projection, the Cropped Ginzburg VIII projection, is presented.     

Kristiansenite, a new calcium–scandium–tin sorosilicate from granite pegmatite in Tørdal, Telemark, Norway

Summary Kristiansenite occurs as a late hydrothermal mineral in vugs in an amazonite pegmatite at Heftetjern, T?rdal, Telemark, Norway. Tapering crystals, rarely up to 2 mm long, are colourless, white, or slightly yellowish. The mineral has the ideal composition Ca₂ScSn(Si₂O₇)(Si₂O₆OH) and is triclinic C1 with cell parameters a = 10.028(1), b = 8.408(1), c = 13.339(2) ?, α = 90.01(1), β = 109.10(1), γ = 90.00(1)°, V = 1062.7(3) ?³ (Z = 4). It has a monoclinic cell within ∼ 0.1 ? and is polysynthetically twinned on {010} by metric merohedry. The strongest reflections in the X-ray powder pattern are [d in ?, (I _obs), (hkl)]: 5.18 (53) (1–11), 3.146 (100) (004), 3.089 (63) (−222), 2.901 (19) (221), 2.595 (34) (222), 2.142 (17) (−3–31). The Mohs’ hardness is 5?–6; D_calc. = 3.64 g/cm³; only a mean refractive index of 1.74 could be measured. Scandium enrichment in the Heftetjern pegmatite and the crystal chemistry of scandium are briefly discussed. Received April 30, 2001; accepted July 28, 2001     

A porous media finite element approach for soil instability including the second-order work criterion

This paper deals with the hydromechanical modelling of the initiation of failure in soils with particular reference to landslides. To this end, localized and diffused failure modes are simulated with a finite element model for coupled elasto-plastic variably saturated porous geomaterials, in which the material point instability is detected with the second-order work criterion based on Hill’s sufficient condition of stability. Three different expressions of the criterion are presented, in which the second-order work is expressed in terms of generalized effective stress, of total stress and thirdly by taking into account the hydraulic energy contribution for partially saturated materials. The above-mentioned computational framework has been applied to study two initial boundary value problems: shear failure of a plane strain compression test of globally undrained water-saturated dense sand (where cavitation occurs at strain localization) and isochoric grain matter, and the onset of a flowslide from southern Italy due to rainfall (Sarno-Quindici events, May 5–6 1998). It is shown that the second-order work criterion applied at the material point level detects the local material instability and gives a good spatial indication of the extent of the potentially unstable domains in both the localized and diffused failure mechanisms of the cases analyzed, is able to capture the instability induced by cavitation of the liquid water and gives results according to the time evolution of plastic strains and displacement rate.     

Climate change mitigation strategies for agriculture: an analysis of nationally determined contributions,biennial reports and biennial update reports

The role of agriculture in the context of climate change is a complex issue. On the one hand, concerns about food security highlight the need to prioritize adaptation; on the other hand, the target of the Paris Agreement (keeping global temperature rise well below 2°C) cannot be achieved without a significant decrease in agricultural emissions. Various analyses of nationally determined contributions (NDCs) submitted under the Paris Agreement show how countries intend to prioritize the needs for adaptation and mitigation in the agricultural sector. This paper focuses on 46 countries that contribute 90% of global agricultural emissions and asks how they are addressing the agricultural sector in their climate mitigation policies. It takes into account that conditions and circumstances in countries vary significantly but might also indicate similar patterns. The analysis is based on information provided by countries in their NDCs, as well as their Biennial Reports (BRs) or Biennial Update Reports (BURs) under the UN Framework Convention on Climate Change (UNFCCC). It further includes data on national agricultural emissions. By applying a mixed methods approach, which combines qualitative content analysis and comparative cluster analysis, we find that countries vary in their progress on agriculture and climate mitigation for many different reasons. These reasons include the national perception of the problem, divergent starting points for climate policy, particularities of the agricultural sector and, correspondingly, the availability of cost-effective mitigation technologies.

Key policy insights

• While for many countries the NDCs signify the beginning of their climate policy, UNFCCC biennial reports can be used to learn more about the policies that countries have already implemented.

• Mitigation action in the agricultural sector is emphasized most prominently in cases where co-benefits are possible and production is not impacted negatively.

• Policies and measures in the agricultural sector often do not align with the UNFCCC system of monitoring, reporting and verification (MRV). In addition to improving MRV-systems, it seems equally important to exchange national experiences with implemented measures and policies.

• The Koronivia Joint Work on Agriculture could take into account the problem of different definitions of sector boundaries and thus the importance of different mitigation measures.

     

SPIRE point source photometry: within the Herschel interactive processing environment (HIPE)

The different algorithms appropriate for point source photometry on data from the SPIRE instrument on-board the Herschel Space Observatory, within the Herschel Interactive Processing Environment (HIPE) are compared. Point source photometry of a large ensemble of standard calibration stars and dark sky observations is carried out using the 4 major methods within HIPE: SUSSEXtractor, DAOphot, the SPIRE Timeline Fitter and simple Aperture Photometry. Colour corrections and effective beam areas as a function of the assumed source spectral index are also included to produce a large number of photometric measurements per individual target, in each of the 3 SPIRE bands (250, 350, 500μm), to examine both the accuracy and repeatability of each of the 4 algorithms. It is concluded that for flux densities down to the level of 30mJy that the SPIRE Timeline Fitter is the method of choice. However, at least in the 250 and 350μm bands, all 4 methods provide photometric repeatability better than a few percent down to at approximately 100mJy. The DAOphot method appears in many cases to have a systematic offset of ～8 % in all SPIRE bands which may be indicative of a sub-optimal aperture correction. In general, aperture photometry is the least reliable method, i.e. largest scatter between observations, especially in the longest wavelength band. At the faintest fluxes, <30mJy, SUSSEXtractor or DAOphot provide a better alternative to the Timeline Fitter.     

Herschel SPIRE fourier transform spectrometer: calibration of its bright-source mode

The Fourier Transform Spectrometer (FTS) of the Spectral and Photometric Imaging REceiver (SPIRE) on board the ESA Herschel Space Observatory has two detector setting modes: (a) a nominal mode, which is optimized for observing moderately bright to faint astronomical targets, and (b) a bright-source mode recommended for sources significantly brighter than 500 Jy, within the SPIRE FTS bandwidth of 446.7–1544 GHz (or 194–671 microns in wavelength), which employs a reduced detector responsivity and out-of-phase analog signal amplifier/demodulator. We address in detail the calibration issues unique to the bright-source mode, describe the integration of the bright-mode data processing into the existing pipeline for the nominal mode, and show that the flux calibration accuracy of the bright-source mode is generally within 2 % of that of the nominal mode, and that the bright-source mode is 3 to 4 times less sensitive than the nominal mode.