In situ LA-ICPMS Isotopic and Geochronological Studies on Carbonatites and Phoscorites from the Guli Massif,Maymecha-Kotuy,Polar Siberia

In this study we present a fresh isotopic data, as well as U–Pb ages from different REE-minerals in carbonatites and phoscorites of Guli massif using in situ LA-ICPMS technique. The analyses were conducted on apatites and perovskites from calcio-carbonatite and phoscorite units, as well as on pyrochlores and baddeleyites from the carbonatites. The ⁸⁷Sr/⁸⁶Sr ratios obtained from apatites and perovskites from the phoscorites are 0.70308–0.70314 and 0.70306–0.70313, respectively; and 0.70310–0.70325 and 0.70314–0.70327, for the pyrochlores and apatites from the carbonatites, respectively.Furthermore, the in situ laser ablation analyses of apatites and perovskites from the phoscorite yield εNd from 3.6 (±1) to 5.1 (±0.5) and from 3.8 (±0.5) to 4.9 (±0.5), respectively; εNd of apatites, perovskites and pyrochlores from carbonatite ranges from 3.2 (±0.7) to 4.9 (±0.9), 3.9 (±0.6) to 4.5 (±0.8) and 3.2 (±0.4) to 4.4 (±0.8), respectively. Laser ablation analyses of baddeleyites yielded an eHf(t)d of +8.5 (± 0.18); prior to this study Hf isotopic characteristic of Guli massif was not known. Our new in situ εNd, ⁸⁷Sr/⁸⁶Sr and eHf data on minerals in the Guli carbonatites imply a depleted source with a long time integrated high Lu/Hf, Sm/Nd, Sr/Rb ratios.In situ U–Pb age determination was performed on perovskites from the carbonatites and phoscorites and also on pyrochlores and baddeleyites from carbonatites. The co-existing pyrochlores, perovskites and baddeleyites in carbonatites yielded ages of 252.3 ± 1.9, 252.5 ± 1.5 and 250.8 ± 1.4 Ma, respectively. The perovskites from the phoscorites yielded an age of 253.8 ± 1.9 Ma. The obtained age for Guli carbonatites and phoscorites lies within the range of ages previously reported for the Siberian Flood Basalts and suggest essentially synchronous emplacement with the Permian-Triassic boundary.     

Wind-Driven Dissolved Organic Matter Dynamics in a Chesapeake Bay Tidal Marsh-Estuary System

Controls on organic matter cycling across the tidal wetland-estuary interface have proved elusive, but high-resolution observations coupled with process-based modeling can be a powerful methodology to address shortcomings in either methodology alone. In this study, detailed observations and three-dimensional hydrodynamic modeling are used to examine biogeochemical exchanges in the marsh-estuary system of the Rhode River, MD, USA. Analysis of observations near the marsh in 2015 reveals a strong relationship between marsh creek salinity and dissolved organic matter fluorescence (fDOM), with wind velocity indirectly driving large amplitude variation of both salinity and fDOM at certain times of the year. Three-dimensional model results from the Finite Volume Community Ocean Model implemented for the wetland system with a new marsh grass drag module are consistent with observations, simulating sub-tidal variability of marsh creek salinity. The model results exhibit an interaction between wind-driven variation in surface elevation and flow velocity at the marsh creek, with northerly winds driving increased freshwater signal and discharge out of the modeled wetland during precipitation events. Wind setup of a water surface elevation gradient axially along the estuary drives the modeled local sub-tidal flow and thus salinity variability. On sub-tidal time scales (>36 h, <1 week), wind is important in mediating dissolved organic matter releases from the Kirkpatrick Marsh into the Rhode River.     

Assessment of water inrush risk using the principal component logistic regression model in the Pandao coal mine,China

In order to improve the accuracy of floor water inrush assessment, the risk prediction model of floor water inrush was established by combining the principal component logistic regression analysis (PCLRA) and GIS spatial geographic analysis. In this paper, the geological data of Pandao coal mine was taken as the engineering background. First of all, main controlling factors of floor water inrush were determined and quantified. Next, PCLRA was used to determine the weight of each factor and establish the mathematical model for predicting the floor water inrush. And then, GIS’s spatial analysis and data processing function was used to draw related single factor thematic maps. Related thematic maps were weighted superposed to draw a floor water inrush zoning map based on PCLRA mathematical model. The study areas were divided into five levels by Jenks optimization method and vulnerability index initial model. And the corresponding threshold range was determined. The results show that (1) the high sensitivity factors in floor failure depth were added to evaluate the water inrush, and the fault fractal dimension was used to replace the fault structure related factors, and the main controlling factors of floor water inrush are more comprehensive; (2) the fitting degree of PCLRA model is high and the test accuracy is 83.3%; (3) the prediction results were well fitted to the actual position of water inrush (three water inrush points are located in the dangerous area, and two water inrush points are located in the relatively dangerous area).     

Carbonate formation mechanism in paleosol sediments of the Bohai Sea coastal zone,China

The Bohai Sea coastal zone of China consists of the Pacific Ocean to the east and Eurasia to the west; hence, this region is influenced by both the ocean and continental landmasses. The carbonate formation mechanism of eolian sediment within this area is poorly understood. The loess-paleosol sediments of the Miaodao stratigraphical section (MDS) contain a record of carbonate changes in this region during the last interglacial period. New insights into regional carbonate formation mechanisms since the last interglacial period were obtained by analyzing the ages of various sedimentary facies in combination with proxy paleoclimatic indices (including average grain size, standard deviation, CaCO₃ content, and clay minerals), as well as via foraminiferal analysis. The results led to three principal findings: (1) The carbonate content change in the MDS was neither controlled by grain size nor affected by minerals. The carbonate change controlled by precipitate leaching in the Loess Plateau region cannot explain the eolian sediments within the Bohai Sea coastal zone. (2) Various subsections contain obvious carbonate content changes caused by foraminiferal deposits atop the eolian sediments, which were deposited by storm surges during a high sea-level period. This increased the carbonate content in the eolian sediments and restricted the carbonate content in the Bohai Sea coastal zone. (3) Newly detected foraminifera of the last interglacial period on the eolian sediment of the MDS were the main source of carbonate content, providing a new understanding of the carbonate formation mechanism in eolian sediments different from that of the Loess Plateau.     

Ranking of productivity improvement strategies in Iran mineral sector based on integrated SWOT-FAHP-FTOPSIS analysis

The Iran’s mineral sector, as a major supplier of mineral industries, plays a central role on Iran economy. Promoting the productivity in this area leads to the enhancement of the business environment. Also, it can influence the production chain and minerals value added. In this study, a comprehensive study was conducted on the major barriers/drivers factors affecting the efficiency in the mining sector. Furthermore, 16 key factors were identified using the expert views. These parameters are divided into four main categories: strengths, weaknesses, opportunities, and threats. In addition, a hierarchy model was designed in which the mentioned four efficient strategic parameters were implemented and the SWOT analysis was applied, as well as the nine macro strategies were determined. In order to prioritize these strategies, multiple steps were carried out. First, the subfactors were weighted by implementing the fuzzy multi attribute decision-making technique by combining the experts’ views and triangular fuzzy numbers. Subsequently, the strategies were prioritized by employing the group Fuzzy Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) model. The sensitive analysis of the results presents some minor changes in score of the alternatives, but no alteration was affected in the prioritized strategies. The results revealed the importance of resource allocation strategies related to the existing investments as well as supporting and facilitating the new technology in the mining sector.     

Sealing efficiency analysis for shallow-layer caprocks in CO<Subscript>2</Subscript> geological storage

The CO₂ migrated from deeper to shallower layers may change its phase state from supercritical state to gaseous state (called phase transition). This phase transition makes both viscosity and density of CO₂ experience a sharp variation, which may induce the CO₂ further penetration into shallow layers. This is a critical and dangerous situation for the security of CO₂ geological storage. However, the assessment of caprock sealing efficiency with a fully coupled multi-physical model is still missing on this phase transition effect. This study extends our previous fully coupled multi-physical model to include this phase transition effect. The dramatic changes of CO₂ viscosity and density are incorporated into the model. The impacts of temperature and pressure on caprock sealing efficiency (expressed by CO₂ penetration depth) are then numerically investigated for a caprock layer at the depth of 800 m. The changes of CO₂ physical properties with gas partial pressure and formation temperature in the phase transition zone are explored. It is observed that phase transition revises the linear relationship of CO₂ penetration depth and time square root as well as penetration depth. The real physical properties of CO₂ in the phase transition zone are critical to the safety of CO₂ sequestration. Pressure and temperature have different impact mechanisms on the security of CO₂ geological storage.     

Chromium spinels in North Chinese kimberlites,Huabei platform

Samples from diamondiferous pipes in the Mengyin and Fuxian regions were investigated. The chemical compositions of Cr spinels in kimberlites of China were found to be similar to those in kimberlites of the Arkhangelsk province in Russia. A long and complex evolution that was individual for each pipe was demonstrated. The kimberlites of the Shandong Province proved to be rich in high-Cr chromites. This means that the kimberlites formed at large depths in the field of diamond thermodynamic stability. Variations in the redox conditions were noted. They manifested themselves as a wide range of fluctuations of the chemical composition of microcrystalline spinels, up to formation to Ti-magnetite and magnetite.     

Volume estimation and stage division of the Mahu landslide in Sichuan Province,China

The Mahu lake, the third deepest lake in China, is located on the west bank of the Jinsha River in Leibo county, Sichuan Province. It is a dammed lake created by an old landslide on the ancient Huanglang river, a tributary on the west bank of the Jinsha River. Previous studies (Wang and Lu in J Mt Res S1:44–47, 2000) suggested that this landslide was caused by an earthquake approximately 372 ka (Middle Pleistocene), during which a few hundreds of million cubic meters of debris were deposited between 1177 and 900 m a.s.l. (above sea level), covering an area of around 15 km². Our further investigations, including geodetic survey, borehole drilling, and field reconnaissance, combining with five chronological data, have made some new discoveries at this site. First, the toe of the landslide extends from 900 m a.s.l. down to 320 m a.s.l., i.e., the local bed elevation of the contemporary Jinsha River. Second, the area of the landslide deposits is 17.3 km² with a volume of 2.38 km³, much larger than the previous estimation. Thus, it should be one of the largest known landslides in China. And the lower elevation of the landslide’s toe also rules out the possibility that it is a hanging valley on the ancient Huanglang river. Our work suggests that this landslide was created by five events according to the overlapping characteristics of the deposits and five chronological data, which are old than 52,600 years, old than 16,000 years, old than 15,500 years, 5800 years, and old than 4200 years, respectively.     

Deformation mechanism of strain localization in 2D numerical interface tests

Heterogeneity arises in soil subjected to interface shearing, with the strain gradually localizing into a band area. How the strain localization accumulates and develops to form the structure is crucial in explaining some significant constitutive behaviors of the soil–structural interface during shearing, for example, stress hardening, softening, and shear-dilatancy. Using DEM simulation, interface shear tests with a periodic boundary condition are performed to investigate the strain localization process in densely and loosely packed granular soils. Based on the velocity field given by grains’ translational and rotational velocities, several kinematic quantities are analyzed during the loading history to demonstrate the evolution of strain localization. Results suggest that tiny concentrations in the shear deformation have already been observed in the very early stage of the shear test. The degree of the strain localization, quantified by a proposed new indicator, α, steadily ascends during the stress-hardening regime, dramatically jumps prior to the stress peak, and stabilizes at the stress steady state. Loose specimen does not develop a steady pattern at the large strain, as the deformation pattern transforms between localized and diffused failure modes. During the stress steady state of both specimens, remarkable correlations are observed between α and the shear stress, as well as between α and the volumetric strain rate.     

Holocene tectono-geomorphic evolution of Haryana plains,Western Ganga plain,India

Haryana plain is the drainage divide between the Ganga plain in the east and the Indus plain in the west. Being a part of the Himalayan foreland, its geomorphology, sedimentation processes, and tectonism are broadly controlled by the Himalayan tectonics. Soil and geomorphological mapping in Haryana plain bring out geomorphic features such as paleochannels, various active drainage patterns, and landforms such as old fluvial plains, floodplains, piedmonts, pediments, terminal fans, and eolian plains. Based on the degree of soil development, and Optical stimulated luminescence (OSL) ages, the soil-geomorphic units were grouped into six members (QIMS-I to VI) (Quaternary Indus Morphostratigraphic Sequence) of a morphostratigraphic sequence: QIMS-VI 9.86–5.38 Ka, QIMS-V 5.38–4.45 Ka, QIMS-IV 4.45–3.60 Ka, QIMS-III 3.60–2.91 Ka, QIMS-II <?2.91–1.52 Ka, and QIMS-I <?1.52 Ka. OSL chronology of different geomorphic features suggests six episodes of tectono-geomorphic evolution in the region since 10 Ka. Neotectonic features such as nine faults, two lineaments, and five fault-bounded tectonic blocks have been identified. Independent tilting and sagging of the blocks in response to neotectonics have resulted in modification of landforms, depositional processes, and hydro-geomorphology of the region. Major rivers like the Yamuna, the Ghaggar, and the Sutlej show different episodes of shifting of their courses. Lineament controlled few extinct channels have been recorded between 20 and 25 m depth below the surface in the ground-penetrating radar (GPR) profiles. These buried channels are aligned along the paleo-course of the Lost Saraswati River interpreted from the existing literature and hence are considered as the course of the lost river. Seven terminal fans have been formed on the downthrown blocks of the associated faults. The Markanda Terminal Fan, the first of such features described, is indeed a splay terminal fan and was formed by a splay distributary system of the Markanda River. Association of three terminal fans of different ages with the Karnal fault indicates the segment-wise development of the fault from west to east. Also, comparison with other such studies in the Ganga plain to further east suggests that the terminal fans formed by streams with distributary drainage pattern occur only in semiarid regions as in the present area and thus are indicators of semiarid climate/paleoclimate. Though the whole region is tectonically active, the region between the Rohtak fault and Hisar fault is most active at present signified by the concentration of earthquake epicenters.