Mollusc and brachiopod skeletal hard parts: Intricate archives of their marine environment

The biogenic carbonate hard parts of fossil bivalves, cephalopods and brachiopods are among the most widely exploited marine archives of Phanerozoic environmental and climate dynamics research. The advent of novel analytical tools has led many workers to explore non‐traditional geochemical and petrographic proxies, and work performed in neighbouring disciplines sheds light on the complex biomineralization strategies applied by these organisms. These considerations form a strong motivation to review the potential and problems related to the compilation and interpretation of proxy data from bivalve, cephalopod and brachiopod hard parts from the viewpoint of the sedimentologist and palaeoceanographer. Specific focus is on the complex biomineralization pathways of a given dissolved ion or food particle from its aquatic environment via the digestion and biomineralization apparatus in molluscs and brachiopods and its incorporation into a biomineral. Given that molluscs and brachiopods do not secrete their hard parts from seawater but rather from their mantle and periostracum, this paper evaluates differences and similarities of seawater versus that of body fluids. Cephalopods, bivalves and brachiopods exert a strong biological control on biomineralization that, to some degree, may buffer their shell geochemistry against secular changes in seawater chemistry. Disordered (amorphous) calcium carbonate precursor phases, later transformed to crystalline biominerals, may be significant in carbonate archive research due to expected geochemical offset relative to the direct precipitation of stable phases. A reasonable level of understanding of the related mechanisms is thus crucial for those who use these skeletal hard parts as archives of the palaeo‐environment. The impact of what is commonly referred to as ‘biological factors’ on the geochemistry of mollusc and brachiopod hard parts is explored for conventional isotope systems such as carbon, oxygen, strontium and traditionally used element to calcium ratios. In particular, the often used δ¹³C_carb or the Mg/Ca and Sr/Ca elemental proxies are fraught with problems. An interesting new research field represents the analysis, calibration and application of non‐traditional proxies to mollusc and brachiopod hard parts. Examples include the carbonate clumped isotope (Δ₄₇) approach and the analysis of the isotopes of Ca, Mg, N, Li, S or element to Ca ratios such as Li/Ca or B/Ca and rare earth elements. Based on considerations discussed here, a series of “do's and don'ts” in mollusc and brachiopod archive research are proposed and suggestions for future work are presented. In essence, the suggestions proposed here include experimental work (also field experiments) making use of recent archive organisms or, where possible, a reasonable recent analogue in the case of extinct groups. Moreover, the detailed understanding of the architecture of mollusc and brachiopod hard parts and their ultra‐structures must guide sampling strategies for geochemical analyses. Where feasible, a detailed understanding of the diagenetic pathways and the application of multi‐proxy and multi‐archive approaches should form the foundation of fossil carbonate archive research. The uncritical compilation of large data sets from various carbonate‐shelled organisms collected at different locations is not encouraged.     

Analyzing the spatial interactions between rainfall levels and flooding prediction in São Paulo

Rainfall is one of the primary triggers for many geological and hydrological natural disasters. While the geological events are related to mass movements in land collapse due to waterlogging, the hydrological ones are usually assigned to runoff or flooding. Studies in the literature propose predicting mass movement events as a function of accumulated rainfall levels recorded at distinct periods. According to these approaches, a two-dimensional rainfall levels feature space is segmented into the occurrence and non-occurrence decision regions by an empirical critical curve (CC). Although this scheme may easily be extended to other purposes and applications, studies in the literature need to discuss its use for flooding prediction. In light of this motivation, the present study is unfolded in (1) verifying that defining CCs in the rainfall levels feature space is a practical approach for flooding prediction and (2) analyzing how geospatial components interact with rainfall levels and flooding prediction. A database containing the rainfall levels recorded for flooding and non-flooding events in São Paulo city, Brazil, regarding the period 2015–2016, was considered in this study. The results indicate good accuracy for flooding prediction using only partial rain, which can be improved by adding physical characteristics of the flooding locations, demonstrating a direct correlation with spatial interactions, and rainfall levels.     

Pyroxene glasses — candidates for the interstellar silicate dust component

Experimentelle Arbeiten, die von der Universitäts-Sternwarte Jena in Zusammenarbeit mit chemischen Institutionen durchgeführt wurden, haben gezeigt, daß Pyroxengläser vielversprechende Kandidaten zur Identifizierung von Silikatstaubteilchen in der Umgebung sehr junger Objekte in Molekülwolken, z. B. BN-Objekten und T-Tauri-Sternen, sind. Die Wichtigkeit dieser Experimente besteht darin, daß sie die zur Modellierung der Quellen benötigren optischen Daten liefern und daß sie es ermöglichen, die mineralogische Beschaffenheit des Teilchenmaterials zu verstehen. In dieser Arbeit werden die Schritle, die in der jüngsten Zeit von der Jenaer Staubarbeitsgruppe in beide Richtungen unternommen wurden, beschrieben.