Coronal disturbances

Time lapse movies acquired with the Sacramento Peak Observatory 6-in filter coronagraph very infrequently show dramatic transient events. Many of these events (at 1.04 < r/r < 1.20) are correlated with H activity at the limb, especially with large surges and eruptive prominences. Metric or centrimetric radio bursts are found associated with certain types of 5303 coronal events. The heights to which such disturbances will propagate can often be estimated from the green line movie data. We report the results of a study of all the examples of such transients observed during the last 16 years.     

The minimum cost combination in agriculture

It has been made clear that the minimum cost combination in agriculture varies greatly from country to country and must change considerably from phase to phase in the course of national economic development. The criteria according to which the minimum cost combinations of the different developing countries tend to change vary greatly, depending on whether the countries in question were initially sparsely or densely populated. It also follows that in developing countries with varying economic structures the technical progress made will also vary in importance. It is easy to see from what has been said that progress in the mechanical field will be of greatest profit to thinly populated agricultural countries, while the future development of overpopulated agricultural countries will receive most benefit from progress in the field of organic sciences.     

Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb     

Evaluation of pre-CHAMP gravity models `GRIM5-S1' and `GRIM5-C1' with satellite crossover altimetry

 The new GFZ/GRGS gravity field models GRIM5-S1 and GRIM5-C1, currently used as initial models for the CHAMP mission, have been compared with other recent models (JGM 3, EGM 96) for radial orbit accuracy (by means of latitude lumped coefficients) in computations on altimetry satellite orbits. The bases for accuracy judgements are multi-year averages of crossover sea height differences from Geosat and ERS 1/2 missions. This radially sensitive data is fully independent of the data used to develop these gravity models. There is good agreement between the observed differences in all of the world's oceans and projections of the same errors from the scaled covariance matrix of their harmonic geopotential coefficients. It was found that the tentative scale factor of five for the formal standard deviations of the harmonic coefficients of the new GRIM fields is justified, i.e. the accuracy estimates, provided together with the GRIM geopotential coefficients, are realistic. Received: 20 February 2001 / Accepted: 24 October 2001     

Gas saturation prediction and effect of low frequencies on acoustic impedance images at Foinaven Field

Low frequencies are necessary in seismic data for proper acoustic impedance imaging and for petrophysical interpretation. Without lower frequencies, images can be distorted leading to incorrect reservoir interpretation and petrophysical predictions. As part of the Foinaven Active Reservoir Management (FARM) project, a Towed Streamer survey and an Ocean Bottom Hydrophone (OBH) survey were shot in both 1995 and 1998. The OBH surveys contain lower frequencies than the streamer surveys, providing a unique opportunity to study the effects that low frequencies have on both the acoustic impedance image along with petrophysical time‐lapse predictions. Artefacts that could easily have been interpreted as high‐resolution features in the streamer data impedance volumes can be distinguished by comparison with the impedance volumes created from the OBH surveys containing lower frequencies. In order to obtain results from the impedance volumes, impedance must be related to saturation. The mixing of exsolved gas, oil and water phases involves using the Reuss (uniform) or Voigt (patchy approximation) mixing laws. The Voigt average is easily misused by assuming that the end‐points correspond to 0% and 100% gas saturation. This implies that the patches are either 0% gas saturation or 100% gas saturation, which is never the case. Here, the distribution of gas as it comes out of solution is assumed to be uniform until the gas saturation reaches a sufficiently high value (critical gas saturation) to allow gas to flow. Therefore, at low gas saturations the distribution is uniform, but at saturations above critical, it is patchy, with patches that range from critical gas saturation to the highest gas saturation possible (1 minus residual oil and irreducible water saturation).     

Compositions,sources and depositional environments of organic matter from the Middle Jurassic clays of Poland

The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C₂₉-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C₃₃–C₃₅ homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ¹⁸O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples.     

Sublimation pressure and sublimation enthalpy of H2O ice Ih between 0 and 273.16 K

The sublimation of water in the region of extremely low pressures and temperatures meets increasing interest for the exploration of icy cosmic bodies. At temperatures below 130 K, the shape of the sublimation curve of H₂O is not known; neither experimental data nor theoretical treatments exist for this region. Based upon theoretical upper and lower bounds for the heat capacity of water vapor in this range, a narrow region in the pressure-temperature diagram is identified which must necessarily enclose the sublimation curve down to virtually any lower pressures and temperatures. Within this region, an approximate sublimation curve is computed from the 2006 Gibbs potential of ice Ih, using available heat capacity data points of water vapor between 10 and 130 K. The theoretical zero-point limiting law of the sublimation pressure is derived. Valid between 20 and 273.16 K, correlation equations for the sublimation enthalpy and the sublimation pressure are fitted to the computed data. All quantities are expressed in the 1990 temperature scale ITS-90. Under cosmic conditions, our results suggest that the sublimation of ice is unlikely below 50 K and impossible below 23 K.     

An 'outside-in' outburst of Aql X–1

We present optical spectroscopy and optical and infrared photometry of the neutron star soft X-ray transient Aql X–1 during its X-ray outburst of 1997 August. By modelling the X-ray, optical and IR light curves, we find a 3-d delay between the IR and X-ray rise times, analogous to the UV–optical delay seen in dwarf novae outbursts and black hole X-ray transients. We interpret this delay as the signature of an 'outside-in' outburst, in which a thermal instability in the outer disc propagates inward. This outburst is the first of this type definitively identified in a neutron star X-ray transient.     

Heat capacity of wadeite-type K2Si4O9 and the pressure-induced stable decomposition of K-feldspar

The heat capacity of synthetic, stoichiometric wadeite-type K₂Si₄O₉ has been measured by DSC in the 195≤T(K)≤598 range. Near the upper temperature limit of our data, the heat capacity observed by DSC agrees with that reported by Geisinger et al. (1987) based on a vibrational model of their infrared and Raman spectroscopic data. However, with decreasing temperature, the Cp observed by DSC is progressively higher than that predicted from the vibrational model, suggesting that the standard entropy of K₂Si₄O₉ is likely to be larger than 198.9 ± 4.0 J/K · mol computed from the spectroscopic data. A fit to the DSC data gave: Cp(T) = 499.13 (±1.87) − 4.35014 · 10³(±3.489 · 10¹) · T ^−0.5, with T in K and average absolute percent deviation of 0.37%. The room-temperature compressibilities of kalsilite and leucite, hitherto unknown, have been measured as well. The data, fitted to the Murnaghan equation of state, gave K _o = 58.6 GPa, K _o ^′ = 0.1 for kalsilite and K _o = 45 GPa, K _o ^′ = 5.7 for α-leucite. Apart from the above mentioned data on the properties of the individual phases, we have also obtained reaction-reversals on four equilibria in the system K₂O-Al₂O₃-SiO₂. The Bayesian method has been used simultaneously to process the properties of 13 phases and 15 reactions between them to derive an internally consistent thermodynamic dataset for the K₂O-Al₂O₃-SiO₂ ternary. The enthalpy of formation of K₂Si₄O₉ wadeite is in perfect agreement with its revised calorimetric value, the standard entropy is 232.1 ± 10.4 J/K · mol, ∼15% higher than that implied by vibrational modeling. The phase diagram, generated from our internally consistent thermodynamic dataset, shows that for all probable P-T trajectories in the subduction regime, the stable pressure-induced decomposition of K-feldspar will produce coesite + kalsilite rather than coesite + kyanite + K₂Si₄O₉ (cf. Urakawa et al. 1994). Received: 11 June 1997 / Accepted: 2 December 1997