Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors

A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.     

On Geodynamic Evolution of Simao Region (Southwestern Yunnan, China) during Late Paleozoic and Triassic

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＳｉｍａｏｒｅｇｉｏｎ (ＳＷＹｕｎｎａｎ ,Ｃｈｉｎａ) ,ｓｉｔｕａｔｅｄｂｅ ｔｗｅｅｎｔｈｅＡｉｌａｏｓｈａｎｂｅｌｔｉｎｔｈｅｅａｓｔａｎｄｔｈｅＬａｎｃａｎｇｊｉａｎｇｚｏｎｅｉｎｔｈｅｗｅｓｔ (Ｆｉｇ .1) ,ｉｓａｋｅｙａｒｅａｔｏｃｈｒｏｎｏｌｏｇｉｃａｌｌｙｃｏｎｓｔｒａｉｎｌａｔｅＰａｌｅｏｚｏｉｃｃｏｍｐｒｅｓｓｉｏｎａｌｄｅｆｏｒｍａｔｉｏｎｓａｎｄｔｈｕｓｏｆｐｒｉｍｅｉｎ ｔｅｒｅｓｔｗｈｅｎｄｉｓｃｕｓｓｉｎｇｔｈｅｐｌａｔｅ ｔｅｃｔｏｎｉｃｈｉ…     

Biomarkers in sedimentary sulfides of precambrian age

Samples of the Mt Isa formation (Australia, c, 1.5 Ga), and the Shungit formation (U.S.S.R., c. 2.3 Ga) were studied by organic geochemical means. All samples were freed of any low-molecular-weight solvent soluble organic material in order to insure the authenticity of the analysed material. The isolation of biochemical compounds entrapped in sulfides was the major goal of this work.Organic compounds that were entrapped during the early stages of sulfide formation may obviously survive extended periods of time and can be released by a mild hydrogenation of the sulfides. Preliminary investigations of the hydrocarbon fraction indicate n-alkanes, monomethylalkanes, cycloalkanes, and an unknown series of branched alkanes as major constituents. Their distribution patterns show great selectivity with respect to structures and chain lengths of individual compounds. Differences between the hydrogenation reaction product and the sample extract may arise from the release of a different kind of lipid material through dissolution of the sulfides.     

Protecting small cetaceans from coastal development: Impact assessment and mitigation experience in Hong Kong

Since the early 1990s, there has been an active program in Hong Kong to manage and protect local populations of small cetaceans from the effects of massive development in the area. This paper reviews the progress that has been made. Only two species regularly occur there: the Indo-Pacific humpback dolphin and the finless porpoise. Because most development has occurred in the western waters of Hong Kong, where generally only the humpback dolphin occurs, most of the work has been conducted on that species. Development of large infrastructure projects (such as airports, bridges, expressways, power plants, fuel facilities, and container ports) in Hong Kong often results in land reclamation, dredging and dumping of spoils, pipe and cable laying, percussive and bored piling work, underwater blasting, large increases in vessel traffic, and other impacts. Several mitigation measures have been used with varying levels of success, including bubble curtains/jackets, exclusion zones, ramping up of piling hammers, acoustic decoupling of noisy equipment, vessel speed limits, no-dumping policies, and silt curtains. Baseline, construction-phase, and operational-phase cetacean monitoring is often conducted to evaluate the success of conservation measures put into place. The Environmental Impact Assessment process in Hong Kong has involved cetaceans to a degree perhaps higher than anywhere else in the world, and much can be learned from studying the successes and failures of this situation.     

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.     

Estimation of the temporal autocorrelation structure by the collocation technique with an emphasis on soil moisture studies

Abstract

The collocation technique has become a popular tool in oceanography and hydrology for estimating the error variances of different data sources such as in situ sensors, models and remote sensing products. It is also possible to determine calibration constants, for example to account for an off-set between the data sources. So far, the temporal autocorrelation structure of the errors has not been studied, although it is known that it has detrimental effects on the results of the collocation technique, in particular when calibration constants are also determined. This paper shows how the (triple) collocation estimators can be adapted to retrieve the autocovariance functions; the statistical properties as well as the structural deficencies are described. The coupling between the autocorrelation of the error and the estimation of calibration constants is studied in detail, due to its importance for analysing temporal changes. In soil moisture applications, such time variations can be induced, for example, by seasonal changes in the vegetation cover, which affect both models and remote sensing products. The limitations of the proposed technique associated with these considerations are analysed using remote sensing and in situ soil moisture data. The variability of the inter-sensor calibration and the autocovariance are shown to be closely related to temporal patterns of the data.

Editor D. Koutsoyiannis

Citation Zwieback, S., Dorigo, W., and Wagner, W., 2013. Estimation of the temporal autocorrelation structure by the collocation technique with an emphasis on soil moisture studies. Hydrological Sciences Journal, 58 (8), 1729–1747.     

Coronal disturbances

Time lapse movies acquired with the Sacramento Peak Observatory 6-in filter coronagraph very infrequently show dramatic transient events. Many of these events (at 1.04 < r/r < 1.20) are correlated with H activity at the limb, especially with large surges and eruptive prominences. Metric or centrimetric radio bursts are found associated with certain types of 5303 coronal events. The heights to which such disturbances will propagate can often be estimated from the green line movie data. We report the results of a study of all the examples of such transients observed during the last 16 years.     

3XMM J185246.6+003317 as transient neutron star

We performed an X‐ray timing and spectral analysis of the variable source 3XMM J185246.6+003317 to investigate its physical nature. The data from all observations of 3XMMJ185246.6+003317 conducted by XMM‐Newton EPIC MOS1 and MOS2 with the same instrumental setup in 2004–2009 were reprocessed to form a homogenous data set of solar barycenter corrected photon arrival times and high S/N spectra of 3XMM J185246.6+003317. A Bayesian method for the search, detection, and estimation of the parameters of a periodic signal of unknown shape was employed, as developed by Gregory & Loredo (1992, 1993). The results show that 3XMM J185246.6+003317 is a transient neutron star with the genuine spin‐period of 23.11722 (23.11711–23.11727) s and its derivative of 5.3(0.3–5.5)×10^–11 s s^–1, implying a characteristic age of 7 (6–104) kyr, if the period derivative can be ascribed to the genuine spin‐down rate of the neutron star. The rotational‐phase averaged X‐ray spectra at the different brightness periods can be fitted with a highly absorbed blackbody model with different temperatures. The phase‐folded light curves in different energy bands with high S/N ratio show a double‐peaked profile; the variations depend on time and energy, indicating that radiation emerges from at least two emitting areas. The spectra at the phases corresponding to the maxima in the phase‐folded light curve show different spectral parameters of absorbed blackbody radiation, i.e. the hotter one has a smaller size. The source is detected only from September 2008 to April 2009 with persistently decreasing brightness, but not before, even though it was observed by XMM. Hence, it is a transient neutron star or a binary system hosting it. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Particle dynamics in reconnection field configurations

Trajectories of test particles are studied numerically in two types of reconnection magnetic field configurations, a single X-line magnetic field configuration and a tearing magnetic field configuration. Both adiabatic and nonadiabatic motions are examined, with special emphasis on net energy gain and time spent in the neutral line regions. They spend typically one characteristic gyroperiod in the X-line region and are ejected predominantly along field lines in the vicinity of the separatrix. Both adiabatic and nonadiabatic test particles in the tearing-type field configuration are channelled into and accelerated along the O-line region. It may be inferred from these test particle results that particle energizations are significant along the O-line region, but not along the X-line region. These results are in qualitative agreement with those obtained by a self-consistent particle simulation.