Geomorphological evidence for the Late Holocene evolution and the Holocene lake level maximum of the Aral Sea

During the Holocene the Aral Sea underwent various transgressive and regressive phases of different magnitudes. However, previous work has not yet fully clarified the evolution and chronology of the individual phases. Research presented here throws light on the evolution of the Aral Sea during the past  2000 years. It includes field surveys, tachymetric and DGPS-derived altitude measurements, analysis of sediments from two areas of the northern and southern Aral Basin (Tastubek Bay and Karaumbet Bay), and their correlation with GIS-based lake area models. Geomorphological and sedimentological evidence from the study areas shows a transgression of the Aral Sea around 200 AD, ending at a lake level maximum of 54 to 55 m. After a medieval regression, the lake reached this level again between the late 16th and early 19th century AD. The digital elevation model SRTM-3 was used to estimate a lake size of 72,400 km² for the lake level maximum.Elevated palaeoshorelines, specifically at 72–73 m, are completely absent in the study areas. Local remains of escarpments at elevations of 66 m and 73 m are due to resistant Miocene caprock and are therefore not interpretable as shoreline features.     

Multiphase flow above explosion sites in debris-filled volcanic vents: Insights from analogue experiments

Discrete explosive bursts are known from many volcanic eruptions. In maar–diatreme eruptions, they have occurred in debris-filled volcanic vents when magma interacted with groundwater, implying that material mobilized by such explosions passed through the overlying and enclosing debris to reach the surface. Although other studies have addressed the form and characteristics of craters formed by discrete explosions in unconsolidated material, no details are available regarding the structure of the disturbed debris between the explosion site and the surface. Field studies of diatreme deposits reveal cross-cutting, steep-sided zones of non-bedded volcaniclastic material that have been inferred to result from sedimentation of material transported by “debris jets” driven by explosions. In order to determine the general processes and deposit geometry resulting from discrete, explosive injections of entrained particles through a particulate host, we ran a series of analogue experiments. Specific volumes of compressed (0.5–2.5 MPa) air were released in bursts that drove gas-particle dispersions through a granular host. The air expanded into and entrained coloured particles in a small crucible before moving upward into the host (white particles). Each burst drove into the host an expanding cavity containing air and coloured particles. Total duration of each run, recorded with high-speed video, was approximately 0.5–1 s. The coloured beads sedimented into the transient cavity. This same behaviour was observed even in runs where there was no breaching of the surface, and no coloured beads ejected. A steep-sided body of coloured beads was left that is similar to the cross-cutting pipes observed in deposits filling real volcanic vents, in which cavity collapse can result not only from gas escape through a granular host as in the experiments, but also through condensation of water vapour. A key conclusion from these experiments is that the geometry of cross-cutting volcaniclastic deposits in volcanic vents is not directly informative of the geometry of the “intrusions” that formed them. An additional conclusion is that complex structures can form quickly from discrete events.     

Ten Years of Development of Equipment for Measurement of Atmospheric Radioactive Xenon for the Verification of the CTBT

Atmospheric measurement of radioactive xenon isotopes (radioxenon) plays a key role in remote monitoring of nuclear explosions, since it has a high capability to capture radioactive debris for a wide range of explosion scenarios. It is therefore a powerful tool in providing evidence for nuclear testing, and is one of the key components of the verification regime of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The reliability of this method is largely based on a well-developed measurement technology. In the 1990s, with the prospect of the build-up of a monitoring network for the CTBT, new development of radioxenon equipment started. This article summarizes the physical and technical principles upon which the radioxenon technology is based and the advances the technology has undergone during the last 10 years. In contrast to previously used equipment, which was manually operated, the new generation of radioxenon monitoring equipment is designed for automated and continuous operation in remote field locations. Also the analytical capabilities of the equipment were strongly enhanced. Minimum detectable concentrations of the recently developed systems are well below 1 mBq/m³ for the key nuclide ¹³³Xe for sampling periods between 8 and 24 h. All the systems described here are also able to separately measure with low detection limits the radioxenon isotopes ^131mXe, ^133mXe and ¹³⁵Xe, which are also relevant for the detection of nuclear tests. The equipment has been extensively tested during recent years by operation in a laboratory environment and in field locations, by performing comparison measurements with laboratory type equipment and by parallel operation. These tests demonstrate that the equipment has reached a sufficiently high technical standard for deployment in the global CTBT verification regime.     

Meltwater and the global ocean conveyor: northern versus southern connections

The sensitivity of the ocean circulation to changes in North Atlantic surface fluxes has become a major factor in explaining climate variability. The role of the Antarctic Bottom Water in modulating this variability has received much less attention, limiting the development of a complete understanding of decadal to millennial time-scale climate change. New analyses indicate that the southern deepwater source may change dramatically (e.g., experience a decrease of as much as two thirds during last 800 years). Such change can substantially alter the ocean circulation patterns of the last millennium. Additional analyses indicate that the Southern Hemisphere led the Northern Hemisphere changes in some of the glacial cycles of Pleistocene, implying a seesaw-type oscillation of the global ocean conveyor. The potential for melting of sea ice and ice sheets in the Antarctica associated with global warming can cause a further slowdown of the southern deepwater source. These results demand an assessment of the role of the Southern Ocean in driving changes of the global ocean circulation and climate. Systematic model simulation targeting the ocean circulation response to changes in surface salinity in the high latitudes of both Northern and Southern Hemispheres demonstrate that meltwater impacts in one hemisphere may lead to a strengthening of the thermohaline conveyor driven by the source in the opposite hemisphere. This, in turn, leads to significant changes in poleward heat transport. Further, meltwater events can lead to deep-sea warming and thermal expansion of abyssal water, that in turn cause a substantial sea-level change even without a major ice sheet melting.     

Analysis of heavy rainfall events in North Rhine–Westphalia with radar and raingauge data

Five heavy rainfall events were investigated with radar and raingauge data. Special attention was paid to quality check and adjustment of radar data. Attenuation effects could be observed on both, C-Band and on X-Band radar. Adjustment of radar data to raingauge values turned out to be difficult in the vicinity of heavy local rain cells. Four adjustment methods were analysed and radar data from different radar stations were compared. As a further result of this project, the spatial extent of the precipitation fields was identified by adjusted radar data and compared to raingauge data. For each rainfall event, radar derived accumulated rainfall images and catchment time series were produced.     

Organic geochemistry of Deep Sea Drilling Project sediments from the Gulf of Calofornia—hydrothermal effects on unconsolidated diatom ooze

The effects of intrusive thermal stress have been studied on a number of Pleistocene sediment samples obtained from Leg 64 of the DSDP-IPOD program in the Gulf of California. Samples were selected from Sites 477, 478 and 481 where the organic matter was subjected to thermal stress from sill intrusions. For comparison purposes, samples from Sites 474 and 479 were selected as representative of unaltered material.The GC and GC-MS data show that lipids of the thermally unaltered samples were derived from microbial and terrestrial higher-plant detritus. Samples from sill proximities were found to contain thermally-derived distillates and those adjacent to sills contained essentially no lipids. Curie point pyrolysis combined with GC and GC-MS was used to show that kerogens from the unaltered samples reflected their predominantly autochthonous microbial origin. Pyrograms of the altered kerogens were much less complex than the unaltered samples, reflecting the thermal effects. The kerogens adjacent to the sills produce little or no pyrolysis products since these intrusions into unconsolidated, wet sediments resulted in in situ pyrolysis of the organic matter.Examination of the kerogens by ESR showed that spin density and line width pass through a maximum during the course of alteration but ESR g-values show no correlation with maturity. Stable carbon isotope (δ¹³C) values of kerogens decrease by 1–1.5‰ near the sills at Sites 477 and 481 and the atomic N/C decreases slightly with proximity to a smaller sill at Site 478. Differences in maturation behavior between Site 477 and 481 and Site 478 are attributed to dissimilarities in thermal stress and to chemical and isotopic heterogeneity of Guaymas Basin protokerogen.     

Seismicity and tectonics of southern Central America and adjacent regions with special attention to the surroundings of Panama

Ten new focal mechanisms are derived for earthquakes in southern Central America and its adjacent regions. These are combined with a study of seismicity and data of previous workers to delineate the position and nature of the plate boundaries in this complex region.The Middle America subduction zone may be divided into four or five distinct seismic segments. The plate boundary between North America and the Caribbean near the trench might be located more towards the south than previously suspected. Subduction has basically stopped south of the underthrusting Cocos Ridge. There is not much evidence for a seismically active strike-slip fault south of Panama, but its existence cannot be ruled out. More activity reveals the zone north of Panama which is identified as a subduction zone with normal fault events. Shallow seismicity induced by the interaction of the Nazca plate extends from the Colombia-Panama border south along the Pacific coast to meet a high-angle continental thrust fault system. Subduction with a pronounced slab starts only south of that point near a hot region which offsets the seismic trend at the trench. The Carnegie Ridge and/or the change of direction of subduction in Ecuador produce a highly active zone of seismicity mainly at the depth of 200 km. The area in the Pacific displays a termination of activity at a propagating rift west of the Galapagos Islands. The main eastern boundary of the Cocos plate, the Panama Fracture Zone, is offset towards the west at the southern end of the Malpelo Ridge. Its northern end consists of two active branches as defined by large earthquakes. A strike-slip mechanism near the southeastern flank of the Cocos Ridge was previously believed to be the site of an extended fracture zone. This paper proposes submarine volcanic activity as an alternative explanation.     

Cyclic terpenoids of contemporary resinous plant detritus and of fossil woods, ambers and coals

Cyclic terpenoids present in the solvent extractable material of fossil woods, ambers and brown coals have been analyzed. The sample series chosen consisted of wood remains preserved in Holocene to Jurassic sediments and a set of of ambers from the Philippines (copalite), Israel, Canada and Dominican Republic. The brown coals selected were from the Fortuna Garsdorf Mine and Miocene formations on Fiji.The fossil wood extracts contained dominant diterpenoid or sesquiterpenoid skeletons, and aromatized species were present at high concentrations, with a major amount of two-ring aromatic compounds. Tricyclic diterpenoids were the predominant compounds in the ambers. Aromatized derivatives were the major components, consisting of one or two aromatic ring species with the abietane and occasionally pimarane skeletons. The saturated structures were comprised primarily of the abietane and pimarane skeletons having from three to five carbon (C₁, C₂, etc.) substituents. Kaurane and phyllocladane isomers were present in only minor amounts. Bicyclic sesquiterpenoids as saturated and partial or fully aromatized forms were also common in these samples, but only traces of sesterterpenoids and triterpenoid derivatives were found.The brown coal extracts were composed of major amounts of one- and two-ring aromatized terpenoids, with a greater proportion of triterpenoid derivatives than in the case of the woods and ambers. This was especially noticeable for the German coal, where the triterpenoids were predominant. Open C-ring aromatized structures were also present in this coal. Steroid compounds were not detectable, but some hopanes were found as minor components in the German brown coal.An overview of the skeletal structure classes identified in each sample, as well as the general mass spectrometric characteristics of the unknown compounds are included in the present paper. It can be concluded from these structural distributions that aromatization is the main process for the transformation of terrestrial cyclic terpenoids during diagenesis, constituting a general pathway for all terpenoids.