Application of the Mussel Watch concept in studies of the distribution of hydrocarbons in the coastal zone of the Ebro Delta

The Mussel Watch concept was applied in a study of man-induced chemical changes in the Ebro Delta on the Catalonian coast to obtain a preliminary assessment of the distribution of synthetic organic compounds, petroleum and biogenic hydrocarbons in the local coastal zone. Mussels, oysters and clams were selected as the indicator organisms. Levels of petroleum accumulated by mussels were generally high, in the order of 100–800 μg^?1 dry weight, equivalent to those in mussels in the most polluted harbours and bays of California. The relative distributions of the steranes and pentacyclic triterpanes in the mussels were significantly different from those found in petroleum from a local field, indicating that local petroleum was not contributing to the present contamination. The composition of biogenic compounds was variable, probably reflecting differences in the composition of local plankton communities, PCB levels were high in relation to current levels in mussels from US sites, reflecting continuing PCB use in Spain. The Delta appears to be a point source of a number of organochlorine compounds, including HCB, the DDT compounds, endrin and γ-chlordane. Levels of the DDT compound o,p′-DDD, a pharmacologically active substance, were unexpectedly high; identification was confirmed by GS/MS. Many unidentified peaks were present on EC chromatograms, indicating a more complex pattern of contamination than might be suggested by printed summaries of data.     

Floodplain sediments on the divide between Huang He and Chang Jiang,Gansu Province,NW China

At Lingfeng, (34°17'N, 104°08'E) on the northern slopes of the Qinling Mountains, a stratigraphic survey was made of a 21-m-profile of floodplain sediments on the watershed between the Chang Jiang (Yangtze River) and Huang He (Yellow River) at 2500 m above sea level. The sediments contain <2 m thick layers of peat and detritical plant matter that had been deposited on the floodplain of the Langouhe. If the radiometric dates are reliable, the chronology of the site spans some 80,000 years, covering an accumulation process from the terminal Last Interglacial up to <24 ka BP. The phase >73 ka BP had cool and wet conditions with a coniferous forest vegetation. Between 73 ka and > 40 ka colder and drier conditions were likely. The vegetation changed from aPicea-Pinus forest to aPicea-Abies-Larix forest with a later increase of non-arboreal pollen. Around 40 ka the climate was warm and moist. The accumulation of silt and organic matter as well as the development of a mixed coniferous forest with high rates of thermophilous trees(Quercus, Castanea) characterize the interstadial conditions at this time. Later on, the climate changed to cool and moist conditions, evidenced by silt and peat accumulation and a coniferous forest vegetation up to <24 ka BP. The loess in this area was deposited after 24 ka and erosion by the tributaries of Chang Jiang and Huang He to a depth of at least 40 m created the watershed between the two river systems.     

Determination of chlorophyll content of small water bodies (kettle holes) using hyperspectral airborne data

This study presents an approach for chlorophyll content determination of small shallow water bodies (kettle holes) from hyperspectral airborne ROSIS and HyMap data (acquired on 15 May and 29 July 2008 respectively). Investigated field and airborne spectra for almost all kettle holes do not correspond to each other due to differences in ground sampling distance. Field spectra were collected from the height of 30–35 cm (i.e. area of 0.01–0.015 m²). Airborne pixels of ROSIS and HyMap imageries cover an area of 4 m² and 16 m² respectively and their spectra are highly influenced by algae or bottom properties of the kettle holes. Analysis of airborne spectra revealed that chlorophyll absorption near 677 nm is the same for both datasets. In order to enhance absorption properties, both airborne hyperspectral datasets were normalized by the continuum removal approach. Linear regression algorithms for ROSIS and HyMap datasets were derived using normalized average chlorophyll absorption spectra for each kettle hole. Overall accuracy of biomass mapping for ROSIS data was 71%, and for HyMap 64%. Biomass mapping results showed that, depending on the type of kettle hole, algae distribution, the ‘packaging effect’ and bottom reflection lead to miscalculations of the chlorophyll content using hyperspectral airborne data.     

Local variations of solifluction activity and environment in the Abisko Mountains,Northern Sweden

Seven sites within the mountain region of Abisko, northern Sweden, were selected for measurement of solifluction movement rates and correlation with the local environmental factors. Grids with sizes from 20 m × 30 m to 50 m × 100 m included both solifluction landforms and adjacent ground. Positions of movement markers and the terrain were recorded and the grid areas were digitally reconstructed. This allowed topography, vegetation and soil texture (fraction of fine material) surfaces to be interpolated and used together with data on soil moisture in statistical analyses. Significant correlations differ from site to site indicating that environmental factors have varying importance and inter‐relations depending on the local setting. Geomorphic work was also assessed within the grids. The results indicate measurable geomorphic work where no landforms are present. These areas may make larger contributions to sediment displacement than where solifluction landforms exist. Solifluction is an important denudational agent in the region and has its greatest impact on landscape development in the western part of the region. Copyright © 2011 John Wiley & Sons, Ltd.     

Coronal Density Structures and CMEs: Superior Solar Conjunctions of Mars Express, Venus Express, and Rosetta: 2004, 2006, and 2008

Coronal radio-sounding experiments were carried out using the S-band (2.3 GHz) and X-band (8.4 GHz) signals of the ESA Mars Express, Venus Express, and Rosetta spacecraft during five superior conjunctions occurring in 2004, 2006 (3×), and 2008/2009. Differential frequency and propagation delay (ranging) observations were recorded during these opportunities over the better part of a solar cycle, yielding information on the large-scale structure of the coronal electron-density distribution and its variations, including fluctuations on time scales from seconds to hours. These results concern primarily regions of slow solar wind because the radio propagation path is generally confined to the low heliolatitude regions by the conjunction. The mean frequency fluctuation and total electron content are determined as a function of heliocentric distance, and, with a few exceptions caused by streamers and CMEs, are found to be consistent with previous results from experiments on Ulysses. Dense coronal streamers and several coronal mass ejection (CME) events were identified in the radio-frequency data, some of which were observed in white light by the LASCO coronagraphs onboard SOHO. For those events with sufficient mutual coverage, good correlations are found between the electron-content fluctuations and structure imaged by the LASCO instrument.     

Bitumen from Coalport tar tunnel

The Coalport (Shropshire, U.K.) Tar Tunnel bitumen has been known since 1787 and the first geochemical data are reported here. The bitumen was analyzed for molecular markers useful for correlational studies. Gas chromatographic analysis of aliphatic and aromatic hydrocarbons failed to detect any specific major components normally used for genetic correlational and maturational studies. A search for minor and trace components by gas chromatographic-mass fragmentographic analysis showed the presence of triterpenoid hydrocarbons primarily of the 17α (H)-hopane series (C₂₇ to C₃₅, ex. C₂₈) and a C₂₆ to C₃₁ series of ring A/B demethylated hopanes. Two homologous sterane series (C₂₇ to C₂₉) of the 5α, 14β, 17β (H)-sterane and 13β, 17α (H)-diasterane type were also detected. Pophyrins of the DPEP and etio series (C₂₇ to C₄₁, DPEP/etio > 1) were also found. Characterization of their alkyl substitution pattern demonstrated C₁, C₂ and C₃ substituents on the pyrole moieties of the parent petroporphyrins.The molecular markers detected in this bitumen indicate its biogenic origin and show evidence of diagenetic and geothermal maturation processes. The overall geochemical characteristics of the Coalport Tar Tunnel bitumen suggest that it corresponds to a well matured crude oil, which was heavily altered by in-reservoir biodegradation or close to surface exposure.     

Tensor visualizations in computational geomechanics

We present a novel technique for visualizing tensors in three dimensional (3D) space. Of particular interest is the visualization of stress tensors resulting from 3D numerical simulations in computational geomechanics. To this end we present three different approaches to visualizing tensors in 3D space, namely hedgehogs, hyperstreamlines and hyperstreamsurfaces. We also present a number of examples related to stress distributions in 3D solids subjected to single and load couples. In addition, we present stress visualizations resulting from single‐pile and pile‐group computations. The main objective of this work is to investigate various techniques for visualizing general Cartesian tensors of rank 2 and it's application to geomechanics problems. Copyright © 2002 John Wiley & Sons, Ltd.     

A new tool for in situ monitoring of Fe-mobilization in soils

The aim of this study was to design and test a new tool for (i) the quantitative in situ monitoring of Fe(III) reduction in soils and (ii) the tracking of the potential mineralogical changes of Fe-oxides. The tool consists of small (2 × 2 × 0.2 cm) striated polymer plates coated with synthetic pure ferrihydrite or As-doped ferrihydrite (Fh–As). These slides were then inserted within two different horizons (organo-mineral and albic) located in a wetland soil with alternating redox conditions. Dissolution was quantified by X-ray fluorescence (XRF) analyses of total metal contents before and after insertion into the soil. The crystallographic evolution of Fe-oxides was characterized by scanning electron microscope equipped with an energy-dispersive spectrometer (SEM–EDS). Over the months, the ferrihydrite progressively disappeared, at rates comparable to those previously measured in laboratory studies, i.e. in the 1–10 × 10⁻¹² mol Fe m⁻² s⁻¹ range. SEM observations indicate that the supports were highly colonized by bacteria and biofilms in the organo-mineral horizon, suggesting a biological-mediated process, while the albic horizon appeared to be characterized by a mostly chemical-mediated process. In the albic horizon, Fe-sulphide and other micro-precipitates were formed after 7 months of incubation in balance with a quasi dissolution of initial Fe-oxides.