Late Pleistocene and Holocene history of Lake Terrasovoje,Amery Oasis,East Antarctica,and its climatic and environmental implications

A 5.52 m long sediment sequence was recovered from Lake Terrasovoje, Amery Oasis, East Antarctica, in order to reconstruct the regional environmental history. The basal sediments, which are dominated by glacial and glaciofluvial clastic sediments, attest to a Late Pleistocene deglaciation of the lake basin. These sediments are overlain by 2.70 m of laminated algal and microbial mats and a few interspersed moss layers. Radiocarbon dating, conducted on bulk organic carbon of 12 samples throughout the organic sequence, provides a reliable chronology since the onset of biogenic accumulation at c. 12,400 cal. year BP. Successful diatom colonization, however, was probably hampered by extensive ice and snow cover on the lake and restricted input of nutrients until 10,200 cal. year BP. A subsequent increase of nutrient supply culminated between 8600 and 8200 cal. year BP and is related to warm summer temperatures and reduced albedo in the catchment. Warm conditions lasted until 6700 cal. year BP, supporting the establishment of a diatom community. Colder temperatures from 6700 cal. year BP culminated in several periods between 6200 and 3700 cal. year BP, when high amounts of sulphur and low abundances of diatoms were deposited due to a perennial ice and snow cover on the lake. During the late Holocene, relatively warm conditions between 3200 and 2300 cal. year BP and between 1500 to 1000 cal. year BP, respectively, indicated by high accumulation of organic matter and reducing bottom water conditions, were interrupted and followed by colder periods.     

Palaeozoic granites of the Umberatana region,South Australia: the role of volatiles in the crystallization of some alkaline-peralkaline granites

Palaeozoic alkaline to peralkaline sodic granites of the Umberatana area of South Australia have high MnO, P₅O₅, Nb, Ta, Be, F and B abundances as is typical of »A-type« or anorogenic granites. Abundant F and B in the magma permitted primary muscovite to crystallize at pressures that may have been as low as 1 Kbar because of the lowered solidus temperatures. These volatile-rich magmas precipitated both albite and two generations of K-rich alkali feldspar. The hydrothermal fluids released during crystallization of these magmas resulted in considerable element redistribution and recrystallization both in the plutons and the adjacent country rocks.

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Zusammenfassung Paläozoische alkaline-peralkaline Sodagranite von Umberatana, Südaustralien, besitzen erhöhte Gehalte an MnO, P₂O₅, Nb, Ta, Be, F and B und zeigen Charakteristika von »A-Typ« Graniten. Erhöhte Gehalte an F und B erlaubte die Kristallisation von primärem Muskovit bei Drucken, die auf Grund der erniedrigten Solidus Temperaturen möglicherweise 1 Kbar betrugen. Diese Gas reichen Magmen schieden Albit und zwei Generationen von K-reichem Alkalifeldspat aus. Die hydrothermalen fluiden Phasen, die sich während der Kristallisation dieser Magmen bildeten, verursachten eine bedeutene Elementumverteilung und Rekristallisation in den Intrusionen und dem unmittelbaren Nebengestein.

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Résumé Les granites sodiques alcalins à peralcalins paléozoïques de la région d'Umberatana (Australie méridionale) présentent des teneurs élevées en MnO, P₂O₅, Nb, Ta, Be, F et B, caractère typique des granites de type A, ou anorogéniques. La grande quantité de F et de B présente dans le magma a permis la cristallisation de muscovite primaire à une pression qui ne devait pas excéder 1 Kbar, en raison de l'abaissement de la température du solidus. Ces magmas, riches en matières volatiles, ont précipité de l'albite et deux générations de feldspath alcalin potassique. Les fluides hydrothermaux libérés au cours de la cristallisation ont permis une redistribution et une recristallisation importante des éléments à la fois dans les plutons et dans les roches encaissantes.

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- ( ) MnO, P₂O₅, Nb, , Be, F B, , «». , , , , 1 . , . , , , , .

     

Alkaline permanganate oxidation of kerogens from Cretaceous black shales thermally altered by diabase intrusions and laboratory simulations

Potassium permanganate oxidative degradations were conducted for kerogens isolated from Cretaceous black shales (DSDP Leg 41, Site 368), thermally altered during the Miocene by diabase intrusions and from unaltered samples heated under laboratory conditions (250–500°C).Degradation products of less altered kerogens are dominated by normal C₄–C₁₅ α,ω-dicarboxylic acids, with lesser amounts of n-C₁₆ and n-C₁₈ monocarboxylic acids, and benzene mono-to-tetracarboxylic acids. On the other hand, thermally altered kerogens show benzene di-to-tetracarboxylic acids as dominant degradation products, with lesser or no amounts (variable depending on the degree of thermal alteration) of α,ω-dicarboxylic acids. Essentially no differences between the oxidative degradation products of naturally- and artificially-altered kerogens are observed.As a result of this study, five indices of aromatization (total aromatic acids/kerogen; apparent aromaticity; benzenetetracarboxylic acids/total aromatic acids; benzene-1,2-dicarboxylic acid/benzenedicarboxylic acids; benzene-1,2,3-tricarboxylic acid/benzenetricarboxylic acids) and two indices of aliphatic character (Total aliphatic acids/kerogen; Aliphaticity) are proposed to characterize the degree of thermal alteration of kerogens.Furthermore, a good correlation is observed between apparent aromaticity estimated by the present KMnO₄ oxidation method and that from the ¹³C NMR method (DENNIS et al., 1982).     

Organic matter of the troposphere — V: Application of molecular marker analysis to biogenic emissions into the troposphere for source reconciliations

Organic matter in tropospheric aerosols is derived from two major sources and is admixed depending on the geographic area. These sources are biogenic detritus and anthropogenic emissions. The biogenic materials in the solvent-extractable organic matter are comprised predominantly of higher plant waxes, with lesser amounts of resin and microbial detritus and the anthropogenic components are primarily vehicular emissions (e.g. oils, soot, etc.) and input from combustion (e.g. charcoal, thermally-altered biogenic matter, etc.). Both biogenic detritus and anthropogenic emissions contain organic compounds (C₁₂–C₄₀₊), which can be identified with unique and distinguishable distribution patterns. Molecular composition analysis has been applied to such extracts after suitable chemical separation into subfractions (i.e. hydrocarbons, ketones, aldehydes, carboxylic acids, alcohols, and wax esters). Both homologous compound series and specific natural products (e.g. phytosterols, terpenes, etc.) are identified as molecular markers.Aerosols from rural and remote areas in the western United States, South America, Nigeria and Australia have been analyzed and all contained predominantly plant waxes. The loadings of hydrocarbons ranged approximately from 10–1400 ng/m³ of air, of fatty acids from 10–450 ng/m³ and of fatty alcohols from 10–1650 ng/m³. These higher molecular weight lipids primarily from flora comprise a major component of the organic carbon in rural and remote aerosols. They are thus important indicators for regional biogenic sources in the global cycling of organic carbon.Presented in part at the International Symposium on Biosphere-Atmosphere Exchange, Mainz, E.R. Germany, March 16–22, 1986, for Part IV see Simoneit et al. (1988) Atmos. Environ. 22, 983–1004.     

Structural states of Mg cordierite III: Infrared spectroscopy and the nature of the hexagonal-modulated transition

The time evolution of the Al, Si ordering and the ferroelastic distortion of the Mg-cordierite structure are quantified on a local length scale by Hard Mode Infrared Spectroscopy (HMIS). The line profiles of various absorption peaks were measured at room temperature and at 80 K. Their integrated intensities, frequencies and half width are correlated with the interacting order parameters Q _od (Al, Si ordering), Q (displacive orthorhombic distortion) and their equivalent short-range analogs. It is shown that the phase transition between hexagonal and modulated cordierite is stepwise, as predicted earlier. The local structural state of quenched, modulated cordierite is essentially equivalent to that of the orthorhombic phase. A general concept is outlined which allows, in general, the independent determination of various interacting order parameters using HMIS.     

Structural states of natural potassium feldspar: An infrared spectroscopic study

Natural samples of K-feldspar representing various states of Al, Si order were characterised using X-ray methods, transmission electron microscopy, and Fourier transform infrared spectroscopy. Line profiles of infrared absorption bands were observed to show strong correlation with the degree of Al, Si order present. In particular, the absorption frequencies of the 540 cm^?1 and 640 cm^?1 bands were seen to vary by ca. 10 cm^?1 between sanidine and microcline, with modulated samples respresenting intermediate behaviour. Linewidths of these modes also decrease by ca. 50% in this series. The experimental results are discussed within the framework of Hard Mode Infrared Spectroscopy (HMIS), and it is shown that the absorption frequencies vary with the short range order parameter τ = (4t₁-1)² and the symmetry breaking order parameter describing Al, Si order, Q _od=(t₁ 0?t₁ m)/Q _od=(t₁ 0+t₁ m), where t₁ is the average Al occupancy on the T₁ sites and t₁ o and t₁ m are the individual site occupancies of the T₁ o and T₁ m sites, respectively. The structural state of orthoclase is characterised by strain-induced modulations with large spatial variations of the modulation wavelength. No such modulations were observed in the degree of local Al, Si order. Sanidine shows mode hardening in excess of the extrapolated effect of symmetry breaking Al, Si order, which is presumably related to nonsymmetry breaking ordering between T₁ and T₂ sites and/or as yet unobserved short range order of the symmetry breaking ordering scheme. The possibility of an additional phase transition in K-feldspar at temperatures above 1300 K is discussed.     

Compositions and sources of extractable organic matter in Mesopotamian marshland surface sediments of Iraq: II. Polar compounds

The concentrations of polar organic compounds including n-alkanoic acids, n-alkanols, steroids and triterpenoids were determined in extracts of shallow sediments from the Mesopotamian marshlands of Iraq. The sediments were collected by a stainless steel sediment corer, extracted with a dichloromethane and methanol mixture (3:1 v:v) by ultrasonic agitation and then analyzed by gas chromatography–mass spectrometric (GC–MS). The analysis results showed that the n-alkanoic acids ranged from C₈ to C₂₀ with concentrations of 7.8 ± 1.2 μg/g sample, whereas the concentrations of n-alkanols, which ranged from C₁₂ to C₃₉ were from 28.6 ± 4.3 to 121.7 ± 18.3 μg/g sample. The steroids and triterpenoids included stenols, stanols, stenones, stanones, tetrahymanol, tetrahymanone and extended ββ-hopanes. The total concentrations of steroids and triterpenoids ranged from 26.8 ± 4.1 to 174.6 ± 26.2 μg/g and from 0.74 ± 0.11 to 11.2 ± 1.7 μg/g sample, respectively. The major sources of these lipids were from natural vegetation, microbial (plankton) residues and bacteria in the sediments, with some contribution from anthropogenic sources (livestock, sewage and petroleum). Further studies of these wetlands are needed to characterize the input rate, transformation and diagenesis of the organic matter and to assess its various sources.     

Compositions and sources of extractable organic matter in Mesopotamian marshland surface sediments of Iraq. I: aliphatic lipids

Shallow surface sediment samples from the Mesopotamian marshlands of Iraq were collected and analyzed to determine the distribution, concentrations and sources of aliphatic lipid compounds (n-alkanes, n-alkanols, n-alkanoic acids, and methyl n-alkanoates) and molecular markers of petroleum in these wetlands. The sediments were collected using a stainless steel sediment corer, dried, extracted with a dichloromethane/methanol mixture and then analyzed by gas chromatography-mass spectrometry (GC–MS). The aliphatic lipid compounds included n-alkanes, n-alkanoic acids, n-alkanols and methyl n-alkanoates with concentrations ranged from 6.8 to 31.1 μg/g, 4.1 to 5.0 μg/g, 5.9 to 7.7 μg/g and from 0.3 to 5.9 μg/g, respectively. The major sources of aliphatic lipids were natural from waxes of higher plants (24–30%) and microbial residues (42–30%), with a significant contribution from anthropogenic sources (27–30%, petroleum), based on the organic geochemical parameters and indices. Further studies are needed to characterize the rate, accumulation and transformation of various organic matter sources before and after re-flooding of these wetlands.     

Origin and fluxes of atmospheric REE entering an ombrotrophic peat bog in Black Forest (SW Germany): Evidence from snow, lichens and mosses

The fate of the Rare Earth Elements (REE) were investigated in different types of archives of atmospheric deposition in the Black Forest, Southern Germany: (1) a 70 cm snow pack collected on the domed part of a raised bog and representing 2 months of snow accumulation, (2) a snow sample collected close to the road about 500 m from the peat bog, (3) two species of lichens and (4) a peat profile representing 400 years of peat accumulation as well as a “preanthropogenic” sample and the living moss layer from the top of the core. REE concentrations in peat are significantly correlated to Ti which is a lithogenic conservative element suggesting that REE are immobile in peat bog environments. Snow, lichens and peat samples show similar PAAS (Post Archean Australian Shale) normalized REE distributions suggesting that the complete atmospheric REE signal is preserved in the peat profile. However, the annual flux of REE accumulated by the peat is ca. 10 times greater than that of the bulk winter flux of REE. This difference probably indicates that the REE concentrations in the snowpack are not representative of the average REE flux over the whole year. Despite the pronounced geological differences between this site (granite host-rock) and a previously studied peat bog in Switzerland (limestone host-rock) similar REE distribution patterns and accumulation rates were found at both sites. Given that both sites confirm an Upper Continental Crust signature, the data suggests both sites are influenced by regional and not local, soil-derived lithogenic aerosols.