Seleniferous minerals of palladium and platinum from ouro preto-bearing mineralisation in Brazil

Foram determinadas as composições químicas e as idades Rb–Sr de mica branca, feldspato potássico e de rochas totais das mineralizações de esmeraldas de Capoeirana e Belmont, de pegmatitos sem esmeraldas e dos gnaisses Borrachudos, Monlevade e Guanhães da região de Nova Era–Itabira–Ferros (Minas Gerais, Brazil). Os gnaisses graníticos Borrachudos, os gnaisses bandados Monlevade, seus respectivos pegmatitos e veios/schlieren pegmatóides, e os gnaisses Guanhães, adquiriram suas texturas e composições mineralógicas atuais há cerca de 1.9 Ga no contexto do evento Transamazônico.As rochas regionais encaixantes típicas das ocorrências de esmeraldas são os gnaisses Monlevade que pertencem a uma sequência metavulcano-sedimentar de tipo greenstone belt. O evento principal de formação de esmeraldas em Belmont e Capoeirana foi uma reação metassomática dos pegmatitos anatéticos ricos em Be com rochas ultrabásicas ricas em Cr durante o evento Transamazônico em torno de 1.9 Ga. Em Capoeirana nesse contexto os pegmatitos com feldspato potássico ricos em Be foram transformados em rochas de plagioclasio–quartzo. As idades Rb–Sr de cerca de 480 Ma de minerais das mineralizações de esmeralda resultaram da reequilibração de biotitas e feldspatos Transamazônicos durante o evento Brasiliano.Os pegmatitos não-metamórficos e sem esmeralda da região estudada foram formados no evento Brasiliano há 477±14 Ma. O grau de diferenciação dos pegmatitos, estudado em diagramas indicadores específicos como por exemplo Cs vs. K/Rb de micas brancas e feldspatos potássicos, varia desde pegmatitos cerámicos até muscovita-pegmatitos, à pegmatitos de metais raros e até berilíferos. Alguns dos pegmatitos apresentam marcante diferenciação interna.

Late Holocene hydrologic changes in northern New Zealand inferred from stable isotope values of aquatic cellulose in sediments from Lake Pupuke

Isotopic records of aquatic cellulose are becoming increasingly important for palaeohydrological reconstructions, but widespread application of this climate proxy is hampered by minerogenic contamination that affects oxygen isotope measures in cellulose. Few records of isotopes in aquatic cellulose are available from palaeoclimate archives in the Southern Hemisphere. In this study, we used a new bulk cellulose extraction method and determined the oxygen (δ¹⁸O) and carbon (δ¹³C) isotope values in cellulose from a Holocene lake sediment core segment (7.2–1.1 cal ka BP) from Lake Pupuke, Auckland, New Zealand. Isotope values from modern, potential sources of sedimentary cellulose revealed the aquatic origin of the cellulose extracted from the core, and hence enabled inference of past lake water δ¹⁸O values from the δ¹⁸O of measured cellulose in the core. A shift to a more positive water balance in the lake was identified around 2.8 cal ka BP by a decrease in inferred lake water δ¹⁸O values. At that time, greater epilimnetic primary productivity is indicated by the higher δ¹³C values of sedimentary cellulose. Greater divergence between the δ¹³C values of cellulose and bulk organic matter suggests stronger stratification of the lake, likely caused by greater freshwater input. We discuss a possible link to a solar minimum that occurred at that time.     

Web-based 4D visualization of marine geo-data using WebGL

For marine logistics and maintenance of extensive and expensive marine engineering projects in the coastal zone, it is essential that institutions provide the public with relevant information in an easily understandable yet comprehensive manner over the web. A perennial challenge, however, has been the development of spatio-temporal (four-dimensional (4D)) geo-visualization algorithms to enable the integration of time-varying geo-information in map-based visualizations on the Internet. In this paper, we address the challenge of visualizing marine spatial data in web-based applications through a 4D visualization concept, focusing on usability criteria, performance parameters, the required implementation effort, and delivering a breath of spatial information that supports decision-making on multiple levels. We used Web Graphic Library (WebGL) to validate our concept through a prototypical implementation. In our technology evaluation, WebGL proved highly suitable for the development of interactive, responsive, efficient, and mobile web-based Geographic Information applications, including 2D, 3D, and 4D (spatiotemporal) content. During our research, we identified a number of open research questions, including mapping graphic variables to thematic expressivity, representation of the time dimension in 4D systems, generic temporal generalization, and integration of (pseudo-)photorealistic illustrations in web-based geo-visualization systems.     

Future mitigation commitments: differentiating among non-Annex I countries

Abstract

In the long term, any definition of adequacy consistent with UNFCCC Article 2 will require increased mitigation efforts from almost all countries. Therefore, an expansion of emission limitation commitments will form a central element of any future architecture of the climate regime. This expansion has two elements: deepening of quantitative commitments for Annex B countries and the adoption of commitments for those countries outside of the current limitation regime. This article seeks to provide a more analytical basis for further differentiation among non-Annex I countries. To be both fair and reflective of national circumstances, it is based on the criteria of responsibility, capability and potential to mitigate. Altogether, non-Annex I countries were differentiated in four groups, each including countries with similar national circumstances: newly industrialized countries (NICs), rapidly industrializing countries (RIDCs), ‘other developing countries’, and least developed countries (LDCs). Based on the same criteria that were used for differentiating among non-Annex I countries, a set of decision rules was developed to assign mitigation and financial transfer commitments to each group of countries (including Annex I countries). Applying these decision rules results in (strict) reduction commitments for Annex I countries, but also implies quantifiable mitigation obligations for NICs and RIDCs, assisted by financial transfers from the North. Other developing countries are obliged to take qualitative commitments, but quantifiable mitigation commitments for these countries and the LDC group would be not justifiable. As national circumstances in countries evolve over time, the composition of the groups will change according to agreed triggers.     

Experimental reactions between olivine and orthopyroxene with phonolite melt: implications for the origins of hydrous amphibole + phlogopite + diopside bearing metasomatic veins

Amphibole + phlogopite + diopside bearing veins are observed in a large number of upper mantle xenoliths, but the composition of the melt that forms them is poorly constrained. Recent data from the Heldburg Phonolite, Central Germany, has shown that phonolite melt will react with olivine and orthopyroxene xenocrysts to form reaction rims of amphibole + phlogopite + diopside at mid-lower crustal pressures. This is the first example of where a melt has reacted with peridotite to form the mineralogy of the metasomatic veins. It is therefore necessary to explore whether a phonolite melt could be the parent melt that forms amphibole + phlogopite + diopside metasomatic veins. Experimental reactions between single crystals of olivine and orthopyroxene with phonolite melt were conducted at upper mantle conditions of 1.0–1.5 GPa and 900–1,000 °C. Melt water contents were varied from anhydrous to >12 wt. H₂O. Olivine reacts to form phlogopite reaction rims with overgrowths of diopside <1,000 °C or rims of secondary olivine >1,000 °C. Orthopyroxene reacts to form amphibole with epitaxial diopside overgrowths <1,000 °C. No reaction rims form when the bulk melt H₂O is lower than ~3.8 wt%. Pressure has little effect over the small range tested. These experiments reproduce reaction rims on olivine and orthopyroxene observed in the Heldburg Phonolite, Central Germany, and suggest that a relatively narrow range of temperatures and melt water contents is required for rim formation. The compositions of rim amphibole, phlogopite and diopside from the experiments have very similar compositions to those from Heldburg but do not match those from metasomatic veins. Phenocrysts from Heldburg are similar to the metasomatic veins, suggesting that a phonolite could potentially form the veins if vein formation is dominated by crystallization rather than reaction and replacement of wall rock phases.     

Characterization and sources of extractable organic matter from sediment cores of an urban lake (Tasik Perdana), Kuala Lumpur,Malaysia

The extractable organic matter of sediment samples from six sampling sites in Lake Perdana, Kuala Lumpur, was analyzed to characterize the source inputs. The analysis of aliphatic homologous series indicated that terrestrial higher plant waxes can be assigned as the major sources of the identified aliphatic components in the lake sediments. The presence of an unresolved complex mixture of branched and cyclic compounds and a series of hopanes ranging from C₂₇ to C₃₅ reflected the contamination by petroleum residues from urban vehicular emissions brought in by runoff and fallout. The steroids present included stenols and stanols and showed an input of organic matter from higher plants. The detected pentacyclic triterpenoids comprised oleanane, ursane, lupane and friedelane skeletons including unsaturated oxygenated, mono-, di- and triaromatic counterparts. They are recognized as biomarkers for angiosperms. The presence of des-A-triterpenoids and their aromatized derivatives as the major diagenetic products of triterpenoids reflected the degradation of natural organic matter in the sediments occurring under mainly anoxic conditions. In addition, the presence of tetrahymanol and ββ-bishomohopan-32-ol indicated a minor algal/plankton and bacterial input to the sediments.