Resin diterpenoids as tracers for biomass combustion aerosols

Diterpenoids present in atmospheric particles produced by slash burns were analyzed by capillary gas chromatography-mass spectrometry. This suite of compounds, originating in the resinous higher plants which were combusted, was comprised of reaction intermediates in the thermal transformation sequence of components such as abietic acid and dehydroabietin to retene. This sequence parallels the diagenetic alteration/decomposition processes noted in sedimentary records. Since global transport of combustion aerosols has been well documented, it is likely that the thermally-altered diterpenoids elucidated in this study can be deposited directly to sedimentary sinks.     

Floodplain sediments on the divide between Huang He and Chang Jiang,Gansu Province,NW China

At Lingfeng, (34°17'N, 104°08'E) on the northern slopes of the Qinling Mountains, a stratigraphic survey was made of a 21-m-profile of floodplain sediments on the watershed between the Chang Jiang (Yangtze River) and Huang He (Yellow River) at 2500 m above sea level. The sediments contain <2 m thick layers of peat and detritical plant matter that had been deposited on the floodplain of the Langouhe. If the radiometric dates are reliable, the chronology of the site spans some 80,000 years, covering an accumulation process from the terminal Last Interglacial up to <24 ka BP. The phase >73 ka BP had cool and wet conditions with a coniferous forest vegetation. Between 73 ka and > 40 ka colder and drier conditions were likely. The vegetation changed from aPicea-Pinus forest to aPicea-Abies-Larix forest with a later increase of non-arboreal pollen. Around 40 ka the climate was warm and moist. The accumulation of silt and organic matter as well as the development of a mixed coniferous forest with high rates of thermophilous trees(Quercus, Castanea) characterize the interstadial conditions at this time. Later on, the climate changed to cool and moist conditions, evidenced by silt and peat accumulation and a coniferous forest vegetation up to <24 ka BP. The loess in this area was deposited after 24 ka and erosion by the tributaries of Chang Jiang and Huang He to a depth of at least 40 m created the watershed between the two river systems.     

Age of intrusion and rapid cooling of the Frankenstein gabbro (Odenwald,SW-Germany) evidenced by40Ar/39Ar and single-zircon207Pb/206Pb measurements

The Frankenstein gabbro complex in the northern Odenwald/FR Germany is one of the Hercynian plutonic bodies of the Saxothuringian zone in the Variscan belt.⁸⁷Sr/⁸⁶Sr isotopic investigations on pyroxene,⁴⁰Ar/³⁹Ar age determinations on hornblendes, plagioclases, biotites and pyroxenes and²⁰⁷Pb/²⁰⁶Pb dating on single zircon crystals have been carried out. The⁸⁷Sr/⁸⁶Sr initial ratio of the gabbro (0.70380) indicates uncontaminated derivation of the magma from the mantle. The results on hornblendes, plagioclases and zircons establish the isotopic age of intrusion and the mode of cooling. Pyroxene and biotite data indicate disturbed K-Ar systems of these minerals. The average ages of the hornblendes (363±7 Ma), of the plagioclases (359±3 Ma) and of the zircons (362 ±9 Ma) agree within the 1-sigma levels and constrain the early history of the plutonic intrusion at the turn from Devonian to Carboniferous times. These minerals must have been cooled below their closure temperatures within a time-interval shorter than the error margins of 10 Ma. The ages therefore are, unlike those of the neighbouring Bergsträßer Odenwald, not long-time cooling ages due to largescale and slow geological uplift of the crustal segment. Instead, they will closely estimate the time of intrusion of the Frankenstein pluton into a shallow crustal level. The hiatus of about 20 Ma compared to the average ages of the crystalline rocks of the Bergsträßer Odenwald in the south characterizes the mafic Frankenstein pluton as a separated unit of the Odenwald crystalline, and underlines the importance of the Carboniferous tectonic fault zone in-between. The present data set clearly demonstrates the importance of the applied combination of methods and techniques to constrain the history of intrusion and cooling of mafic plutonic rocks.     

Molecular composition and chemosystematic aspects of Cretaceous amber from the Amazonas,Araripe and Recôncavo basins,Brazil

Amber occurrences in Brazil are rare. In this regard, the molecular composition of three such fossil resin samples from Brazilian Cretaceous sedimentary basins has been analyzed to determine the botanical origin of the resins. The samples were collected from the Amazonas (Alter do Chão Formation), Araripe (Santana Formation, Crato Member) and Recôncavo (Maracangalha Formation, Caruaçu Member) basins. The mono-, sesqui- and diterpenoids in the extracts were used as chemosystematic markers when compared with terpenoids in extant conifers. The compounds were mainly diterpenoids and their degradation products from the labdane, podocarpane, pimarane and isopimarane classes, in addition to paraffins, methoxyphenols and carboxylic acids. Tetracyclic diterpenoids such as phyllocladane, kaurenol and kauranol were also present. The biomarker compositions are certainly typical for conifers and, given the absence of triterpenoids and diterpenoids such as ozic acid, angiosperms can be excluded as a botanical source. The absence of phenolic diterpenoids (ferruginol, totarol) and their derivatives excludes podocarpaceous affinities for the ambers from the Amazonas and Araripe basins. The fossil records of the embedding sediments (e.g. Araucariaceae pollen and leaves) support the proposal of an Araucariacae origin for these ambers, but Cupressaceae and Cheirolepidiaceae cannot be excluded. On the other hand, the presence of phyllocladane and kaurane derivatives is evidence for Araucariaceae or Podocarpaceae origins for the amber from the Recôncavo basin, but Cupressaceae cannot be excluded.     

Orthopyroxene rim growth between olivine and quartz at low temperatures (750–950°C) and low water concentration

Orthopyroxene reaction rims were synthesized between polished plates of natural olivine or synthetic forsterite and quartz at 1.9 GPa and temperatures of 750–950°C. The experiments were performed in a piston-cylinder apparatus after drying the samples at 600°C. Each experiment comprised 4 or 7 quartz-olivine contacts that were positioned along a temperature gradient. As a monitor for water content in the samples, the water concentration in the two olivines was determined by FTIR before and after the experiments. The orthopyroxene layers show two different structural variants. Type one (normal layers) has very constant thickness at each contact and formed with equal growth rates at both interfaces. Type two (bulging layers) comprises more irregular areas with 3–5 times thicker rims where porosity provides evidence for the local presence of a fluid. In the bulging layers the growth rate at the olivine-orthopyroxene interface exceeds that at the quartz-orthopyroxene interface. The relative growth rates at the interfaces are in accordance with SiO₂-immobile growth of the normal layers and SiO₂-mobile growth of the bulging layers. The natural olivine contains about 60 wt-ppm intracrystalline water before and after experiment and took up about 20 wt-ppm water molecular adsorbed to micro- and nanocracks and -pores during the runs. The synthetic forsterite contains about 7 wt-ppm internally adsorbed molecular water before and after experiment, and during the runs took up hydrogen equivalent to 3 wt-ppm adsorbed water. The IR spectra indicate that large parts of the point defects (possibly tetrahedral) were frozen-in at the conditions of the experiments. In both olivines a new band appeared at 3,355 or 3,357 cm^?1, respectively, equivalent to about 3 wt-ppm water that at the high pressure of the experiments and opx-buffered aSiO₂ of the experiments might already mean water saturation of the olivines. Despite the effective drying before experiment and the absence of porosity, the bulk diffusivity derived from the rim growth rates is perfectly in line with data from water-bearing piston-cylinder experiments at higher temperatures. The bulk diffusivity during rim growth is 4 to 7 orders of magnitude higher than an extrapolation of really dry experiments to the temperature range of this study.     

Geomorphological evidence for the Late Holocene evolution and the Holocene lake level maximum of the Aral Sea

During the Holocene the Aral Sea underwent various transgressive and regressive phases of different magnitudes. However, previous work has not yet fully clarified the evolution and chronology of the individual phases. Research presented here throws light on the evolution of the Aral Sea during the past  2000 years. It includes field surveys, tachymetric and DGPS-derived altitude measurements, analysis of sediments from two areas of the northern and southern Aral Basin (Tastubek Bay and Karaumbet Bay), and their correlation with GIS-based lake area models. Geomorphological and sedimentological evidence from the study areas shows a transgression of the Aral Sea around 200 AD, ending at a lake level maximum of 54 to 55 m. After a medieval regression, the lake reached this level again between the late 16th and early 19th century AD. The digital elevation model SRTM-3 was used to estimate a lake size of 72,400 km² for the lake level maximum.Elevated palaeoshorelines, specifically at 72–73 m, are completely absent in the study areas. Local remains of escarpments at elevations of 66 m and 73 m are due to resistant Miocene caprock and are therefore not interpretable as shoreline features.     

Multiphase flow above explosion sites in debris-filled volcanic vents: Insights from analogue experiments

Discrete explosive bursts are known from many volcanic eruptions. In maar–diatreme eruptions, they have occurred in debris-filled volcanic vents when magma interacted with groundwater, implying that material mobilized by such explosions passed through the overlying and enclosing debris to reach the surface. Although other studies have addressed the form and characteristics of craters formed by discrete explosions in unconsolidated material, no details are available regarding the structure of the disturbed debris between the explosion site and the surface. Field studies of diatreme deposits reveal cross-cutting, steep-sided zones of non-bedded volcaniclastic material that have been inferred to result from sedimentation of material transported by “debris jets” driven by explosions. In order to determine the general processes and deposit geometry resulting from discrete, explosive injections of entrained particles through a particulate host, we ran a series of analogue experiments. Specific volumes of compressed (0.5–2.5 MPa) air were released in bursts that drove gas-particle dispersions through a granular host. The air expanded into and entrained coloured particles in a small crucible before moving upward into the host (white particles). Each burst drove into the host an expanding cavity containing air and coloured particles. Total duration of each run, recorded with high-speed video, was approximately 0.5–1 s. The coloured beads sedimented into the transient cavity. This same behaviour was observed even in runs where there was no breaching of the surface, and no coloured beads ejected. A steep-sided body of coloured beads was left that is similar to the cross-cutting pipes observed in deposits filling real volcanic vents, in which cavity collapse can result not only from gas escape through a granular host as in the experiments, but also through condensation of water vapour. A key conclusion from these experiments is that the geometry of cross-cutting volcaniclastic deposits in volcanic vents is not directly informative of the geometry of the “intrusions” that formed them. An additional conclusion is that complex structures can form quickly from discrete events.     

Ten Years of Development of Equipment for Measurement of Atmospheric Radioactive Xenon for the Verification of the CTBT

Atmospheric measurement of radioactive xenon isotopes (radioxenon) plays a key role in remote monitoring of nuclear explosions, since it has a high capability to capture radioactive debris for a wide range of explosion scenarios. It is therefore a powerful tool in providing evidence for nuclear testing, and is one of the key components of the verification regime of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The reliability of this method is largely based on a well-developed measurement technology. In the 1990s, with the prospect of the build-up of a monitoring network for the CTBT, new development of radioxenon equipment started. This article summarizes the physical and technical principles upon which the radioxenon technology is based and the advances the technology has undergone during the last 10 years. In contrast to previously used equipment, which was manually operated, the new generation of radioxenon monitoring equipment is designed for automated and continuous operation in remote field locations. Also the analytical capabilities of the equipment were strongly enhanced. Minimum detectable concentrations of the recently developed systems are well below 1 mBq/m³ for the key nuclide ¹³³Xe for sampling periods between 8 and 24 h. All the systems described here are also able to separately measure with low detection limits the radioxenon isotopes ^131mXe, ^133mXe and ¹³⁵Xe, which are also relevant for the detection of nuclear tests. The equipment has been extensively tested during recent years by operation in a laboratory environment and in field locations, by performing comparison measurements with laboratory type equipment and by parallel operation. These tests demonstrate that the equipment has reached a sufficiently high technical standard for deployment in the global CTBT verification regime.     

Meltwater and the global ocean conveyor: northern versus southern connections

The sensitivity of the ocean circulation to changes in North Atlantic surface fluxes has become a major factor in explaining climate variability. The role of the Antarctic Bottom Water in modulating this variability has received much less attention, limiting the development of a complete understanding of decadal to millennial time-scale climate change. New analyses indicate that the southern deepwater source may change dramatically (e.g., experience a decrease of as much as two thirds during last 800 years). Such change can substantially alter the ocean circulation patterns of the last millennium. Additional analyses indicate that the Southern Hemisphere led the Northern Hemisphere changes in some of the glacial cycles of Pleistocene, implying a seesaw-type oscillation of the global ocean conveyor. The potential for melting of sea ice and ice sheets in the Antarctica associated with global warming can cause a further slowdown of the southern deepwater source. These results demand an assessment of the role of the Southern Ocean in driving changes of the global ocean circulation and climate. Systematic model simulation targeting the ocean circulation response to changes in surface salinity in the high latitudes of both Northern and Southern Hemispheres demonstrate that meltwater impacts in one hemisphere may lead to a strengthening of the thermohaline conveyor driven by the source in the opposite hemisphere. This, in turn, leads to significant changes in poleward heat transport. Further, meltwater events can lead to deep-sea warming and thermal expansion of abyssal water, that in turn cause a substantial sea-level change even without a major ice sheet melting.