Late Holocene hydrologic changes in northern New Zealand inferred from stable isotope values of aquatic cellulose in sediments from Lake Pupuke

Isotopic records of aquatic cellulose are becoming increasingly important for palaeohydrological reconstructions, but widespread application of this climate proxy is hampered by minerogenic contamination that affects oxygen isotope measures in cellulose. Few records of isotopes in aquatic cellulose are available from palaeoclimate archives in the Southern Hemisphere. In this study, we used a new bulk cellulose extraction method and determined the oxygen (δ¹⁸O) and carbon (δ¹³C) isotope values in cellulose from a Holocene lake sediment core segment (7.2–1.1 cal ka BP) from Lake Pupuke, Auckland, New Zealand. Isotope values from modern, potential sources of sedimentary cellulose revealed the aquatic origin of the cellulose extracted from the core, and hence enabled inference of past lake water δ¹⁸O values from the δ¹⁸O of measured cellulose in the core. A shift to a more positive water balance in the lake was identified around 2.8 cal ka BP by a decrease in inferred lake water δ¹⁸O values. At that time, greater epilimnetic primary productivity is indicated by the higher δ¹³C values of sedimentary cellulose. Greater divergence between the δ¹³C values of cellulose and bulk organic matter suggests stronger stratification of the lake, likely caused by greater freshwater input. We discuss a possible link to a solar minimum that occurred at that time.     

Web-based 4D visualization of marine geo-data using WebGL

For marine logistics and maintenance of extensive and expensive marine engineering projects in the coastal zone, it is essential that institutions provide the public with relevant information in an easily understandable yet comprehensive manner over the web. A perennial challenge, however, has been the development of spatio-temporal (four-dimensional (4D)) geo-visualization algorithms to enable the integration of time-varying geo-information in map-based visualizations on the Internet. In this paper, we address the challenge of visualizing marine spatial data in web-based applications through a 4D visualization concept, focusing on usability criteria, performance parameters, the required implementation effort, and delivering a breath of spatial information that supports decision-making on multiple levels. We used Web Graphic Library (WebGL) to validate our concept through a prototypical implementation. In our technology evaluation, WebGL proved highly suitable for the development of interactive, responsive, efficient, and mobile web-based Geographic Information applications, including 2D, 3D, and 4D (spatiotemporal) content. During our research, we identified a number of open research questions, including mapping graphic variables to thematic expressivity, representation of the time dimension in 4D systems, generic temporal generalization, and integration of (pseudo-)photorealistic illustrations in web-based geo-visualization systems.     

Future mitigation commitments: differentiating among non-Annex I countries

Abstract

In the long term, any definition of adequacy consistent with UNFCCC Article 2 will require increased mitigation efforts from almost all countries. Therefore, an expansion of emission limitation commitments will form a central element of any future architecture of the climate regime. This expansion has two elements: deepening of quantitative commitments for Annex B countries and the adoption of commitments for those countries outside of the current limitation regime. This article seeks to provide a more analytical basis for further differentiation among non-Annex I countries. To be both fair and reflective of national circumstances, it is based on the criteria of responsibility, capability and potential to mitigate. Altogether, non-Annex I countries were differentiated in four groups, each including countries with similar national circumstances: newly industrialized countries (NICs), rapidly industrializing countries (RIDCs), ‘other developing countries’, and least developed countries (LDCs). Based on the same criteria that were used for differentiating among non-Annex I countries, a set of decision rules was developed to assign mitigation and financial transfer commitments to each group of countries (including Annex I countries). Applying these decision rules results in (strict) reduction commitments for Annex I countries, but also implies quantifiable mitigation obligations for NICs and RIDCs, assisted by financial transfers from the North. Other developing countries are obliged to take qualitative commitments, but quantifiable mitigation commitments for these countries and the LDC group would be not justifiable. As national circumstances in countries evolve over time, the composition of the groups will change according to agreed triggers.     

Experimental reactions between olivine and orthopyroxene with phonolite melt: implications for the origins of hydrous amphibole + phlogopite + diopside bearing metasomatic veins

Amphibole + phlogopite + diopside bearing veins are observed in a large number of upper mantle xenoliths, but the composition of the melt that forms them is poorly constrained. Recent data from the Heldburg Phonolite, Central Germany, has shown that phonolite melt will react with olivine and orthopyroxene xenocrysts to form reaction rims of amphibole + phlogopite + diopside at mid-lower crustal pressures. This is the first example of where a melt has reacted with peridotite to form the mineralogy of the metasomatic veins. It is therefore necessary to explore whether a phonolite melt could be the parent melt that forms amphibole + phlogopite + diopside metasomatic veins. Experimental reactions between single crystals of olivine and orthopyroxene with phonolite melt were conducted at upper mantle conditions of 1.0–1.5 GPa and 900–1,000 °C. Melt water contents were varied from anhydrous to >12 wt. H₂O. Olivine reacts to form phlogopite reaction rims with overgrowths of diopside <1,000 °C or rims of secondary olivine >1,000 °C. Orthopyroxene reacts to form amphibole with epitaxial diopside overgrowths <1,000 °C. No reaction rims form when the bulk melt H₂O is lower than ~3.8 wt%. Pressure has little effect over the small range tested. These experiments reproduce reaction rims on olivine and orthopyroxene observed in the Heldburg Phonolite, Central Germany, and suggest that a relatively narrow range of temperatures and melt water contents is required for rim formation. The compositions of rim amphibole, phlogopite and diopside from the experiments have very similar compositions to those from Heldburg but do not match those from metasomatic veins. Phenocrysts from Heldburg are similar to the metasomatic veins, suggesting that a phonolite could potentially form the veins if vein formation is dominated by crystallization rather than reaction and replacement of wall rock phases.     

Characterization and sources of extractable organic matter from sediment cores of an urban lake (Tasik Perdana), Kuala Lumpur,Malaysia

The extractable organic matter of sediment samples from six sampling sites in Lake Perdana, Kuala Lumpur, was analyzed to characterize the source inputs. The analysis of aliphatic homologous series indicated that terrestrial higher plant waxes can be assigned as the major sources of the identified aliphatic components in the lake sediments. The presence of an unresolved complex mixture of branched and cyclic compounds and a series of hopanes ranging from C₂₇ to C₃₅ reflected the contamination by petroleum residues from urban vehicular emissions brought in by runoff and fallout. The steroids present included stenols and stanols and showed an input of organic matter from higher plants. The detected pentacyclic triterpenoids comprised oleanane, ursane, lupane and friedelane skeletons including unsaturated oxygenated, mono-, di- and triaromatic counterparts. They are recognized as biomarkers for angiosperms. The presence of des-A-triterpenoids and their aromatized derivatives as the major diagenetic products of triterpenoids reflected the degradation of natural organic matter in the sediments occurring under mainly anoxic conditions. In addition, the presence of tetrahymanol and ββ-bishomohopan-32-ol indicated a minor algal/plankton and bacterial input to the sediments.     

Determining hydrological regimes in an agriculturally used tropical inland valley wetland in Central Uganda using soil moisture,groundwater, and digital elevation data

Inadequate knowledge exists on the distribution of soil moisture and shallow groundwater in intensively cultivated inland valley wetlands in tropical environments, which are required for determining the hydrological regime. This study investigated the spatial and temporal variability of soil moisture along 4 hydrological positions segmented as riparian zone, valley bottom, fringe, and valley slope in an agriculturally used inland valley wetland in Central Uganda. The determined hydrological regimes of the defined hydrological positions are based on soil moisture deficit calculated from the depth to the groundwater table. For that, the accuracy and reliability of satellite‐derived surface models, SRTM‐30m and TanDEM‐X‐12m, for mapping microscale topography and hydrological regimes are evaluated against a 5‐m digital elevation model (DEM) derived from field measurements. Soil moisture and depth to groundwater table were measured using frequency domain reflectometry sensors and piezometers installed along the hydrological positions, respectively. Results showed that spatial and temporal variability in soil moisture increased significantly (p < .05) towards the riparian zone; however, no significant difference was observed between the valley bottom and riparian zone. The distribution of soil hydrological regimes, saturated, near‐saturated, and nonsaturated regimes does not correlate with the hydrological positions. This is due to high spatial and temporal variability in depth to groundwater and soil moisture content across the valley. Precipitation strongly controlled the temporal variability, whereas microscale topography, soil properties, distance from the stream, anthropogenic factors, and land use controlled the spatial variability in the inland valley. TanDEM‐X DEM reasonably mapped the microscale topography and thus soil hydrological regimes relative to the Shuttle Radar Topography Mission DEM. The findings of the study contribute to improved understanding of the distribution of hydrological regimes in an inland valley wetland, which is required for a better agricultural water management planning.     

On the error analyses of polarization measurements of the white-light coronagraph aboard ASO-S

The Advanced Space-based Solar Observatory(ASO-S) mission aims to explore the two most spectacular eruptions on the Sun: solar flares and coronal mass ejections(CMEs), and their magnetism.For the study of CMEs, the payload Lyman-alpha Solar Telescope(LST) has been proposed. It includes a traditional white-light coronagraph and a Lyman-alpha coronagraph which opens a new window to CME observations. Polarization measurements taken by white-light coronagraphs are crucial for deriving fundamental physical parameters of CMEs. To make such measurements, there are two options for a Stokes polarimeter which have been applied by existing white-light coronagraphs for space missions. One uses a single or triple linear polarizer, the other involves both a half-wave plate and a linear polarizer. We find that the former option is subject to less uncertainty in the derived Stokes vector propagating from detector noise.The latter option involves two plates which are prone to internal reflections and may have a reduced transmission factor. Therefore, the former option is adopted as our Stokes polarimeter scheme for LST. Based on the parameters of the intended linear polarizer(s) colorPol provided by CODIXX and the half-wave plate 2-APW-L2-012 C by Altechna, it is further shown that the imperfect maximum transmittance of the polarizer significantly increases the variance amplification of Stokes vector by at least about 50% when compared with the ideal case. The relative errors of Stokes vector caused by the imperfection of colorPol polarizer and the uncertainty due to the polarizer assembly in the telescope are estimated to be about 5%. Among the considered parameters, we find that the dominant error comes from the uncertainty in the maximum transmittance of the polarizer.     

Catalogue of ${>}\,55$ MeV Wide-longitude Solar Proton Events Observed by SOHO,ACE, and the STEREOs at ≈1${\approx}\,1$ AU During 2009 – 2016

Based on energetic particle observations made at \({\approx}\,1\) AU, we present a catalogue of 46 wide-longitude (\({>}\,45^{\circ}\)) solar energetic particle (SEP) events detected at multiple locations during 2009?–?2016. The particle kinetic energies of interest were chosen as \({>}\,55\) MeV for protons and 0.18?–?0.31 MeV for electrons. We make use of proton data from the Solar and Heliospheric Observatory/Energetic and Relativistic Nuclei and Electron Experiment (SOHO/ERNE) and the Solar Terrestrial Relations Observatory/High Energy Telescopes (STEREO/HET), together with electron data from the Advanced Composition Explorer/Electron, Proton, and Alpha Monitor (ACE/EPAM) and the STEREO/Solar Electron and Proton Telescopes (SEPT). We consider soft X-ray data from the Geostationary Operational Environmental Satellites (GOES) and coronal mass ejection (CME) observations made with the SOHO/Large Angle and Spectrometric Coronagraph (LASCO) and STEREO/Coronagraphs 1 and 2 (COR1, COR2) to establish the probable associations between SEP events and the related solar phenomena. Event onset times and peak intensities are determined; velocity dispersion analysis (VDA) and time-shifting analysis (TSA) are performed for protons; TSA is performed for electrons. In our event sample, there is a tendency for the highest peak intensities to occur when the observer is magnetically connected to solar regions west of the flare. Our estimates for the mean event width, derived as the standard deviation of a Gaussian curve modelling the SEP intensities (protons \({\approx}\,44^{\circ}\), electrons \({\approx}\,50^{\circ}\)), largely agree with previous results for lower-energy SEPs. SEP release times with respect to event flares, as well as the event rise times, show no simple dependence on the observer’s connection angle, suggesting that the source region extent and dominant particle acceleration and transport mechanisms are important in defining these characteristics of an event. There is no marked difference between the speed distributions of the CMEs related to wide events and the CMEs related to all near-Earth SEP events of similar energy range from the same time period.