Seleniferous minerals of palladium and platinum from ouro preto-bearing mineralisation in Brazil

Foram determinadas as composições químicas e as idades Rb–Sr de mica branca, feldspato potássico e de rochas totais das mineralizações de esmeraldas de Capoeirana e Belmont, de pegmatitos sem esmeraldas e dos gnaisses Borrachudos, Monlevade e Guanhães da região de Nova Era–Itabira–Ferros (Minas Gerais, Brazil). Os gnaisses graníticos Borrachudos, os gnaisses bandados Monlevade, seus respectivos pegmatitos e veios/schlieren pegmatóides, e os gnaisses Guanhães, adquiriram suas texturas e composições mineralógicas atuais há cerca de 1.9 Ga no contexto do evento Transamazônico.As rochas regionais encaixantes típicas das ocorrências de esmeraldas são os gnaisses Monlevade que pertencem a uma sequência metavulcano-sedimentar de tipo greenstone belt. O evento principal de formação de esmeraldas em Belmont e Capoeirana foi uma reação metassomática dos pegmatitos anatéticos ricos em Be com rochas ultrabásicas ricas em Cr durante o evento Transamazônico em torno de 1.9 Ga. Em Capoeirana nesse contexto os pegmatitos com feldspato potássico ricos em Be foram transformados em rochas de plagioclasio–quartzo. As idades Rb–Sr de cerca de 480 Ma de minerais das mineralizações de esmeralda resultaram da reequilibração de biotitas e feldspatos Transamazônicos durante o evento Brasiliano.Os pegmatitos não-metamórficos e sem esmeralda da região estudada foram formados no evento Brasiliano há 477±14 Ma. O grau de diferenciação dos pegmatitos, estudado em diagramas indicadores específicos como por exemplo Cs vs. K/Rb de micas brancas e feldspatos potássicos, varia desde pegmatitos cerámicos até muscovita-pegmatitos, à pegmatitos de metais raros e até berilíferos. Alguns dos pegmatitos apresentam marcante diferenciação interna.

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur,Malaysia

The concentrations of n-alkanes, unresolved complex mixture (UCM), petroleum molecular markers, other tracers of cooking and burning emissions, and natural background in atmospheric particles and roadside dust particles were measured at eight locations in the city center and the suburbs of Kuala Lumpur, Malaysia. Atmospheric particles were collected using high-volume filtration (PM-10, GFF) over 24 h average periods. Road dusts were swept up, dried and sieved. Both types of samples were extracted with dichloromethane/methanol mixture (3:1 v/v) by ultrasonic agitation. The extracts were then fractionated by column chromatography and the alkanes subjected to gas chromatography–mass spectrometry (GC–MS). Total extracts were also analyzed directly by GC–MS after silylation. The molecular distributions of compounds as well as diagnostic geochemical ratios were determined in order to identify the sources of the organic compounds. Samples collected from a rural area and lubricating oils were also analyzed for comparisons. Anthropogenic and biogenic sources such as vehicular emissions, waxes of higher plants, food cooking operations, and biomass and domestic refuse burning processes contributed to the organic matter content of atmospheric and to lesser extent, roadside dust particles.     

Ten Years of Development of Equipment for Measurement of Atmospheric Radioactive Xenon for the Verification of the CTBT

Atmospheric measurement of radioactive xenon isotopes (radioxenon) plays a key role in remote monitoring of nuclear explosions, since it has a high capability to capture radioactive debris for a wide range of explosion scenarios. It is therefore a powerful tool in providing evidence for nuclear testing, and is one of the key components of the verification regime of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). The reliability of this method is largely based on a well-developed measurement technology. In the 1990s, with the prospect of the build-up of a monitoring network for the CTBT, new development of radioxenon equipment started. This article summarizes the physical and technical principles upon which the radioxenon technology is based and the advances the technology has undergone during the last 10 years. In contrast to previously used equipment, which was manually operated, the new generation of radioxenon monitoring equipment is designed for automated and continuous operation in remote field locations. Also the analytical capabilities of the equipment were strongly enhanced. Minimum detectable concentrations of the recently developed systems are well below 1 mBq/m³ for the key nuclide ¹³³Xe for sampling periods between 8 and 24 h. All the systems described here are also able to separately measure with low detection limits the radioxenon isotopes ^131mXe, ^133mXe and ¹³⁵Xe, which are also relevant for the detection of nuclear tests. The equipment has been extensively tested during recent years by operation in a laboratory environment and in field locations, by performing comparison measurements with laboratory type equipment and by parallel operation. These tests demonstrate that the equipment has reached a sufficiently high technical standard for deployment in the global CTBT verification regime.