Mobility and potential bioavailability of traffic-derived trace metals in a ‘wet–dry’ tropical region,Northern Australia

The aqueous mobility and potential bioavailability of metals and metalloids in road runoff in a ‘wet–dry’ tropical location were assessed by analysing metal and metalloid concentrations in particulate, total dissolved and labile dissolved phases in runoff waters. Road-derived Al, Cu, Pb, Sb and Zn concentrations were substantially elevated in runoff when compared to receiving creek waters. Median dissolved concentrations in road runoff exceeded those in creek waters by up to an order of magnitude. Leaching experiments of road sediments confirmed that several metals and metalloids were released in high concentrations from road sediments. Labile Zn and Cu concentrations measured by diffusion gradients in thin films (DGT) showed that almost all dissolved Zn and up to half of dissolved Cu in runoff waters and in road sediment leachate were potentially bioavailable. Comparisons of dissolved metal concentrations in receiving waters affected by road runoff with ecosystem guideline levels, indicated a risk of reaching toxic levels of Cu and Zn in the receiving waters in the absence of adequate treatment or dilution. Low dilution rates of road runoff are likely to occur during late ‘dry’ season/early ‘wet’ season storms which have the potential to produce high metal concentrations derived from long periods of accumulation of road sediment at a time when creek flow rates are at their annual minimum.     

2D and 3D Polar Plume Analysis from the Three Vantage Positions of STEREO/EUVI A, B, and SOHO/EIT

Polar plumes appear as elongated objects starting at the solar polar regions. Here we analyze these objects from a sequence of images taken simultaneously by the three spacecraft telescopes STEREO/EUVI A and B, and SOHO/EIT. We establish a method capable of automatically identifying plumes in solar EUV images close to the limb at 1.01?–?1.39?R _⊙ in order to study their temporal evolution. This plume-identification method is based on a multiscale Hough-wavelet analysis. Then two methods to determine the 3D localization and structure of the plumes are discussed: first, tomography using filtered back-projection and including the differential rotation of the Sun and, second, conventional stereoscopic triangulation. We show that tomography and stereoscopy are complementary for studying polar plumes. We also show that this systematic 2D identification and the proposed methods of 3D reconstruction are well suited to identify plumes individually and also to analyze the distribution of plumes and inter-plume regions. Finally, the results are discussed, focusing on plume position and cross-sectional area.     

Multi-spacecraft Observations of CIR-Associated Ion Increases During the Ulysses 2007 Ecliptic Crossing

The period between 21 June and 8 October, 2007 (Carrington rotations 2058 to 2061), comprising the Ulysses ecliptic plane crossing, was characterized by low solar activity. Excluding the small solar energetic particle events observed during July, the ion increases observed in the inner heliosphere between 100?keV/n and 10?MeV/n were associated with Corotating Interaction Regions (CIRs). In this work, we investigate CIR-related ion increases using multipoint observations from Ulysses, ACE, and the twin STEREO spacecraft. The ballistic backmapping technique has been used to correlate in situ observations of these spacecraft and remote-sensing observations of coronal holes. Although the radial, longitudinal and latitudinal separation of the spacecraft (except Ulysses) are relatively small, we find discrepancies when a detailed comparison of narrow structures like stream interfaces and CIR-associated shocks is performed. Therefore we concentrate on the two CIR events from day 5 to day 10 of August 2007 and from day 25 to day 31 of August 2007, which lend themselves to a more undisturbed comparison. Using the multi-spacecraft measurements we could determine a radial gradient of 230±30% AU^?1, which is consistent with previous results by van Hollebeke et al. (J. Geophys. Res. 83, 4723, 1978) of ～?350% AU^?1 using Helios and Pioneer data.

     

Relative sea level changes during the Holocene in the Sisimiut area,south‐western Greenland

Holocene relative sea level (RSL) changes have been investigated by analysing and dating isolation sequences from five lakes near Sisimiut in south‐western Greenland. The transitions between marine and lacustrine sediments were determined from elemental analyses and analyses of macroscopic plant and animal remains. Radiocarbon dating was used to provide minimum ages for the transitions and to construct a RSL curve. Dating of a shell of the marine bivalve Macoma balthica indicates that deglaciation of the lowlands occurred in the early Holocene, at around 10 900 cal a BP. The RSL curve shows initial rapid regression from the marine limit at around 140 m, implying strong glacio‐isostatic rebound. We suggest that the margin of the Greenland Ice Sheet was located at the shelf break during the Last Glacial Maximum. Frequent remains of the ostracode Sarcypridopsis aculeata, which is a thermophilous brackish water species that is unknown from the extant fauna of Greenland, in one of the basins around 8500 cal a BP may mark the beginning of the Holocene thermal maximum in the region. Copyright © 2011 John Wiley & Sons, Ltd.     

The behaviour of outer radiation belt electrons (> 1·5 MeV) during a geomagnetically disturbed time on 8 March 1970 and its relationship to magnetospheric processes

Omnidirectional intensities of electrons with energies E_e > 1·5 MeV detected by a low orbiting polar satellite (GRS-A/AZUR) in the outer radiation belt are examined during disturbed times including the main phase of a very strong geomagnetic storm on 8 March 1970. The particle intensity features are discussed in relationship with proposed magnetospheric processes. It is found that a superposition of the two following effects can explain the particle behavior in the trapping region:(A) Radial diffusion. After the southward turning of the interplanetary field an inward motion of both the energetic electron belt and the plasmapause took place. This effect was observed at L > 3 R_E and we attribute it to enhanced magnetospheric electric field fluctuations. Later, a strong interplanetary shock impinged upon the magnetosphere which was related to the triggering of intense magnetospheric substorms; a further inward diffusion occurred at L ? 3 R_E, accompanied by an inward movement of the electron slot. A rough estimation of the diffusion coefficient leads to a power spectrum of the electric field fluctuations which seems to be consistent with experimentally determined power spectra (Mozer, 1971).(B) Adiabatic response to ring current changes. Large energetic electron intensity decreases within the outer radiation belt are shown to be adiabatic changes due to ring current variations. The influence of the inflation of the magnetosphere due to the developing ring current is simultaneously observed by the decrease of the solar proton outoff (1·7-2·5 MeV).     

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur,Malaysia

The concentrations of n-alkanes, unresolved complex mixture (UCM), petroleum molecular markers, other tracers of cooking and burning emissions, and natural background in atmospheric particles and roadside dust particles were measured at eight locations in the city center and the suburbs of Kuala Lumpur, Malaysia. Atmospheric particles were collected using high-volume filtration (PM-10, GFF) over 24 h average periods. Road dusts were swept up, dried and sieved. Both types of samples were extracted with dichloromethane/methanol mixture (3:1 v/v) by ultrasonic agitation. The extracts were then fractionated by column chromatography and the alkanes subjected to gas chromatography–mass spectrometry (GC–MS). Total extracts were also analyzed directly by GC–MS after silylation. The molecular distributions of compounds as well as diagnostic geochemical ratios were determined in order to identify the sources of the organic compounds. Samples collected from a rural area and lubricating oils were also analyzed for comparisons. Anthropogenic and biogenic sources such as vehicular emissions, waxes of higher plants, food cooking operations, and biomass and domestic refuse burning processes contributed to the organic matter content of atmospheric and to lesser extent, roadside dust particles.     

Orogenic structure of the Eastern Alps, Europe, from TRANSALP deep seismic reflection profiling

The TRANSALP Group, comprising of partner institutions from Italy, Austria and Germany, acquired data on a 340 km long deep seismic reflection line crossing the Eastern Alps between Munich and Venice. Although the field work was split into four campaigns, between fall 1998 and summer 2001, the project gathered for the first time a continuous profile across the Alps using consistent field acquisition and data processing parameters. These sections span the orogen itself, at its broadest width, as well as the editor Fred Davey and the two adjacent basins. Vibroseis and explosion data, complementary in their depth penetration and resolution characteristics, were obtained along with wide-angle and teleseismic data. The profile shows a bi-vergent asymmetric structure of the crust beneath the Alpine axis which reaches a maximum thickness of 55 km, and 80–100 km long transcrustal ramps, the southward dipping ‘Sub-Tauern-Ramp’ and the northward-dipping ‘Sub-Dolomites-Ramp’. Strongly reflective patterns of these ramps can be traced towards the north to the Inn Valley and towards the south to the Valsugana thrust belt, both of which show enhanced seismicity in the brittle upper crust. The seismic sections do not reveal any direct evidence for the presence of the Periadriatic Fault system, the presumed equivalent to the Insubric Line in the Western Alps. According to our new evolutionary model, the Sub-Tauern-Ramp is linked at depth with remnants of the subducted Penninic Ocean. The ‘crocodile’-type model describes an upper/lower crustal decoupling and wedging of both the European and the Adriatic–African continents.     

Influence of source distance and depth on the branches ofPKP waves

Summary The average dependence of the calibration function q and the travel-time residuals t on the depth and distance of the source has been derived for individual branches of PKP waves using earthquakes from the SW Pacific Ocean (distance interval 147°–159°, depths 0–700 km). The analysis of very distant shocks of all depths according to the regional PKP travel time tables can be completed by the magnitude determination.