Coastal margin evolution and postulated “basin‐shipyard” area at ancient Locri‐Epizephiri,Calabria, Italy

Environmental settings on the Ionian coastal plain and inner shelf seaward of Locri‐Epizephiri in Calabria, Italy, differed markedly before, during, and following settlement by the Greeks. Sediment core analyses and geophysical surveys in this study support recent archaeological findings and the hypothesis that the margin may once have served as a harbor and/or shipyard. The subsurface Holocene stratigraphy records that (1) the shoreline advanced to a maximum landward position before Greek settlement, then regressed offshore to what is now the inner shelf before once again migrating landward. These marked coastal shifts were triggered primarily by land uplift and probable subsidence offshore along this structurally active Calabrian Arc segment. Associated with this are: (2) a sediment fining‐upward sequence in Greek–Roman time that indicates only partial protection of the coastal area, and (3) possible presence of subsurface structures seaward of the city wall in a sector now positioned ∼200 m offshore. © 2010 Wiley Periodicals, Inc.     

Phosphate oxygen isotopes: Insights into sedimentary phosphorus cycling from the Benguela upwelling system

Marine sediments are the main sink in the oceanic phosphorus (P) cycle. The activity of benthic microorganisms is decisive for regeneration, reflux, or burial of inorganic phosphate (P_i), which has a strong impact on marine productivity. Recent formation of phosphorites on the continental shelf and a succession of different sedimentary environments make the Benguela upwelling system a prime region for studying the role of microbes in P biogeochemistry. The oxygen isotope signature of pore water phosphate (δ¹⁸O_P) carries characteristic information of microbial P cycling: Intracellular turnover of phosphorylated biomolecules results in isotopic equilibrium with ambient water, while enzymatic regeneration of P_i from organic matter produces distinct offsets from equilibrium. The balance of these two processes is the major control for δ¹⁸O_P.Our study assesses the importance of microbial P cycling relative to regeneration of P_i from organic matter from a transect across the Namibian continental shelf and slope by combining pore water chemistry (sulfate, sulfide, ferrous iron, P_i), steady-state turnover rate modeling, and oxygen isotope geochemistry of P_i.We found δ¹⁸O_P values in a range from 12.8‰ to 26.6‰, both in equilibrium as well as pronounced disequilibrium with water. Our data show a trend towards regeneration signatures (disequilibrium) under low mineralization activity and low P_i concentrations, and microbial turnover signatures (equilibrium) under high mineralization activity and high P_i concentrations. These findings are opposite to observations from water column studies where regeneration signatures were found to coincide with high mineralization activity and high P_i concentrations. It appears that preferential P_i regeneration in marine sediments does not necessarily coincide with a disequilibrium δ¹⁸O_P signature. We propose that microbial P_i uptake strategies, which are controlled by P_i availability, are decisive for the alteration of the isotope signature. This hypothesis is supported by the observation of efficient microbial P_i turnover (equilibrium signatures) in the phosphogenic sediments of the Benguela upwelling system.     

Sull'analisi periodale dei diagrammi

Riassunto Dopo aver indicato un nuovo artificio per rendere più rapida la formazione di combinazioni selettive nella analisi periodale, si illustra un modello di analizzatore armonico che traduce con mezzi fotoelettrici gli schemi diLabrouste e diVercelli. Infine, si propone una variante costruttiva dell'analizzatore elettrico progettato dalLovera.

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Summary After having showed a new way by which the process for making the selective combinations used for periodical analysis is hastened, an harmonic analysing device which traducts with photoelectric means the schemes ofLabrouste andVercelli is illustrated. Further, a change in the construction ofLovera's electric analyser is proposed.

     

AVO signatures of actual and synthetic reflections from different petrophysical targets1

We use a marine seismic dataset to examine the reflections from two gas sands, a lignitic sand and a cineritic bed, by means of their amplitude versus offset (AVO) responses. This offset-dependent signature is related to specific petrophysical and thus elastic situations or to peculiar interference patterns and may help to distinguish the nature of the amplitude anomalies on the stack sections. The prestack analysis is carried out on seismic data which have undergone an accurate true-amplitude processing. It is found that the lignitic-sand reflections exhibit a decreasing AVO while the two-gas sands show markedly increasing AVO trends. Also the reflections from the cineritic layer show increasing amplitudes with offset that may be due either to the petrophysical nature of the cinerites or to thin-layer interference or to both. In order to verify the reliability of the actual AVO responses we develop a detailed model from well data and compute a synthetic CMP seismogram. In order to account for mode conversions and thin-layer effects, the synthetic seismograms are computed using the reflectivity method. The wavelets used in the synthetics are retrieved from actual seismic and borehole data by means of wavelet processing. When finely layered structures are present, the estimation of a reliable wavelet is extremely important to get the correct synthetic AVO response. In particular, the AVO responses of the cineritic layer differ substantially if we make use in the computation of the synthetics of a Ricker wavelet or of a wavelet estimated through wavelet processing. The good match between the observed and modelled data confirms the reliability of the processing sequence and of the final AVO signatures.     

Diatom-inferred late Pleistocene and Holocene palaeolimnological changes in the Ioannina basin, northwest Greece

The character and impact of climate change since the last glacial maximum (LGM) in the eastern Mediterranean region remain poorly understood. Here, two new diatom records from the Ioannina basin in northwest Greece are presented alongside a pre-existing record and used to infer past changes in lake level, a proxy for the balance between precipitation and evaporation. Comparison of the three records indicates that lake-level fluctuations were the dominant driver of diatom assemblage composition change, whereas productivity variations had a secondary role. The reconstruction indicates low lake levels during the LGM. Late glacial lake deepening was underway by 15.0 cal kyr BP, implying that the climate was becoming wetter. During the Younger Dryas stadial, a lake-level decline is recorded, indicating arid climatic conditions. Lake Ioannina deepened rapidly in the early Holocene, but long-term lake-level decline commenced around 7.0 cal kyr BP. The pattern of lake-level change is broadly consistent with an existing lake-level reconstruction at Lake Xinias, central Greece. The timing of the apparent change, however, is different, with delayed early Holocene deepening at Xinias. This offset is attributed to uncertainties in the age models, and the position of Xinias in the rain shadow of the Pindus Mountains.     

Climatic and anthropogenic influence on the stable isotope record from bulk carbonates and ostracodes in Lake Neuchâ, Switzerland, during the last two millennia

Lake Neuchåtel is a medium sized, hard-water lake, lacking varved sediments, situated in the western Swiss Lowlands at the foot of the Jura Mountains. Stable isotope data (18O and 13C) from both bulk carbonate and ostracode calcite in an 81 cm long, radiocarbon-dated sediment core represent the last 1500 years of Lake Neuchåtel's environmental history. Comparison between this isotopic and other palaeolimnologic data (mineralogical, geochemical, palynological, etc.) helps to differentiate between anthropogenic and natural factors most recently affecting the lake. An increase in lacustrine productivity (450–650AD ca), inferred from the positive trend in 13C values of bulk carbonate, is related to medieval forest clearances and the associated nutrient budget changes. A negative trend in both the bulk carbonate and ostracode calcite 18O values between approximately 1300 and 1500AD, is tentatively interpreted as due to a cooling in mean air temperature at the transition from the Medieval Warm Period to the Little Ice Age. Negative trends in bulk carbonate 18O and 13C values through the uppermost sediments, which have no equivalent in ostracode calcite isotopic values, are concomitant with the recent onset of eutrophication in the lake. Isotopic disequilibrium during calcite precipitation, probably due to kinetic factors in periods of high productivity is postulated as the mechanism to explain the associated negative isotopic trends, although the effect of a shift of the calcite precipitation towards the warmer months cannot be excluded.     

New insights on the binary Asteroid 121 Hermione

We report on the results of a 6-month photometric study of the main-belt binary C-type Asteroid 121 Hermione, performed during its 2007 opposition. We took advantage of the rare observational opportunity afforded by one of the annual equinoxes of Hermione occurring close to its opposition in June 2007. The equinox provides an edge-on aspect for an Earth-based observer, which is well suited to a thorough study of Hermione’s physical characteristics. The catalog of observations carried out with small telescopes is presented in this work, together with new adaptive optics (AO) imaging obtained between 2005 and 2008 with the Yepun 8-m VLT telescope and the 10-m Keck telescope. The most striking result is confirmation that Hermione is a bifurcated and elongated body, as suggested by Marchis, et al. [Marchis, F., Hestroffer, D., Descamps, P., Berthier, J., Laver, C., de Pater, I., 2005. Icarus 178, 450-464]. A new effective diameter of 187 ± 6 km was calculated from the combination of AO, photometric and thermal observations. The new diameter is some 10% smaller than the hitherto accepted radiometric diameter based on IRAS data. The reason for the discrepancy is that IRAS viewed the system almost pole-on. New thermal observations with the Spitzer Space Telescope agree with the diameter derived from AO and lightcurve observations. On the basis of the new AO astrometric observations of the small 32-km diameter satellite we have refined the orbit solution and derived a new value of the bulk density of Hermione of 1.4 + 0.5/−0.2 g cm⁻³. We infer a macroscopic porosity of ∼33 + 5/−20%.     

Early diagenesis in rapidly accumulating sediments on the Alboran slope, ODP site 976

 The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15 m indicate maximal organic matter degradation. Methane first appears at ∼20 m subbottom after sulfate is depleted, and its concentrations quickly climb. Received: 27 October 1997 / Revision received: 4 March 1998     

Environmental changes and carbon cycle perturbations at the Triassic–Jurassic boundary in northern Switzerland

The Triassic–Jurassic boundary is characterized by strong perturbations of the global carbon cycle, triggered by massive volcanic eruptions related to the onset of the Central Atlantic Magmatic Province. These perturbations are recorded by negative carbon isotope excursions (CIEs) which have been reported worldwide. In this study, Triassic–Jurassic boundary sections from the southern margin of the Central European Basin (CEB) located in northern Switzerland are analyzed for organic carbon and nitrogen isotopes in combination with particulate organic matter (POM) analyses. We reconstruct the evolution of the depositional environment from Late Triassic to Early Jurassic in northern Switzerland and show that observed negative shifts in δ¹³C of the total organic carbon (δ¹³C_TOC) in the sediment are only subordinately influenced by varying organic matter (OM) composition and primarily reflect global changes in the carbon cycle. Based on palynology and the stratigraphic positions of isotopic shifts, the δ¹³C_TOC record of the studied sections is correlated with the GSSP section at Kuhjoch (Tethyan realm) in Austria and with the St. Audrie’s Bay section (CEB realm) in southwest England. We also show that in contrast to POM analyses the applicability of organic carbon/total nitrogen (OC/TN) atomic ratios and stable isotopes of total nitrogen (δ¹⁵N_TN) for detecting changes in source of OM is limited in marginal depositional environments with frequent changes in lithology and OM contents.