Geogene Versus Anthropogene Origin of Trace Metals in Sediments in Cua Luc Estuary and Ha Long Bay, Vietnam

In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on ¹³⁷Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs.     

Web-GIS tool for the management of rural land markets

Land abandonment and stagnation of rural markets in the last few years have become one of the main concerns of rural administrations. The use of Web and GIS (Geographic Information System) technologies can help to mitigate the effects of these problems. This paper pro-poses a novel Web-GIS tool with spatial capabilities for the dynamization of rural land markets by encouraging the transfer of land from owners to farmers through the leasing of plots. The system, based on open source software, offers information about the properties, their environment and their owners. It uses standards for handling the geographic information and for communicating with external data sources. This system was used as the basis for the development of SITEGAL, the tool for the management of the Land Bank of Galicia (www.bantegal.com/sitegal). SITEGAL has been operational since 2007 obtaining benefits for both administration and users (farmers and land owners), and promoting the e-Government.     

Tectonic and seismic conditions for changes in spring discharge along the Garni right lateral strike slip fault (Armenian Upland)

Abstract

This study presents the relationship between local seismicity and springs discharge, in which the microseismicity modifies the state of stress of the aquifer matrix and these modifications of the local stress control the aquifer behaviour from an example of a basaltic reservoir crossed by a seismic fault.

Along the right-lateral Garni seismic wrench fault, the distribution in space and time of more than 500 micro-earthquakes has been studied providing a pattern of stress distribution. Together with this tectonic survey, the hydrographs of springs issuing from an aquifer located in basaltic lava flows and crossed by the fault have been gauged for 4 years. According to its tectonic, geologic and hydrodynamic properties, the reservoir has been divided in to several parts. The hydrological behaviour of the reservoir and of each of its parts has been modelled, based on the rainfall and hydrodynamic properties of the basaltic reservoir and of nearby reservoirs.

The model allows us to define the ‘normal behaviour’ of the springs, when their discharge is not affected by an earthquake. Anomalies to the normal hydrometric curves are defined, and correlated to small (M < 3.5) earthquakes along the Garni fault. We propose that the circulation of underground water in the area around the fault depends largely on the fracture pattern of the basalts and the aquifer basement, as pointed out from field observations. Changes in spring discharges are explained by variations in the state of stress around the Garni fault, induced by the alternation of elastic strain and stick-slip movement on the fault, and by creep far from the fault. A model of stress distribution is proposed which explains changes in fracture charateristics before and after earthquakes. © Elsevier, Paris     

Isotope geochemistry of Paleoproterozoic metacarbonates from Itatuba,Borborema Province,Northeastern Brazil: Evidence of marble melting within a collisional suture

Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low ⁸⁷Sr/⁸⁶Sr ratios and highly positive δ¹³C values. Available geochemical data for the upper Paleoproterozoic indicate that the ⁸⁷Sr/⁸⁶Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.     

Temporal relationship between Holocene human occupation and vegetation change along the northwestern margin of the Central African rainforest

This paper discusses the relationship between patterns of human settlements and environmental change during the Holocene along the northwestern margins of the equatorial rain forest of central Africa. Palaeoenvironmental data from high-resolution sediment cores from lacustrine deposits, plant macro-remains from forest soils, and archaeological data are harnessed to discuss the differential impact of climate and/or humans on the central African rain forest. It is shown that climate change impacted the rain forest well before the widespread expansion of human settlements all over the study area.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Seismic sequence stratigraphy of Miocene deposits related to eustatic,tectonic and climatic events,Cap Bon Peninsula,northeastern Tunisia

The Cap Bon Peninsula, belonging to northeastern Tunisia, is located in the Maghrebian Alpine foreland and in the North of the Pelagian block. By its paleoposition, during the Cenozoic, in the edge of the southern Tethyan margin, this peninsula constitutes a geological entity that fossilized the eustatic, tectonic and climatic interactions. Surface and subsurface study carried out in the Cap Bon onshore area and surrounding offshore of Hammamet interests the Miocene deposits from the Langhian-to-Messinian interval time. Related to the basin and the platform positions, sequence and seismic stratigraphy studies have been conducted to identify seven third-order seismic sequences in subsurface (SM1-SM7), six depositional sequences on the Zinnia-1 petroleum well (SDM1-SDM6), and five depositional sequences on the El Oudiane section of the Jebel Abderrahmane (SDM1–SDM5). Each sequence shows a succession of high-frequency systems tract and parasequences. These sequences are separated by remarkable sequence boundaries and maximum flooding surfaces (SB and MFS) that have been correlated to the eustatic cycles and supercycles of the Global Sea Level Chart of Haq et al. (1987). The sequences have been also correlated with Sequence Chronostratigraphic Chart of Hardenbol et al. (1998), related to European basins, allows us to arise some major differences in number and in size. The major discontinuities, which limit the sequences resulted from the interplay between tectonic and climatic phenomena. It thus appears very judicious to bring back these chronological surfaces to eustatic and/or local tectonic activity and global eustatic and climatic controls.     

Intercrystalline cation partitioning between minerals of the triplite-zwieselite-magniotriplite and the triphylite-lithiophilite series in granitic pegmatites

Minerals of the triphylite-lithiophilite, Li(Fe, Mn)PO₄, and the triplite-zwieselite-magniotriplite series, (Mn, Fe, Mg)₂PO₄F, occur in the late stage period of pegmatite evolution. Unfortunately, neither are the genetic relationships between these phosphates fully understood nor are thermodynamic data known. Consequently, phosphate associations and assemblages from 8 granitic pegmatites — Clementine II, Rubicon II and III, and Tsaobismund (Namibia); Hagendorf-Süd and Rabenstein (Germany); Valmy (France); Viitaniemi (Finland) — have been tested for compositional zoning and intercrystalline partitioning of main elements by electron microprobe techniques. Although the selected pegmatites display varying degrees of fractionation, and the intergrowth textures indicate different genetic relationships between the phosphates, the plots of mole fractions X _Fe=Fe/(Fe+Mn+Mg+Ca), X _Mn=Mn/(Fe+Mn+Mg+Ca), and X _Mg=Mg/(Fe+Mn+Mg+Ca) can be fitted relatively well with smooth curves in Roozeboom diagrams. Their deviations from symmetrical distribution curves are mainly dependent upon X _Mg or X _Ca, and upon non-ideal solutions. Surprisingly small differences between the partition coefficients were detected for intergrowths of different origin. However, the partitioning of shared components among coexisting phases is clearly dependent upon the conditions of formation. Compositional zoning is observed only when both Fe–Mn phosphates are intergrown mutually or with other Fe–Mn–Mg mineral solid-solutios. Thus, the zoning does not seem to be due to continuous crystallization, but to later diffusion processes. The triplite structure has preference for Mn, Mg, and Ca, while Fe prefers minerals of the triphylite series. A quantification of main element fractionation between minerals of the triphylite and the triplite series is possible in the cases where diffusion can be excluded. For the Fe/(Fe+Mn) ratios of core compositions an equation with a high correlation coefficient (R=0.988) was determined: Fe/(Fe+Mn)_Tr=[Fe/(Fe+Mn)_Li]/{2.737-(1.737)[Fe/(Fe+Mn)_Li]} (Tr=triplite series, Li=triphylite series). Consequently, the Fe/(Fe+Mn) ratio of the triplite series can now also be used in the interpretation of pegmatite evolution, just like that of the triphylite series which has been successfully applied in the past.     

Neo-rural populations and their relations with local decision makers in rural Québec: collaboration or conflict?

The socio-demographic recomposition of the countryside is affecting local interactions and power relations. Understanding these relationships remains a challenge, as the studies to date are often limited to conflicts between neo-rural populations (newcomers) and long-time country residents over partial issues, without including decision makers. To go beyond this conflictual and fragmentary perspective, the objective of this article is to present an overall picture of both cooperative and oppositional relations between four groups, namely, newcomers, long-time rural residents, leaders of local organizations and municipal officials, in regard to all the issues that concern them. The data are based on interviews with these various actors in two contrasting rural areas of Québec (Canada). After looking at the newcomers’ mixed assessment of their participation in community life, we concentrate on areas of collaboration and/or conflict between all the actors regarding demographic, economic, sociocultural, political, environmental and agricultural issues. Three main trends emerge, revealing unexpected ways of interacting, complex power relations and antagonistic conceptions of rural spaces and their future development.     

A Truncated Pareto Model to Estimate the Under Recovery of Large Diamonds

The metallurgical recovery processes in diamond mining may, under certain circumstances, cause an under-recovery of large diamonds. In order to predict high quantiles or tail probabilities we use a Bayesian approach to fit a truncated Generalized Pareto Type distribution to the tail of the data consisting of the weights of individual diamonds. Based on the estimated tail probability, the expected number of diamonds larger than a specified weight can be estimated. The difference between the expected and observed frequencies of diamond weights above an upper threshold provides an estimate of the number of diamonds lost during the recovery process.