Reliable Determination of Ge in Solid Environmental Samples Using a Chemical Preparation Procedure Developed for Si Isotopes and ICP‐MS Analysis

Germanium (Ge) exists at trace levels in the Earth's crust and is a powerful geochemical tracer of the silicon (Si) cycle. This study proposes a simple and reliable method for determining Ge contents in environmental samples using ICP‐MS. As Si and Ge have very similar chemical properties, we investigated the applicability of the chemical preparation procedure developed for Si isotopes for the determination of Ge in environmental samples. Advantages of this procedure are as follows: (a) efficient removal of the matrix and main interferences affecting Ge determinations by ICP‐MS, (b) a low limit of detection (6 ng l^?1), (c) relative repeatability of approximately 3% obtained on ⁷⁴Ge and (d) robustness and accuracy based on agreement within errors with the published Ge values for rock reference materials (BHVO‐2, AGV‐2 and BCR‐2). This procedure allowed revision of the Ge values of three soil reference materials (1.67 ± 0.09 μg g^?1, 2.41 ± 0.18 μg g^?1, 1.89 ± 0.10 μg g^?1 for GBW 07401, GBW 07404 and GBW 07407, respectively) and proposal of a value for the plant reference material ERM‐CD281 (70 ± 3 μg g^?1). This method provides a convenient procedure for determining Ge mass fractions in environmental samples and opens the possibility of coupling two tracers of the Si biogeochemical cycle with a single measurement procedure.     

Coral- and oyster-microbialite patch reefs in the aftermath of the Triassic–Jurassic biotic crisis (Sinemurian,Southeast France)

The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.     

A Study of the Local Geometric Accuracy of Count de Ferraris's Carte de cabinet (1770s) Using Differential Distortion Analysis

The eighteenth century Carte de cabinet of count de Ferraris is the first large-scale (1:11?520) topographic map of the entire Belgian territory, making it a valuable source of historical information. In the past, a number of studies have tried to assess the geometric accuracy of this map, but they all suffer from restricted technical capabilities for computing and visualizing the distortions, and most of them only focus on a limited number of the 275 map sheets. This paper therefore seeks to provide the first systematic and in-depth investigation of the map’s local geometric accuracy. Recently, two Belgian government agencies georeferenced the Flemish and Walloon part of the Carte de cabinet with a high level of detail, using some 30,000 ground control points to link the old map to the modern topographic map of Belgium. These data sets represent a new and unprecedented potential source of accuracy information. However, the high number of control points and our desire to compute distortions in an exact, local, quantitative and continuous way meant prominent techniques for studying the geometric accuracy of old maps, such as displacement vectors, distortion grids, triangular nets and the popular MapAnalyst software, were unsuited for this task. To meet all our requirements a new technique called Differential Distortion Analysis, which is influenced by the treatment of distortions in map projection theory, was used instead. Its advantages, structure and application to the Carte de cabinet are discussed in detail. The new technique allows calculating and displaying the map’s local angular and surface distortions with a very high spatial resolution. Consequently, it was possible to identify trends in the obtained levels of accuracy and to relate these to historical facts about the Carte de cabinet’s production process. This has resulted in important new insights into the map’s geometric accuracy.     

Local stress analysis in granular materials at a mesoscale

The purpose of this paper is to contribute to the change of scale techniques developed for granular materials. The proposed approach consists in considering an intermediate scale between the macroscales and microscales, called the mesoscale, using the classical homogenization scheme. In this approach, the mesoscale for 2D granular materials was defined at the level of local volumes, called mesodomains, which are local closed structures composed of particles in contact. In this paper, we focused on defining a local stress field at this scale. Two different methods are proposed, both based on the equivalent continuum mean stress but using different approximations of the mean stress tensor for each mesodomain. The two proposed methods were then compared to each other. Analyses performed on the stress field at the mesoscale show that this local field is heterogeneous and, in particular, that its heterogeneity is significantly structured at this scale. The distribution of the local mean stress (first invariant of the local stress tensor) is uniform in any mesodomain, whereas the distribution of the stress deviator (second invariant of the deviatoric part of the local stress tensor) is significantly dependent on the elongation direction and on the elongation degree of the mesodomains. The local stress ratio (ratio of the stress deviator to the mean stress) is higher within the mesodomains that are elongated in the global compression direction than that within the ones elongated in the global extension direction. Copyright © 2011 John Wiley & Sons, Ltd.     

A comparison of numerical simulations of eddy generation performed with a two- and a three-layer quasi-geostrophic model of oceanic mesoscale eddies

Abstract

The generation of eddies by a large-scale flow over mesoscale topography is studied with the help of two- and three-layer nonlinear quasi-geostrophic models of the open ocean. The equations are integrated forward in time with no eddies present initially. For a given time, the displacement of the interface between layers two and three (ζ) tends to a well-defined limit (function of the horizontal spatial coordinates) as ρ ₃ - ρ ₂ → 0 (ρ_r is the density of layer r). Even for values of α[= (ρ ₃ - ρ ₂)/(ρ ₂ - ρ ₁)] ^as small as 0.01 the potential energy due to ζ is not negligible and it can reach, in some cases, a considerable fraction of the total eddy energy.     

On the climatology of persistent circulation anomalies in the atmosphere and in a general circulation model

Abstract

The climatologies of upper‐air persistent circulation anomalies found in observations of the Northern Hemisphere and in a General Circulation Model (GCM) integration are compared with each other and with those found in previous studies. The model simulation is that of the Canadian Climate Centre GCM run at resolution T20. The objective criteria that define the persistent events differ from those of some earlier investigations in that the anomalies are not required to be as nearly stationary. It is found that the GCM generates persistent circulation anomalies downstream of the synoptic‐scale storm tracks, in very nearly the correct geographical locations, but that the frequency of occurrence is too low in the model. A kinetic energy and streamfunction variance analysis is presented for both dataseis to clarify the differences between the observed and simulated distributions of circulation anomalies. It is evident that, apart from the mean annual cycle, the middle‐latitude transient eddies of the model are too weak.     

Intense warm and saline upper ocean inflow in the southern Bay of Biscay in autumn–winter 2006–2007

Unusually warm and saline near-surface inflow was observed in the southern Bay of Biscay (Northeast Atlantic) in autumn–winter 2006–2007. These anomalies were swiftly entrained eastward through the Iberian Poleward Current flowing over the slope and shelf. Here, we present a quasi-synoptic three dimensional view of this event, which started as early as August 2006. In situ hydrological and Lagrangian measurements were used to describe its characteristics. The warm anomaly was surface intensified over the shelf, with surface temperature above 17 °C, a monthly anomaly over 1 °C compared to the 1994–2006 period. The saline anomaly was maximum around 100–200 m deep, over the upper slope, with values above 35.9 psu. Slope and shelf were seen to exhibit a complex structure of eastward (poleward) and westward (equatorward) currents. Maximum currents, observed near surface, over the upper slope in the eastern part of the Bay of Biscay, were determined to exceed 1.3 m s^?1. This current system eventually became unstable, thereby promoting strong exchange of properties between coastal and deep ocean. The event was coincident with abnormal southerly wind conditions west of Iberia in autumn 2006, and with the unusually warm autumn–winter weather over western Europe. A dynamical analysis relying on wind forcing west and north of Iberia is proposed.     

Time scales of DNAPL migration in sandy aquifers examined via numerical simulation

The time required for dense nonaqueous phase liquid (DNAPL) to cease migrating following release to the subsurface is a valuable component of a site conceptual model. This study uses numerical simulation to investigate the migration of six different DNAPLs in sandy aquifers. The most influential parameters governing migration cessation time are the density and viscosity of the DNAPL and the mean hydraulic conductivity of the aquifer. Releases of between 1 and 40 drums of chlorinated solvent DNAPLs, characterized by relatively high density and low viscosity, require on the order of months to a few years to cease migrating in a heterogeneous medium sand aquifer having an average hydraulic conductivity of 7.4 x 10(-3) cm/s. In contrast to this, the release of 20 drums of coal tar (rho(D)= 1061 kg/m(3), micro(D)= 0.161 Pa.s) requires more than 100 years to cease migrating in the same aquifer. Altering the mean hydraulic conductivity of the aquifer results in a proportional change in cessation times. Parameters that exhibit relatively little influence on migration time scales are the DNAPL-water interfacial tension, release volume, source capillary pressure, mean aquifer porosity, and ambient ground water hydraulic gradient. This study also demonstrates that low-density DNAPLs (e.g., coal tar) give rise to greater amounts of lateral spreading and greater amounts of pooling on capillary barriers than high-density DNAPLs such as trichloroethylene or tetrachloroethylene.     

Variations in sediment yield over the advance and retreat of a calving glacier, Laguna San Rafael, North Patagonian Icefield

Bathymetric and sub-bottom acoustic data were collected in Laguna San Rafael, Chile, to determine sediment yields during the Little Ice Age advance and subsequent retreat of San Rafael Glacier. The sediment volumes and subaqueous landforms imaged are used to interpret the proglacial dynamics and estimate erosion rates from a temperate tidewater glacier over a complete advance-retreat cycle. Sediment yields from San Rafael Glacier averaged 2.7 × 10⁷ m³/a since the end of the Little Ice Age, circa AD 1898, corresponding to average basin-wide erosion rates of 23 ± 9 mm/a; the highest erosion rates, 68 ± 23 mm/a, occurred at the start of the retreat phase, and have since been steadily decreasing. Erosion rates were much lower during glacial advance, averaging at most 7 mm/a, than during retreat. Such large glacial sediment yields over two centuries of advance and retreat suggest that the contribution of sediments stored subglacially cannot account for much of the sediment being delivered to the terminus today. The detailed sub-bottom information of a proglacial lagoon yields important clues as to the timing of erosion, deposition and transfer of glacigenic sediments from orogens to the continental shelves, and the influence of glacier dynamics on this process.     

Magnesium isotopic composition of the Earth and chondrites

To constrain further the Mg isotopic composition of the Earth and chondrites, and investigate the behavior of Mg isotopes during planetary formation and magmatic processes, we report high-precision (±0.06‰ on δ²⁵Mg and ±0.07‰ on δ²⁶Mg, 2SD) analyses of Mg isotopes for (1) 47 mid-ocean ridge basalts covering global major ridge segments and spanning a broad range in latitudes, geochemical and radiogenic isotopic compositions; (2) 63 ocean island basalts from Hawaii (Kilauea, Koolau and Loihi) and French Polynesia (Society Island and Cook-Austral chain); (3) 29 peridotite xenoliths from Australia, China, France, Tanzania and USA; and (4) 38 carbonaceous, ordinary and enstatite chondrites including 9 chondrite groups (CI, CM, CO, CV, L, LL, H, EH and EL).Oceanic basalts and peridotite xenoliths have similar Mg isotopic compositions, with average values of δ²⁵Mg = −0.13 ± 0.05 (2SD) and δ²⁶Mg = −0.26 ± 0.07 (2SD) for global oceanic basalts (n = 110) and δ²⁵Mg = −0.13 ± 0.03 (2SD) and δ²⁶Mg = −0.25 ± 0.04 (2SD) for global peridotite xenoliths (n = 29). The identical Mg isotopic compositions in oceanic basalts and peridotites suggest that equilibrium Mg isotope fractionation during partial melting of peridotite mantle and magmatic differentiation of basaltic magma is negligible. Thirty-eight chondrites have indistinguishable Mg isotopic compositions, with δ²⁵Mg = −0.15 ± 0.04 (2SD) and δ²⁶Mg = −0.28 ± 0.06 (2SD). The constancy of Mg isotopic compositions in all major types of chondrites suggest that primary and secondary processes that affected the chemical and oxygen isotopic compositions of chondrites did not significantly fractionate Mg isotopes.Collectively, the Mg isotopic composition of the Earth’s mantle, based on oceanic basalts and peridotites, is estimated to be −0.13 ± 0.04 for δ²⁵Mg and −0.25 ± 0.07 for δ²⁶Mg (2SD, n = 139). The Mg isotopic composition of the Earth, as represented by the mantle, is similar to chondrites. The chondritic composition of the Earth implies that Mg isotopes were well mixed during accretion of the inner solar system.