Non-equilibrium alcohol flooding model for immiscible phase remediation: 1. Equation development

The equations for a compositional model for simulation of a two-phase, three-component system with inter-phase mass transfer are developed. Emphasis is placed on development of inter-phase mass transfer equations for incorporation of rate-limited inter-phase mass transfer. Due to the nature of the three-component systems considered, a single-film model may be inadequate and a two-film model must be utilized. A two-film model accounts for the simultaneous transfer of components in both directions across phase interfaces. The effect of interaction between components on diffusion is considered using a general form of Fick's Law. A Hand Plot representation of ternary phase behavior is chosen since it allows for straightforward calculation of miscibility of bulk phases under conditions of local non-equilibrium. The developed set of equations form the basis for a numerical model to simulate the enhanced removal of non-aqueous phase liquids (NAPLs) from porous media using single-component alcohol floods.     

Chemical evolution of thermal waters and changes in the hydrothermal system of Papandayan volcano (West Java,Indonesia) after the November 2002 eruption

Papandayan is a stratovolcano situated in West Java, Indonesia. Since the last magmatic eruption in 1772, only few hydrothermal explosions have occurred. An explosive eruption occurred in November 2002 and ejected ash and altered rocks. The altered rocks show that an advanced argillic alteration took place in the hydrothermal system by interaction between acid fluids and rocks. Four zones of alteration have been defined and are limited in extension and shape along faults or across permeable structures at different levels beneath the active crater of the volcano.     

Patterns of seismic swarm activity in the Corinth Rift in 2000–2005

Based on the data of the detailed earthquake catalog provided on the website of the Corinth Rift Laboratory, zones of swarm activity are revealed and the variations in the statistical parameters of seismic swarms that occurred in the western part of the Gulf of Corinth are calculated. The preliminary analysis of the catalogue is carried out; the magnitude of completeness and the accuracy of the location of the earth-quake are estimated; the changes in these parameters associated with the development of the observational network are assessed. The b-value (b-values) and the cluster dimension of the set of hypocenters are estimated, and time variations in these parameters in the course of the evolution of swarm activity are revealed. The style of changes in the parameters characterizing the seismic regime during intervals of swarm activity indicates that the process of failure exhibits scale redistribution over the course of time, changing from upscaling (progression from smaller to larger scales) at the stage of increasing seismicity to downscaling (progression from larger to lower scales) at the stage of decay. These particular features of enhancement and reduction of swarm seismicity are qualitatively similar to the scenarios of source preparation and aftershock relaxation of strong earthquakes. The pattern of variations of the swarm seismicity studied is similar to those identified in the previous laboratory and field modeling of various transient modes of seismicity. This fact confirms the relevancy of the retrieved results and conclusions based on the laboratory studies of transient modes, and suggests that the latter have a universal governing mechanism.     

Volatile fluxes from volcanoes

Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-³He, ²¹⁰Po, SO₂-and chemical ratios of volatile species in lavas and volcanic gases.
These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO₂, SO₂ and trace metals.
They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them.
The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction.     

Practical method for drawing a VGP path

A statistical method is proposed for the smoothing of polar wander paths and for giving their confidence limits by the mean of successive ellipses. The method is fully parametrical and is based on the relations between the inertia matrix and the parameters of the Fisher distribution, from which a bivariate form is deduced. An elementary tensorial calculation gives the parameters of the confidence ellipse around a vectorial weighted mean, for any unimodal set of vectors. This model can also be used for other statistical tests, wherever the rotational symmetry hypothesis is not consistent (i.e. the fold test).