Sur la mesure de l'intensité du champ magnétique terrestre et la distribution du magnétisme dans les aimants

The measurement of the horizontal component, H, of the geomagnetic field represents an important part of geomagneticians work from 1830 to the end of the 19th century. This measurement remained difficult at the required accuracy of ${10}^{\mathrm{?9}}\text{T}$ (1 nT or $1\gamma$), till the advent of proton and optical pumping magnetometers in geomagnetic observatories, around 1955. The measurement of H consisted in determining the mutual torque between two cylindrical magnets, by measuring either oscillation periods or angular deviations. Poisson was the first, indisputably, to propose the general principle of the measurement, in 1825. But Gauss, some years later (1832), successfully operated his famous oscillation–deviation method, described since then in all the elementary manuals of physics. The computation of the mutual torque depends on the tri-dimensional distribution of the magnetization in each one of the magnets. In the absence of an accurate-enough knowledge of these distributions, Poisson, Gauss, and their successors showed how to make the computations with a minimum number of hypotheses on them. Nevertheless physicists, in particular French ones, worked on the ‘distribution of magnetism’ in magnets; the first of them was Coulomb. We come back to this question through experiments conducted in the magnetic observatory of Chambon-la-Forêt, France. To cite this article: B. Leprêtre, J.-L. Le Mouël, C. R. Geoscience 337 (2005).     

Noble gas and isotope geochemistry in western Canadian Arctic watersheds: tracing groundwater recharge in permafrost terrain

In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems with features including the occurrence of year-round open water and the formation of icings, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Stable isotopes (δ¹⁸O, δD, δ¹³C_DIC), and noble gases have proved useful to study groundwater recharge and flow of groundwater which discharges along rivers in Canada’s western Arctic. In these studies of six catchments, groundwater recharge was determined to be a mix of snowmelt and precipitation. All systems investigated show that groundwater has recharged through organic soils with elevated P_CO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 5 °C, which when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater circulation times were found to be up to 31 years for non-thermal waters using the ³?H-³He method.     

Present weathering rates in a humid tropical watershed: Nsimi, South Cameroon

The study of biogeochemical and hydrological cycles in small experimental watersheds on silicate rocks, common for the Temperate Zone, has not yet been widely applied to the tropics, especially humid areas. This paper presents an updated database for a six-year period for the small experimental watershed of the Mengong brook in the humid tropics (Nsimi, South Cameroon). This watershed is developed on Precambrian granitoids (North Congo shield) and consists of two convexo-concave lateritic hills surrounding a large flat swamp covered by hydromorphic soils rich in upward organic matter. Mineralogical and geochemical investigations were carried out in the protolith, the saprolite, the hillside lateritic soils, and the swamp hydromorphic soils. Biomass chemical analyses were done for the representative species of the swamp vegetation. The groundwater was analysed from the parent rock/saprolite weathering front to the upper fringe in the hillside and swamp system. The chemistry of the wet atmospheric and throughfall deposits and the Mengong waters was monitored.In the Nsimi watershed the carbon transfer occurs primarily in an organic form and essentially as colloids produced by the slow biodegradation of the swamp organic matter. These organic colloids contribute significantly to the mobilization and transfer of Fe, Al, Zr, Ti, and Th in the uppermost first meter of the swamp regolith. When the organic colloid content is low (i.e., in the hillside groundwater), Th and Zr concentrations are extremely low (<3 pmol/L, ICP-MS detection limits). Strongly insoluble secondary thorianite (ThO₂) and primary zircon (ZrSiO₄) crystals control their mobilization, respectively. This finding thus justifies the potential use of both these elements as inert elements for isoelement mass balance calculations pertaining to the hillside regolith.Chloride can not be used as a conservative tracer of hydrological processes and chemical weathering in this watershed. Biogenic recycling significantly influences the low-Cl input fluxes. Sodium is a good tracer of chemical weathering in the watershed. The sodium solute flux corrected from cyclic salt input was used to assess the chemical weathering rate. Even though low (2.8 mm/kyr), the chemical weathering rate predominates over the mechanical weathering rate (1.9 mm/kyr). Compared to the Rio Icacos watershed, the most studied tropical site, the chemical weathering fluxes of silica and sodium in the Mengong are 16 and 40 times lower, respectively. This is not only related to the protective role of the regolith, thick in both cases, but also to differences in the hydrological functioning. This is to be taken into account in the calculations of the carbon cycle balance for large surfaces like that of the tropical forest ecosystems on a stable shield at the global level.     

Modeling reactive transport in sediments subject to bioturbation and compaction

Current bioturbation models are marked by confusion in their treatment of porosity. Different equations appear to be needed for different biodiffusion mechanisms, i.e., interphase mixing, where biological activity causes bulk mixing of sediment affecting both tracer and porosity profiles, versus intraphase mixing, where the solid components are intermixed, but the porosity is left unchanged. Another issue is whether the model depends upon the particle type with which tracers are associated, e.g., ¹³⁷Cs on small clay particles versus ²¹⁰Pb on larger grains. This uncertainty has lead to conflicting conservation equations for radiotracers, and in particular, to the question whether the porosity should be placed inside or outside of the differential term that governs the biodiffusive flux. We have reexamined this situation in the context of multiphase, multicomponent continuum theory. Most importantly, we prove that under the assumption of steady-state porosity, there exists only one correct form of the steady-state conservation equation for a radiotracer, regardless of biodiffusion mechanism and particle type, i.e.,

     

Time scales of DNAPL migration in sandy aquifers examined via numerical simulation

The time required for dense nonaqueous phase liquid (DNAPL) to cease migrating following release to the subsurface is a valuable component of a site conceptual model. This study uses numerical simulation to investigate the migration of six different DNAPLs in sandy aquifers. The most influential parameters governing migration cessation time are the density and viscosity of the DNAPL and the mean hydraulic conductivity of the aquifer. Releases of between 1 and 40 drums of chlorinated solvent DNAPLs, characterized by relatively high density and low viscosity, require on the order of months to a few years to cease migrating in a heterogeneous medium sand aquifer having an average hydraulic conductivity of 7.4 x 10(-3) cm/s. In contrast to this, the release of 20 drums of coal tar (rho(D)= 1061 kg/m(3), micro(D)= 0.161 Pa.s) requires more than 100 years to cease migrating in the same aquifer. Altering the mean hydraulic conductivity of the aquifer results in a proportional change in cessation times. Parameters that exhibit relatively little influence on migration time scales are the DNAPL-water interfacial tension, release volume, source capillary pressure, mean aquifer porosity, and ambient ground water hydraulic gradient. This study also demonstrates that low-density DNAPLs (e.g., coal tar) give rise to greater amounts of lateral spreading and greater amounts of pooling on capillary barriers than high-density DNAPLs such as trichloroethylene or tetrachloroethylene.     

Petroleum potential of the Chalbi basin, NW Kenya

This paper deals with the study of subsurface stratigraphy of the Chalbi rift basin, northwest Kenya. The basin is known to have evolved through extension tectonics that brought out continental rifting as a part of the major Gondwanaland breakup in the Late Paleozoic and continued in the Mesozoic and Tertiary. This work has been based on gravity, seismic and gamma ray data, as well as the drill core logs available. The geophysical data used was collected by AMOCO as part of the hydrocarbon programme. But the gravity anomaly maps as well as seismic profiles were most useful for the interpretations incorporated in the present paper. They revealed the presence of several horst and graben structural systems. It was also revealed that the basin attracted sedimentary piles ranging up to 5 km thickness, which were deposited on basement rocks of Precambrian age. The basin subsequently got covered by basaltic flows of mainly Miocene age. The drill core lithologs that were available pertain to wells: C1, C2 and C3 in the Chalbi basin (Cretaceous). Comparing the lithologs from these wells with the seismic and gamma ray characteristics have been discussed in order to characterise the strata in which there was oil/gas shows. These characteristics were further seen in the light of the porosities, organic matter and other sedimentological parameters in order to understand the essential features of source rocks, reservoir rocks and the cap rocks. An attempt has been made to extrapolate the knowledge gained for recommending the probable prognostic sites for future drilling in the Chalbi Basin.     

Systematic use of trace element in igneous process

This paper describes an extended application of the Rayleigh distillation law to trace element behavior in a fractional crystallization sequence. Using a trace element with a very low bulk partition coefficient as a reference (as suggested by Anderson and Greenland, 1969, and extended by Treuil and Varet, 1973), we can derive bulk partition coefficients for other elements and, in turn, the mineralogical composition of the cumulates. Trace elements with large D, such as Ni and Cr, further constrain the system, and we can deduce the initial composition of the magma. An example of this technique is shown for Terceira Island in the Azores.Contribution IPGNS no 229Now at Dept. of Geological Sciences, California Institute of Technology, Pasadena, California, USA     

The Calcium Isotope Composition of Modern Seawater Determined by Thermal Ionisation Mass Spectrometry

The Ca isotopic composition of modern seawater has been determined using a ⁴³Ca-⁴⁸Ca double spike, which was calibrated using a ⁴²Ca/⁴⁴Ca seawater ratio of 0.30587 ± 0.00026. This ratio was determined from a total evaporation experiment in which the ion beam was measured from the beginning to the end of the emission. With integration of the peak intensities, the fractionation effects can be minimised, since total evaporation of the reservoir cancels out the effect of vapour enrichment in the light isotopes. This experiment avoids the gravimetric uncertainty inherent in the double spike calibration. This calibration allows the precise redetermination of the seawater isotopic composition of Ca. A mean ⁴⁰Ca/⁴⁴Ca ratio for two Atlantic water samples of 45.143 (2s_mean= 0.003) was found. The good reproducibility of the Ca isotope ratios in present seawater and the very strong isotopic homogeneity of Ca in the oceans illustrate the advantage of using seawater as the common standard, with the advantage of decreasing interlaboratory bias.     

Impact of spatial resolution on simulated surface water mass transformations in the Atlantic

We analyze the water mass transformation in coarse (1°) and high (1/6°) resolution ocean simulations with the identical configuration of the CLIPPER model and interannual ERA15 forcing function. Climatological characteristics of surface water mass transformation in the two experiments are quite different. The high resolution experiment exhibits a stronger surface transformation in equatorial and tropical regions, in the Gulf Stream area and in the location of the formation of Subtropical Mode Water (STMW), associated with high levels of eddy kinetic energy. The coarse resolution experiment shows a better representation of the transformation rates corresponding to the densest subpolar mode waters and Labrador Sea Water (LSW). This is explained by the differences in lateral mixing procedures between high and coarse resolution experiments. The high resolution 1/6° run is eddy-resolving only in the tropics and mid-latitudes. In these areas eddies are found to enhance the process of water mass transformation compared to the isopycnal diffusion used to parameterized the eddies in the 1° model. Despite its 1/6° resolution, the high resolution model does not adequately represent eddies in the subpolar gyre and Labrador Sea. In these areas the high resolution model fails to correctly simulate water mass transformation because the lateral mixing (provided through the bi-harmonic sub-gridscale parameterization) of newly ventilated waters with surrounding waters is not efficient enough. In contrast in the coarse 1° resolution model, the strong lateral mixing and the unrealistically broad boundary currents imposed by the high diffusivity required for numerical stability mixes newly formed LSW waters with the warmer and saltier waters of the rim current. Finally, it results in a more effective representation of the surface water mass transformation in high latitudes in the 1° model. A possible impact of the increased lateral diffusion in high resolution experiment on the representation of re-stratification in the Labrador Sea was studied in sensitivity experiments with different lateral diffusion coefficients compared to the regional eddy-resolving 1/15° simulation in the subpolar North Atlantic. If the eddies are not resolved in subpolar latitudes (as in the case of 1/6° model), the GM90 parameterization with the coefficient close to 800 m² s⁻¹ provides the closest agreement with the solution of eddy-resolving 1/15° model.     

Geostatistical traveltime tomography in elliptically anisotropic media

In geological materials, anisotropy may arise due to different mechanisms and can be found at different scales. Neglecting anisotropy in traveltime tomographic reconstruction leads to artefacts that can obscure important subsurface features. In this paper, a geostatistical tomography algorithm to invert cross‐hole traveltime data in elliptically anisotropic media is presented. The advantages of geostatistical tomography are that the solution is regularized by the covariance of the model parameters, that known model parameters can be used as constraints and fitted exactly or within a prescribed variance and that stochastic simulations can be performed to appraise the variability of the solution space. The benefits of the algorithm to image anisotropic media are illustrated by two examples using synthetic georadar data and real seismic data. The first example confirms suspected electromagnetic anisotropy in the vadose zone caused by relatively rapid water content variations with respect to wavelength at georadar frequencies. The second presents how sonic log data can be used to constrain the inversion of cross‐well seismic data and how geostatistical simulations can be used to infer parameter uncertainty. Results of both examples show that considering anisotropy yields a better fit to the data at high ray angles and reduces reconstruction artefacts.