Intense warm and saline upper ocean inflow in the southern Bay of Biscay in autumn–winter 2006–2007

Unusually warm and saline near-surface inflow was observed in the southern Bay of Biscay (Northeast Atlantic) in autumn–winter 2006–2007. These anomalies were swiftly entrained eastward through the Iberian Poleward Current flowing over the slope and shelf. Here, we present a quasi-synoptic three dimensional view of this event, which started as early as August 2006. In situ hydrological and Lagrangian measurements were used to describe its characteristics. The warm anomaly was surface intensified over the shelf, with surface temperature above 17 °C, a monthly anomaly over 1 °C compared to the 1994–2006 period. The saline anomaly was maximum around 100–200 m deep, over the upper slope, with values above 35.9 psu. Slope and shelf were seen to exhibit a complex structure of eastward (poleward) and westward (equatorward) currents. Maximum currents, observed near surface, over the upper slope in the eastern part of the Bay of Biscay, were determined to exceed 1.3 m s^?1. This current system eventually became unstable, thereby promoting strong exchange of properties between coastal and deep ocean. The event was coincident with abnormal southerly wind conditions west of Iberia in autumn 2006, and with the unusually warm autumn–winter weather over western Europe. A dynamical analysis relying on wind forcing west and north of Iberia is proposed.     

Time scales of DNAPL migration in sandy aquifers examined via numerical simulation

The time required for dense nonaqueous phase liquid (DNAPL) to cease migrating following release to the subsurface is a valuable component of a site conceptual model. This study uses numerical simulation to investigate the migration of six different DNAPLs in sandy aquifers. The most influential parameters governing migration cessation time are the density and viscosity of the DNAPL and the mean hydraulic conductivity of the aquifer. Releases of between 1 and 40 drums of chlorinated solvent DNAPLs, characterized by relatively high density and low viscosity, require on the order of months to a few years to cease migrating in a heterogeneous medium sand aquifer having an average hydraulic conductivity of 7.4 x 10(-3) cm/s. In contrast to this, the release of 20 drums of coal tar (rho(D)= 1061 kg/m(3), micro(D)= 0.161 Pa.s) requires more than 100 years to cease migrating in the same aquifer. Altering the mean hydraulic conductivity of the aquifer results in a proportional change in cessation times. Parameters that exhibit relatively little influence on migration time scales are the DNAPL-water interfacial tension, release volume, source capillary pressure, mean aquifer porosity, and ambient ground water hydraulic gradient. This study also demonstrates that low-density DNAPLs (e.g., coal tar) give rise to greater amounts of lateral spreading and greater amounts of pooling on capillary barriers than high-density DNAPLs such as trichloroethylene or tetrachloroethylene.     

Variations in sediment yield over the advance and retreat of a calving glacier, Laguna San Rafael, North Patagonian Icefield

Bathymetric and sub-bottom acoustic data were collected in Laguna San Rafael, Chile, to determine sediment yields during the Little Ice Age advance and subsequent retreat of San Rafael Glacier. The sediment volumes and subaqueous landforms imaged are used to interpret the proglacial dynamics and estimate erosion rates from a temperate tidewater glacier over a complete advance-retreat cycle. Sediment yields from San Rafael Glacier averaged 2.7 × 10⁷ m³/a since the end of the Little Ice Age, circa AD 1898, corresponding to average basin-wide erosion rates of 23 ± 9 mm/a; the highest erosion rates, 68 ± 23 mm/a, occurred at the start of the retreat phase, and have since been steadily decreasing. Erosion rates were much lower during glacial advance, averaging at most 7 mm/a, than during retreat. Such large glacial sediment yields over two centuries of advance and retreat suggest that the contribution of sediments stored subglacially cannot account for much of the sediment being delivered to the terminus today. The detailed sub-bottom information of a proglacial lagoon yields important clues as to the timing of erosion, deposition and transfer of glacigenic sediments from orogens to the continental shelves, and the influence of glacier dynamics on this process.     

Magnesium isotopic composition of the Earth and chondrites

To constrain further the Mg isotopic composition of the Earth and chondrites, and investigate the behavior of Mg isotopes during planetary formation and magmatic processes, we report high-precision (±0.06‰ on δ²⁵Mg and ±0.07‰ on δ²⁶Mg, 2SD) analyses of Mg isotopes for (1) 47 mid-ocean ridge basalts covering global major ridge segments and spanning a broad range in latitudes, geochemical and radiogenic isotopic compositions; (2) 63 ocean island basalts from Hawaii (Kilauea, Koolau and Loihi) and French Polynesia (Society Island and Cook-Austral chain); (3) 29 peridotite xenoliths from Australia, China, France, Tanzania and USA; and (4) 38 carbonaceous, ordinary and enstatite chondrites including 9 chondrite groups (CI, CM, CO, CV, L, LL, H, EH and EL).Oceanic basalts and peridotite xenoliths have similar Mg isotopic compositions, with average values of δ²⁵Mg = −0.13 ± 0.05 (2SD) and δ²⁶Mg = −0.26 ± 0.07 (2SD) for global oceanic basalts (n = 110) and δ²⁵Mg = −0.13 ± 0.03 (2SD) and δ²⁶Mg = −0.25 ± 0.04 (2SD) for global peridotite xenoliths (n = 29). The identical Mg isotopic compositions in oceanic basalts and peridotites suggest that equilibrium Mg isotope fractionation during partial melting of peridotite mantle and magmatic differentiation of basaltic magma is negligible. Thirty-eight chondrites have indistinguishable Mg isotopic compositions, with δ²⁵Mg = −0.15 ± 0.04 (2SD) and δ²⁶Mg = −0.28 ± 0.06 (2SD). The constancy of Mg isotopic compositions in all major types of chondrites suggest that primary and secondary processes that affected the chemical and oxygen isotopic compositions of chondrites did not significantly fractionate Mg isotopes.Collectively, the Mg isotopic composition of the Earth’s mantle, based on oceanic basalts and peridotites, is estimated to be −0.13 ± 0.04 for δ²⁵Mg and −0.25 ± 0.07 for δ²⁶Mg (2SD, n = 139). The Mg isotopic composition of the Earth, as represented by the mantle, is similar to chondrites. The chondritic composition of the Earth implies that Mg isotopes were well mixed during accretion of the inner solar system.     

Springtime changes in snow chemistry lead to new insights into mercury methylation in the Arctic

Seasonal snow is an active media and an important climate factor that governs nutrient transfer in Arctic ecosystems. Since the snow stores and transforms nutrients and contaminants, it is of crucial importance to gain a better understanding of the dynamics of contaminant cycling within the snowpack and its subsequent release to catchments via meltwater. Over the course of a two-month field study in the spring of 2008, we collected snow and meltwater samples from a seasonal snowpack in Ny-Ålesund, Norway (78°56′N, 11°52′E), which were analyzed for major inorganic ions and some organic acids, as well as total, dissolved, bioavailable mercury (THg, DHg, BioHg, respectively) and monomethylmercury (MMHg) species. We observe a seasonal gradient for ion concentrations, with surface samples becoming less concentrated as the season progressed. A significant negative correlation between BioHg and MMHg was observed in the snowpack. MMHg was positively and significantly correlated to methanesulfonate concentrations. Based on these results, we propose a new model for aerobic methylation of mercury involving species in the dimethylsulfoniopropionate cycle.     

Origin of the giant Allard Lake ilmenite ore deposit (Canada) by fractional crystallization,multiple magma pulses and mixing

The late-Proterozoic Allard Lake ilmenite deposit is located in the Havre-Saint-Pierre anorthosite complex, part of the allochtonous polycyclic belt of the Grenville Province. Presently the world's largest Fe–Ti oxide deposit, it had a pre-mining amount in excess of 200 Mt at grades over 60 wt.% hemo-ilmenite. The main ore body is a funnel-shaped intrusion, measuring 1.03 × 1.10 km and 100–300 m-thick. Two smaller bodies are separated by faults and anorthosite. The ore is an ilmenite-rich norite (or ilmenitite) made up of hemo-ilmenite (Hem_22.6–29.4, 66.2 wt.% on average), andesine plagioclase (An_45–50), aluminous spinel and locally orthopyroxene. Whole-rock chemical compositions are controlled by the proportions of ilmenite and plagioclase ± orthopyroxene which supports the cumulate origin of the deposit. Ore-forming processes are further constrained by normal and reverse fractionation trends of Cr concentration in cumulus ilmenite that reveal multiple magma emplacements and alternating periods of fractional crystallization and magma mixing. Mixing of magmas produced hybrids located in the stability field of ilmenite resulted in periodic crystallization of ilmenite alone. The unsystematic differentiation trends in the Allard Lake deposit, arising from a succession of magma pulses, hybridisation, and the fractionation of hemo-ilmenite alone or together with plagioclase suggest that the deposit formed within a magma conduit. This dynamic emplacement mechanism associated with continuous gravity driven accumulation of Fe–Ti oxides and possibly plagioclase buoyancy in a fractionating ferrobasalt explains the huge concentration of hemo-ilmenite. The occurrence of sapphirine associated with aluminous spinel and high-alumina orthopyroxene (7.6–9.1 wt.% Al₂O₃) lacking exsolved plagioclase supports the involvement of a metamorphic overprint during the synchronous Ottawan orogeny, which is also responsible for strong textural equilibration and external granule of exsolved aluminous spinel due to slow cooling.     

Tides at Port Mansfield,Laguna Madre,Texas

Abstract

The tides at Port Mansfield are so small (mean diurnal range of about 2 cm) that they are nearly lost in a noisy (meteorological) continuum. Nevertheless, a precise tidal analysis is necessary to provide the data for a determination of the elevation of mean high water, the boundary between private and state ownership in an oil‐producing area with a very flat terrain. Although response tidal analysis has been shown to be somewhat superior to classical harmonic analysis in various previous tests, no advantage is found in these circumstances of extremely low sighal‐to‐noise ratio.     

Assessing climate change vulnerability in the arctic using geographic information services in spatial data infrastructures

Timely knowing about climate change impacts is crucial to adequately plan and undertake adaptive measures and thus to effectively lower vulnerability. This requires gathering and integrating geographic information on exposure, local response mechanisms and stakeholders’ concerns. Spatial Data Infrastructures (SDI) are internet-based information systems that facilitate the exchange and use of distributed geographic information. This paper presents the application of SDI to climate change assessment by implementing a generic methodology for the quantification of vulnerability to climate change. The resulting integrated tool allows scientists, stakeholders and decision makers to communicate, assess and improve information about vulnerability to climate change. We show how emerging internet technologies and SDI in particular, make a new interactive approach of assessing vulnerability to climate change possible. Vulnerability was quantified based on an active stakeholder involvement by incorporating their varying perceptions, by allowing them to provide feedback and by supporting the acquisition of stakeholders’ knowledge. However, the application showed that to be effective, efforts to achieve and maintain interoperability between the various scientific disciplines should be kept integrated within mainstream IT developments.     

Weathering rates from top to bottom in a carbonate environment

This study investigates U-series, Sr isotopes, major and trace elements in a chalk aquifer system located in Eastern France. Soil and rock samples were collected along depth profiles down to 45 m in four localities as an attempt to investigate the weathering processes in the soil, the unsaturated zone and the saturated zone of the aquifer. Interstitial water was extracted from soils and rocks by a centrifugation technique. U-series offer a powerful tool to calculate weathering rates because the relative mobility of the U- and Th-isotopes can be precisely measured and it does not require the determination of a reference state as in other approaches. As expected, the data show very large mobile element depletion in the soil with large ²³⁰Th excess relative to ²³⁸U, while the rocks show more limited but not insignificant mobile element depletion. The U-series data have been used to constrain weathering rates based on a 1-D reactive transport model. Weathering rates in the near surface are about 10–100 times faster than at depth. However, when integrated over the depth of the cores, including the unsaturated and the saturated zones, this underground weathering represents more than 30% of the total weathering flux, assuming congruent dissolution of carbonates. The (²³⁴U/²³⁸U) ratios in interstitial water are consistent with solid samples showing ²³⁴U depletion near the surface and an excess ²³⁴U at depth. A leaching experiment performed on chalk shows that the excess ²³⁴U in natural waters percolating through carbonate rocks results both from preferential ²³⁴U leaching and direct recoil in the interstitial water. A new approach was used to derive the recoil ejection factor based on BET measurements and the fractal dimension of chalk surface. Consideration of preferential leaching and recoil allows a more accurate modeling of weathering rates.