Changes in water quality following tidal inundation of coastal lowland acid sulfate soil landscapes

This study examines the remediation of surface water quality in a severely degraded coastal acid sulfate soil landscape. The remediation strategy consisted of partial restoration of marine tidal exchange within estuarine creeks and incremental tidal inundation of acidified soils, plus strategic liming of drainage waters. Time-series water quality and climatic data collected over 5 years were analysed to assess changes in water quality due to this remediation strategy. A time-weighted rainfall function (TWR) was generated from daily rainfall data to integrate the effects of antecedent rainfall on shallow groundwater levels in a way that was relevant to acid export dynamics. Significant increases in mean pH were evident over time at multiple monitoring sites. Regression analysis at multiple sites revealed a temporal progression of change in significant relationships between mean daily electrical conductivity (EC) vs. mean daily pH, and TWR vs. mean daily pH. These data demonstrate a substantial decrease over time in the magnitude of creek acidification per given quantity of antecedent rainfall. Data also show considerable increase in soil pH (2–3 units) in formerly acidified areas subject to tidal inundation. This coincides with a decrease in soil pe, indicating stronger reducing conditions. These observations suggest a fundamental shift has occurred in sediment geochemistry in favour of proton-consuming reductive processes. Combined, these data highlight the potential effectiveness of marine tidal inundation as a landscape-scale acid sulfate soil remediation strategy.     

The mesoscale variability in the Caribbean Sea. Part II: Energy sources

The processes which drive the production and the growth of the strong mesoscale eddy field in the Caribbean Sea are examined using a general circulation model. Diagnostics of the simulations suggest that:(1) The mean currents in the Caribbean Sea are intrinsically unstable. The nature of the instability and its strength vary spatially due to strong differences of current structure among basins.(2) The greatest and most energetic eddies of the Caribbean Sea originate in the Venezuela Basin by mixed barotropic-baroclinic instability of an intense jet, formed with waters mostly from the surface return flow of the Meridional Overturning Circulation and the North Equatorial Current which converge and accelerate through the Grenada Passage. The vertical shear of this inflow is enhanced by an eastward undercurrent, which flows along the south American Coast between 100 and 250 m depth. The shallow eddies (less than 200 m depth) formed in the vicinity of the Grenada Passage get rapidly deeper (down to 1000 m depth) and stronger by their interaction with the deep interior flow of the Subtropical Gyre, which enters through passages north of St. Lucia. These main eastern Caribbean inflows merge and form the southern Caribbean Current, whose baroclinic instability is responsible for the westward growth and strengthening of these eddies from the Venezuela to the Colombia Basin.(3) Eddies of lesser strength are produced in other regions of the Caribbean Sea. Their generation and growth is also linked with instability of the local currents. First, cyclones are formed in the cyclonic shear of the northern Caribbean Current, but appear to be rapidly dissipated or absorbed by the large anticyclones coming from the southern Caribbean. Second, eddies in the Cayman Sea, which impact the Yucatan region, are locally produced and enhanced by barotropic instability of the deep Cayman Current.(4) The role of the North Brazil Current (NBC) rings is mostly to act as a finite perturbation for the instability of the mean flow. Their presence near the Lesser Antilles is ubiquitous and they appear to be linked with most of the Caribbean eddies. There are some evidences that the frequency at which they form near the Grenada Passage is influenced by the frequency at which the NBC rings impinge the Lesser Antilles. But large Caribbean eddies also form without a close influence of any ring, and comparison between simulations shows that mean eddy kinetic energy and eddy population in the Caribbean Sea are not substantially different in absence or presence of NBC rings: their presence is not a necessary condition for the generation and growth of the Caribbean eddies.     

Agrometeorological Research and Applications Needed to Prepare Agriculture and Forestry to 21st Century Climate Change

The adaptation of agriculture and forestry to the climate of the twenty-first century supposes that research projects will be conducted cooperatively between meteorologists, agronomists, soil scientists, hydrologists, and modellers. To prepare for it, it is appropriate first of all to study the variations in the climate of the past using extensive, homogenised series of meteorological or phenological data. General circulation models constitute the basic tool in order to predict future changes in climate. They will be improved, and the regionalisation techniques used for downscaling climate predictions will also be made more efficient. Crop simulation models using input data from the general circulation models applied at the regional level ought to be the favoured tools to allow the extrapolation of the major trends on yield, consumption of water, fertilisers, pesticides, the environment and rural development. For this, they have to be validated according to the available agronomical data, particularly the available phenological series on cultivated crops. In addition, climate change would have impact on crop diseases and parasites, as well as on weeds. Very few studies have been carried out in this field. It is also necessary to quantify in a more accurate way the stocks and fluxes of carbon in large forest ecosystems, simulate their future, and assess the vulnerability of the various forest species to a change in climate. This is all the more important in that some propagate species choices must be made in the course of the next ten years in plantations which will experience changed climate. More broadly speaking, we shall have not only to try hard to research new agricultural and forestry practices which will reduce greenhouse gas emissions or promote the storage of carbon, but it will also be indispensable to prepare the adaptation of numerous rural communities for the climate change (with special reference to least developed countries in tropical areas, where malnutrition is a common threat). This can be accomplished with a series of new environmental management practices suited to the new climatic order.     

Scapolite stoichiometry

Over the range Ca/(Ca + Na) from zero to 0.75, scapolites vary linearly between Na₄Al₃Si₉O₂₄Cl and NaCa₃Al₅Si₇O₂₄CO₃, by means of a coupled replacement of Na₃Si₂Cl by Ca₃Al₂CO₃. Ca includes minor Sr, Na includes K, and CO₃ may include substantial SO₄. From Ca/(Ca + Na) = 0.75 to 1.00, variation is between NaCa₃Al₅Si₇O₂₄CO₃ and Ca₄Al₆Si₆O₂₄CO₃, by means of a coupled replacement of NaSi by CaAl, as in plagioclase. Anion substitution is complete at the 0.75 point. Recalculation of scapolite analyses on the basis of Al + Si atoms = 12.0, as suggested by computed unit cell contents, offers a reasonable basis for normalization of atomic proportions. On this basis, Ca + Sr + Na + K + Fe atoms total very close to 4.0. New limits on the minor element content of scapolite are proposed. In view of the inflection at 0.75, subdivision of the scapolites at Ca/(Ca + Na) ratios of 0.25, 0.5, and 0.75 seems more logical than the 0.2, 0.5, and 0.8 limits used hitherto for marialite, dipyre, mizzonite, and meionite.     

Protected nearshore shallow and deep subtidal rocky reef communities differ in their trophic diversity but not their nutritional condition

Large physical changes that alter reef macrobenthos and fish assemblages occur with increasing depth, so the biological processes that regulate communities at different depths are expected to diverge. We used analyses of stable isotopes (δ13C and δ15N) and fatty acids to establish whether shallow (11–25 m) and deep (45–75 m) warm-temperate reef communities within a South African marine protected area differ in their trophic organisation and nutritional condition. We found evidence of enhanced nutritional condition in plankton from the deeper reef as compared with the shallow reef based on the essential fatty acid content, but this effect was generally not observed in the macrobenthos or the fish communities. Community-based indices derived from the stable isotope data indicated that the shallow-reef community had significantly greater niche diversification (greater diversity of carbon sources at the base of the food web) and more niche space occupied than the deep-reef community. One obvious difference in available carbon sources between reef communities was the absence of benthic primary production on the deep reef, where light is limiting. Our results highlight that the decreased trophic diversity, and to an extent functional redundancy, associated with the simplification of food webs at depth may translate into greater vulnerability of deep reefs to disturbance.     

Identifying Common Decision Problem Elements for the Management of Emerging Fungal Diseases of Wildlife

Emerging infectious diseases (EIDs) of wildlife have characteristics that make them difficult to manage, leading to reactive and often ineffective management strategies. Currently, two fungal pathogens, Pseudogymnoascus destructans (Pd) and Batrachochytrium salamandrivorans (Bsal), are causing declines in novel host species. To improve the application of management strategies addressing the risk of these pathogens to North American wildlife, we queried wildlife managers about their concerns regarding managing populations of bats and amphibians potentially impacted by Pd and Bsal. Using these responses, we identified aspects of each decision problem that were shared across pathogens, regions and agencies – and found similarities in decision-problem elements for disease management. Reframing management problems as decisions can enable managers to identify similarities across EIDs, i.e. uncertainties within management actions, and improve reactive responses if proactive management is not possible. Such an approach recognizes context-specific constraints and identifies relevant uncertainties that must be reduced in developing a response.     

Constraining groundwater modeling with magnetic resonance soundings

Magnetic resonance sounding (MRS) is a noninvasive geophysical method that allows estimating the free water content and transmissivity of aquifers. In this article, the ability of MRS to improve the reliability of a numerical groundwater model is assessed. Thirty-five sites were investigated by MRS over a ～5000 km(2) domain of the sedimentary Continental Terminal aquifer in SW Niger. Time domain electromagnetic soundings were jointly carried out to estimate the aquifer thickness. A groundwater model was previously built for this section of the aquifer and forced by the outputs from a distributed surface hydrology model, to simulate the observed long-term (1992 to 2003) rise in the water table. Uncertainty analysis had shown that independent estimates of the free water content and transmissivity values of the aquifer would facilitate cross-evaluation of the surface-water and groundwater models. MRS results indicate ranges for permeability (K = 1 × 10(-5) to 3 × 10(-4) m/s) and for free water content (w = 5% to 23% m(3) /m(3) ) narrowed by two orders of magnitude (K) and by ～50% (w), respectively, compared to the ranges of permeability and specific yield values previously considered. These shorter parameter ranges result in a reduction in the model's equifinality (whereby multiple combinations of model's parameters are able to represent the same observed piezometric levels), allowing a better constrained estimate to be derived for net aquifer recharge (～22 mm/year).     

Biomass carbon storage and its sequestration potential of afforestation under natural forest protection program in China

Based on the data from China′s Seventh Forest Inventory for the period of 2004–2008, area and stand volume of different types and age-classes of plantation were used to establish the relationship between biomass density and age of planted forests in different regions of the country. Combined with the plantation area in the first-stage of the Natural Forest Protection(NFP) program(1998–2010), this study calculated the biomass carbon storage of the afforestation in the first-stage of the program. On this basis, the carbon sequestration potential of these forests was estimated for the second stage of the program(2011–2020). Biomass carbon storage of plantation established in the first stage of the program was 33.67 Tg C, which was majority accounted by protection forests(30.26 Tg C). There was a significant difference among carbon storage in different regions, which depended on the relationship of biomass carbon density, forest age and plantation area. Under the natural growth, the carbon storage was forecasted to increase annually from 2011 to 2020, reaching 96.03 Tg C at the end of the second-stage of the program in 2020. The annual growth of the carbon storage was forecasted to be 6.24 Tg C/yr, which suggested that NFP program has a significant potential for enhancing carbon sequestration in plantation forests under its domain.