Ilmenite composition in the Tellnes Fe–Ti deposit,SW Norway: fractional crystallization,postcumulus evolution and ilmenite–zircon relation

Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1 is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ), and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during stage 1, and (2) implies an increase of D _V^Ilm during stage 2, most likely related to a shift in fO₂. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite. The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content. The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO₂ from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

An analytical solution to multi-component NAPL dissolution equations

This note presents a novel method for determining the changing composition of a multi-component NAPL body dissolving into moving groundwater, and the consequent changes in the aqueous phase solute concentrations in the surrounding pore water. A canonical system of coupled non-linear governing equations is derived which is suitable for representation of both pooled and residual configurations, and this is solved. Whereas previous authors have handled such problems numerically, it is shown that these governing equations succumb to analytical solution. By a suitable substitution, the equations become decoupled, and the problem collapses to a single first-order equation. The final result is expressed implicitly, with time as a function of the number of moles of the least soluble component, m₁. The number of moles of each other component is expressed explicitly in terms of m₁. It is shown that the time-m₁ relationship has a well behaved inverse. An example is given in which the analytic solution is verified against traditional finite difference analysis, and its computational efficiency is shown.     

Field‐based and spectral indicators for soil erosion mapping in semi‐arid mediterranean environments (Coastal Cordillera of central Chile)

The Coastal Cordillera of central Chile is naturally sensitive to soil erosion due to moderate to steep slopes, intense winter rains when the vegetation cover is scarce, and deeply weathered granitic rocks. In 1965, 60 per cent of its surface was moderately to very severely eroded. Today this process is still largely active, but no data are currently available to evaluate the real extent, distribution and severity of soil degradation on a regional scale. This information is vital to support efficient soil conservation plans. A multi‐scale approach was implemented to produce regional land degradation maps based on remote sensing technologies. Fieldwork has shown that the surface colour or ‘redness’ and the density of coarse fragments are pertinent erosion indicators to describe a typical sequence of soil degradation in the context of mediterranean soil developed on granitic materials and micaschists. Field radiometric experiments concluded that both factors influence the reflectance of natural surfaces and can be modelled using radiometric indices accessible from most satellites operating in the optical domain, i.e. redness index and brightness index. Finally the radiometric indices were successfully applied to SPOT images to produce land degradation maps. Only broad classes of erosion status were discriminated and the detection of the degradation processes was only possible when most of the fertile layer had already been removed. This technology provides decision‐making information required to develop regional soil conservation plans and to prioritize actions between catchment areas, especially in vast inter‐tropical regions where spatialized data are not always readily available. Copyright © 2006 John Wiley & Sons, Ltd.     

Geomorphic and dendroecological impacts of slushflows in central Gaspé Peninsula (Québec, Canada)

Slushflows are rare phenomena in southeastern Canada. Here we report for the first time the occurrence of slushflows in a subalpine environment in eastern Canada (Mt. Albert, Gaspé Peninsula, Québec). Because nothing is known of their frequency- magnitude in the area, we reconstructed the chronology of slushflow events over the past century using dendrogeomorphic techniques based on impact scars, reaction wood and traumatic resin ducts. Slushflows contributed to the formation of a tongue-shaped accumulation of 17900 m² at the outlet of a firstorder drainage basin. The slushflow boulder tongue was composed of heterogeneous-sized, angular and unoriented clasts, which are markedly different from the sediments of an adjacent alluvial fan. Although movements were initiated above the subalpine forest limit, slushflows induced forest fragmentation along the treed slope. Three slushflow events were identified over the past century, in 1925, 1964 and 1988, respectively, which indicate exceptional initiation conditions and considerable geomorphic activity of individual events.     

Practical method for drawing a VGP path

A statistical method is proposed for the smoothing of polar wander paths and for giving their confidence limits by the mean of successive ellipses. The method is fully parametrical and is based on the relations between the inertia matrix and the parameters of the Fisher distribution, from which a bivariate form is deduced. An elementary tensorial calculation gives the parameters of the confidence ellipse around a vectorial weighted mean, for any unimodal set of vectors. This model can also be used for other statistical tests, wherever the rotational symmetry hypothesis is not consistent (i.e. the fold test).     

Modelling the relationship between magnetic fabric and strain in polymineralic rocks

We present a model that is applicable to the relatively frequent case of rocks in which the magnetic fabric is dominated by uniaxial paramagnetic minerals, and in which the deformation (pure shear) corresponds to the March-Fernandez model. Borradaile et al.'s procedure for the isolation of the magnetic fabric of monocrystals of anisotropic components allows us to obtain the magnetic properties equivalent to those of all the component minerals if they should be artificially aligned. In the case of real component minerals with similar shape parameters, χ (dependent on dimension ratio), these properties will correspond to those of a theoretical equivalent mineral. Therefore, finite strain and orientation tensors may be determined from magnetic fabric measurements of such polymineralic rocks.     

The product spectra of gravity and barometric pressure in Europe

A total of 111 000 hourly values of gravity and barometric pressure from stations in Europe is analysed. The data consist of two sets of records from Brussels, an early set of 36 000 h length and a more recent set of 21 000 h length, a set of records from Bad Homburg of 24 000 h length, and a set of records from Strasbourg of 30 000 h length. All of the gravity measurements were made with similar superconducting instruments and the pressure data were recorded simultaneously at each superconducting gravimeter site. The four sets of records have different time bases, and to bring out common features and suppress individual station systematic errors, the product spectrum is introduced. Spectral density estimates are first computed for a common spectral window for each record, and the product spectrum is formed by multiplying individual spectral estimates across records. The cumulative distribution function is found for the product spectrum and confidence intervals are calculated from it by iteration. The product spectrum in gravity reveals a triplet of resonances in the subtidal band which are shown by an automated computer search to be uniquely associated with the translational modes of the solid inner core. The product spectrum in barometric pressure clearly reveals the first 10 solar heating tides in the atmosphere, but otherwise does not show common features with the gravity product spectrum. In particular, the triplet of resonances in the subtidal band of the gravity product spectrum do not show up in the product spectrum of barometric pressure, climinating the atmosphere as their source.