Interactions between mean flow and finite-amplitude mesoscale eddies in a barotropic ocean

Abstract

For the purpose of deriving an analytical parametrization, oceanic mesoscale eddies are represented as a horizontally propagating wave field in a non-uniform environment. The mathematical analysis rests upon the assumption of scale disparity between a short eddy scale and a long mean-flow scale. The novelty resides in the treatment of finite-amplitude eddies, which, moreover, form either a band-like or a cell-like pattern. A barotropic ocean is chosen as a first step to illustrate the mathematical analysis, but dissipation is included. The main result is an analytical derivation of a mesoscale-eddy parametrization: the mean-flow equation contains Reynolds-stress terms which are computed from parameters of the eddy field, which, in turn, are predicted by separate evolution equations. Due to restrictive assumptions (barotropy, orthogonal waves,…), the parametrization established here should be viewed only as a first step toward the design of a more practical parameterization for large-scale modelling.     

Relations quantitatives entre les craies à silex et les formations résiduelles à silex de l’ouest du bassin de Paris

Résumé

Depuis plus d’un siècle, l’origine autochtone ou allochtone des formations résiduelles à silex (en abrégé RS : résidus à silex) par rapport aux craies a fait l’objet de multiples discussions. Pour répondre à ce problème, un bilan d’altération entre ces deux formations a été effectué. Il repose sur une connaissance précise des âges des craies-mères des RS et sur des comparaisons granulométrique et chimique entre craie et RS. Ces comparaisons s’appuient sur les quantités de silex contenues dans les craies et les RS, sachant que les silex sont reconnus comme autochtones et que leur degré de dissolution est calculé. Les résultats apportent des informations sur l’évolution crétacée du Bassin anglo-parisien, avec la mise en évidence de la craie du Maastrichtien dans le bassin de Paris et la reconstitution des épaisseurs de craie dissoutes. De plus, ils indiquent que la stratigraphie des craies est conservée dans les profils de RS. Ils montrent également que les silex, éléments autochtones des RS, sont faiblement altérés. Les matrices des RS sont, quant à elles, en grande partie allochtones, notamment dans les dix mètres supérieurs de la formation. L’allochtonie diminue avec la profondeur, avec des RS pouvant être considérés comme des résidus d’altération de la craie au sens strict à partir de 20 mètres de profondeur. © Elsevier, Paris     

Geodynamic evolution of the Tethyan lithosphere as recorded in the Spontang Ophiolite,South Ladakh ophiolites(NW Himalaya,India)

The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable⁸⁷ Sr/⁸⁶ Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.     

Sedimentation rates in flow-restricted and restored salt marshes in Long Island Sound

Many salt marshes in densely populated areas have been subjected to a reduction in tidal flow. In order to assess the impact of tidal flow restriction on marsh sedimentation processes, sediment cores were collected from flow-restricted restricted salt marshes along the Connecticut coast of Long Island Sound. Cores were also collected from unrestricted reference marshes and from a marsh that had been previously restricted but was restored to fuller tidal flushing in the 1970's. High bulk densities and low C and N concentrations were found at depth in the restricted marsh cores, which we attribute to a period of organic matter oxidation, sediment compaction, and marsh surface subsidence upon installation of flow restrictions (between 100 and 200 years before the present, depending on the marsh). Recent sedimentation rates at the restricted marshes (as determined by¹³⁷Cs and²¹⁰Pb dating) were positive and averaged 78% (¹³⁷Cs) and 50% (²¹⁰Pb) of reference marsh sedimentation rates. The accumulation of inorganic sediment was similar at the restricted and reference marshes, perhaps because of the seasonal operation of the tide gates, while organic sediment accretion (and pore space) was significantly lower in the restricted marshes, perhaps because of higher decomposition rates. Sedimentation rates at the restored marsh were significantly higher than at the reference marshes. This marsh has responded to the higher water levels resulting from restoration by a rapid increase in marsh surface elevation.     

Heavy metal removal efficiencies in a river–marsh system estimated from patterns of metal accumulation in sediments

Estuaries have long been thought to be effective traps for river-borne contaminants; however, accurately predicting removal efficiencies remains problematic. In the Quinnipiac River, CT, marsh system, patterns of metal accumulation (Ag, Cd, Cu, Pb) in sediments were used to estimate heavy metal removal efficiencies. Linear and multivariate regression models were fit to sediment metal concentrations to estimate removal curves and surfaces, which avoided the large temporal variability commonly encountered when using direct water column measurements. Second order regressions normalized to the shortest distance to the river channel were found to have the best fit (r>0.67) with the lowest standard error (<32%). The heavy metal removal efficiencies estimated by comparing total metal accumulation in marsh sediments with riverine flux were Ag=21%, Cd=6%, Cu=14%, and Pb=17%, which are comparable to the maximum removal efficiency of riverine suspended particulate matter (28%).     

Phase changes and thermodynamic properties of CaTiO3. Spectroscopic data,vibrational modelling and some insights on the properties of MgSiO3 perovskite

The effect of pressure (up to 21 GPa at room temperature) and temperature (up to 1570 K at room pressure) on the Raman spectrum of CaTiO₃ is presented. No significant changes, which could be attributed to a major structural change, are observed in the spectra up to 22 GPa. The pressure shifts of the Raman modes can be related to a significant compression of the Ti-O bond. Discontinuous changes in the spectra upon heating may be related to phase changes observed by calorimetry and X-ray diffraction. The important temperature shifts of some low-frequency modes can be related to an increase in the Ti-O-Ti angle in agreement with the X-ray data showing a decrease of the structural distortion with increasing temperature. These data are compared to those available for MgSiO₃-perovskite and show that CaTiO₃ is a good structural analogue for MgSiO₃-perovskite. The present spectroscopic data are used to calculate the specific heat and entropy of CaTiO₃. The role of the low frequency modes in the calculations is emphasized. Good agreement is observed between calculated and experimentally determined values in the 0–1300 K temperature range. A similarly defined model is proposed for MgSiO₃-perovskite. It is found that the entropy lies between 57 and 64 J/mol/K at 298 K and between 190 and 200 J/mol/K at 1000 K in agreement with the values inferred from experimental equilibrium data. Finally we briefly discuss the values of the Grüneisen parameters of both perovskites inferred from macroscopic and microscopic data.     

Injection experiments and thermal recovery in corehole OH-1, Lake City,California

Two injection tests, shallow and deep, followed by repeated temperature logging were performed in the Lake City, California OH-1 corehole, to delineate permeable zones, investigate the permeability of rocks adjacent to the wellbore, and to test the validity of maximum-reading thermometer (MRT) measurements collected during the drilling process that show lower than static temperatures above a depth of 2100 ft and significantly higher than static temperatures below a depth of about 2500 ft. The tests confirmed several permeable zones in OH-1. At about 300 ft, there is a strong zone of lateral flow, and at 947 ft there is a major outflow zone for injected fluid. Two other possible permeable flow zones were detected from the thermal recovery logs: one at about 1500 ft and another at about 2300 ft. The 2300 ft permeable zone seems to be an inflow zone, and the source of a probable downflow responsible for cooling the wellbore below about 2500 ft. The hotter MRT data obtained during drilling may be reconciled with the significantly lower static temperature logs if downflow from about 2300 ft is present.     

Rift propagation at craton margin.: Distribution of faulting and volcanism in the North Tanzanian Divergence (East Africa) during Neogene times

A revised kinematic model is proposed for the Neogene tectono-magmatic development of the North Tanzanian Divergence where the axial valley in S Kenya splits southwards into a wide diverging pattern of block faulting in association with the disappearance of volcanism. Propagation of rifting along the S Kenya proto-rift during the last 8 Ma is first assumed to have operated by linkage of discrete magmatic cells as far S as the Ngorongoro–Kilimanjaro transverse volcanic belt that follows the margin of cratonic blocks in N Tanzania. Strain is believed to have nucleated throughout the thermally-weakened lithosphere in the transverse volcanic belt that might have later linked the S Kenya and N Tanzania rift segments with marked structural changes along-strike. The North Tanzanian Divergence is now regarded as a two-armed rift pattern involving: (1) a wide domain of tilted fault blocks to the W (Mbulu) that encompasses the Eyasi and Manyara fault systems, in direct continuation with the Natron northern trough. The reactivation of basement fabrics in the cold and intact Precambrian lithosphere in the Mbulu domain resulted in an oblique rift pattern that contrasts with the orthogonal extension that prevailed in the Magadi–Natron trough above a more attenuated lithosphere. (2) To the E, the Pangani horst-like range is thought to be a younger (< 1 Ma) structure that formed in response to the relocation of extension S of the Kilimanjaro magmatic center. A significant contrast in the mechanical behaviour of the stretched lithosphere in the North Tanzanian diverging rift is assumed to have occurred on both sides of the Masai cratonic block with a mid-crustal decoupling level to the W where asymmetrical fault-basin patterns are dominant (Magadi–Natron and Mbulu), whereas a component of dynamical uplift is suspected to have caused the topographic elevation of the Pangani range in relation with possible far-travelled mantle melts produced at depth further N.     

Investigating possible links between the North Atlantic Oscillation and rainfall variability in Marrakech (Morocco)

Eighty-two-year rainfall time series have been studied together with climatic patterns of NAO using classical statistical methods. Then, the wavelet approach has been applied to show annual (1 year (1y)) and inter-annual (2–4 years (2-4y), 5–8 years (5-8y), and 8–16 years (8-16y)) modes distributed following four major discontinuities: 1945, 1960, 1975, and 1995. The 1y, 2-4y, and 5-8y powers show high energy during the wet period 1922–1930 and a low one in 1928–1938. After 1945, the annual mode highlights a high energy while the inter-annual modes present low energy. Between 1975 and 1995, powerful modes of 1 and 2–4 years are identified with low power of 5-8y and 8-16y modes. Since 1995, the low power of 5–8y decreases, while the 8-16y mode emphasizes a high variability. The coherence between NAO and Marrakech precipitation is strongly defined for low frequencies with a total contribution of 75 %. This coherence is in phase in the beginning and presents out phase signs since 1945. The change of phase can be associated to a decreasing of coherence especially around 1990. This finding is useful to understand the relationship between the hydrological variability and NAO climate patterns in the southern side of the Mediterranean Sea.