Assessment of the Design of an Experimental Cover with Capillary Barrier Effect Using 4 Years of Field Data

One important step in the design of inclined covers with capillary barrier effect (CCBE) is the determination of the water diversion length (DL). Numerical simulations can predict the DL more precisely than steady-state analytical solutions. Nevertheless, as simplified methods have always been part of engineering design, the application of analytical solutions with conservative boundary conditions, may allow engineers to make reasonable predictions, particularly during the pre-feasibility stage of a project. In this study, a CCBE was designed, constructed and instrumented at the Saint-Tite-des-Caps landfill, Quebec, Canada. This CCBE included a seepage control layer superimposing a sand-gravel capillary barrier. The seepage control layer was made up of deinking by-products (DBP), an industrial by-product that was previously disposed of as waste. The capillary barrier was designed using an adaptation of the Ross analytical solution and the scenario considered was that of steady-state flow during constant seepage flow applied uniformly at the top of the sand-gravel capillary barrier. Although these conditions appear simplistic, they were deemed reasonable because placement of the seepage control layer on the top of the capillary barrier led to very low suctions at the interface, thereby allowing uniform downward seepage rates, limited by the saturated hydraulic conductivity of the DBP. In this paper, a discussion about the behaviour of the cover system based on 4 years of field data from several instruments is presented. The challenge of using DBP, more precisely the settlement of the DBP layer and its impact on k _sat , is also assessed. The DL was reassessed considering the new k _sat . A discussion on the validity of employing analytical solutions to determine DL is also presented. This paper illustrates how certain variables affect the design of inclined CCBEs that include a highly compressible material as seepage control layer.     

The natural thermoluminescence of meteorites VI: Carbon-14, thermoluminescence and the terrestrial ages of meteorites

Abstract Research on meteorite finds, especially those from the Antarctic and from desert regions in Australia, Africa, and America, has become increasingly important, notably in studies of possible changes in the nature of the meteorite flux in the past. One important piece of information needed in the study of such meteorites is their terrestrial age which can be determined using a variety of methods, including ¹⁴C, ³⁶Cl, and ⁸¹Kr. Natural thermoluminescence (TL) levels in meteorites can also be used as an indicator of terrestrial age. In this paper, we compare ¹⁴C-determined terrestrial ages with natural TL levels in finds from the Prairie States (central United States), a group of finds from Roosevelt County (New Mexico, USA), and a group from the Sahara Desert. We find that, in general, the natural TL data are compatible with the ¹⁴C-derived terrestrial ages using a 20 °C TL decay curve for the Prairie States and Roosevelt County and a 30 °C decay curve for the Saharan meteorites. We also present TL data for a group of meteorites from the Sahara desert which has not been studied using cosmogenic radionuclides. Within these data there are distinct terrestrial age clusters which probably reflect changes in meteorite preservation efficiency over ～ 15, 000 years in the region.     

Properties of chondrules in EL3 chondrites,comparison with EH3 chondrites,and the implications for the formation of enstatite chondrites

Abstract— The study of chondrules provides information about processes occurring in the early solar system. In order to ascertain to what extent these processes played a role in determining the properties of the enstatite chondrites, the physical and chemical properties of chondrules from three EL3 chondrites and three EH3 chondrites have been examined by optical, cathodoluminescence (CL), and electron microprobe techniques. Properties examined include size, texture, CL, and composition of both individual phases and bulk chondrules. The textures, distribution of textures, and composition of silicates of the EL3 chondrules resemble those of EH3 chondrules. However, the chondrules from the two classes differ in that (1) the size distribution of the EL chondrules is skewed to larger values than EH chondrules, (2) the enstatite in EL chondrules displays varying shades of red CL due to the presence of fine‐grained sulfides and metal in the silicates, and (3) the mesostasis of EH chondrules is enriched in Na relative to that of EL chondrules. The similarities between the chondrules of the two classes suggest similar precursor materials, while the differences suggest that there was not a single reservoir of meteoritic chondrules, but that their origin was fairly local. The differences in the size distribution of chondrules in EH and EL chondrites may be explained by aerodynamic and gravitational sorting during accumulation of the meteoric material, while differences in CL and mesostasis properties may reflect differences in formation conditions and cooling rate following chondrule formation. We argue that our observations are consistent with the formation of enstatite chondrites in a thick dynamic regolith on their parent body.     

Investigation of biological, chemical and physical processes on and in planetary surfaces by laboratory simulation

The recently established Arkansas-Oklahoma Center for Space and Planetary Science has been given a large planetary simulation chamber by the Jet Propulsion Laboratory, Pasadena, California. When completely refurbished, the chamber will be dubbed Andromeda and it will enable conditions in space, on asteroids, on comet nuclei, and on Mars, to be reproduced on the meter-scale and surface and subsurface processes monitored using a range of analytical instruments. The following projects are currently planned for the facility. (1) Examination of the role of surface and subsurface processes on small bodies in the formation of meteorites. (2) Development of in situ sediment dating instrumentation for Mars. (3) Studies of the survivability of methanogenic microorganisms under conditions resembling the subsurface of Mars to test the feasibility of such species surviving on Mars and identify the characteristics of the species most likely to be present on Mars. (4) The nature of the biochemical “fingerprints” likely to have been left by live organisms on Mars from a study of degradation products of biologically related molecules. (5) Testing local resource utilization in spacecraft design. (6) Characterization of surface effects on reflectivity spectra for comparison with the data from spacecraft-borne instruments on Mars orbiters.     

Volcanic Markers of the Post-Subduction Evolution of Baja California and Sonora, Mexico: Slab Tearing Versus Lithospheric Rupture of the Gulf of California

The study of the geochemical compositions and K-Ar or Ar-Ar ages of ca. 350 Neogene and Quaternary lavas from Baja California, the Gulf of California and Sonora allows us to discuss the nature of their mantle or crustal sources, the conditions of their melting and the tectonic regime prevailing during their genesis and emplacement. Nine petrographic/geochemical groups are distinguished: ??regular?? calc-alkaline lavas; adakites; magnesian andesites and related basalts and basaltic andesites; niobium-enriched basalts; alkali basalts and trachybasalts; oceanic (MORB-type) basalts; tholeiitic/transitional basalts and basaltic andesites; peralkaline rhyolites (comendites); and icelandites. We show that the spatial and temporal distribution of these lava types provides constraints on their sources and the geodynamic setting controlling their partial melting. Three successive stages are distinguished. Between 23 and 13 Ma, calc-alkaline lavas linked to the subduction of the Pacific-Farallon plate formed the Comondú and central coast of the Sonora volcanic arc. In the extensional domain of western Sonora, lithospheric mantle-derived tholeiitic to transitional basalts and basaltic andesites were emplaced within the southern extension of the Basin and Range province. The end of the Farallon subduction was marked by the emplacement of much more complex Middle to Late Miocene volcanic associations, between 13 and 7 Ma. Calc-alkaline activity became sporadic and was replaced by unusual post-subduction magma types including adakites, niobium-enriched basalts, magnesian andesites, comendites and icelandites. The spatial and temporal distribution of these lavas is consistent with the development of a slab tear, evolving into a 200-km-wide slab window sub-parallel to the trench, and extending from the Pacific coast of Baja California to coastal Sonora. Tholeiitic, transitional and alkali basalts of subslab origin ascended through this window, and adakites derived from the partial melting of its upper lip, relatively close to the trench. Calc-alkaline lavas, magnesian andesites and niobium-enriched basalts formed from hydrous melting of the supraslab mantle triggered by the uprise of hot Pacific asthenosphere through the window. During the Plio-Quaternary, the ??no-slab?? regime following the sinking of the old part of the Farallon plate within the deep mantle allowed the emplacement of alkali and tholeiitic/transitional basalts of deep asthenospheric origin in Baja California and Sonora. The lithospheric rupture connected with the opening of the Gulf of California generated a high thermal regime associated to asthenospheric uprise and emplaced Quaternary depleted MORB-type tholeiites. This thermal regime also induced partial melting of the thinned lithospheric mantle of the Gulf area, generating calc-alkaline lavas as well as adakites derived from slivers of oceanic crust incorporated within this mantle.     

Exposure of developing countries to sea-level rise and storm surges

An increase in sea surface temperature is strongly evident at all latitudes and in all oceans. The scientific evidence to date suggests that increased sea surface temperature will intensify cyclone activity and heighten storm surges. The paper assesses the exposure of (coastal) developing countries to sea-level rise and the intensification of storm surges. Geographic Information System (GIS) software is used to overlay the best available, spatially-disaggregated global data on critical exposed elements (land, population, GDP, agricultural extent and wetlands) with the inundation zones projected with heightened storm surges and a 1 m sea-level rise. Country-level results indicate a significant increase in exposure of developing countries to these climate-induced changes.     

New insight into the structure of nanocrystalline ferrihydrite: EXAFS evidence for tetrahedrally coordinated iron(III)

Ferrihydrite (Fh) is a short-range ordered nanocrystalline iron(III) (oxyhydr)oxide that has been recognized to play an important role in contaminant sequestration and in iron cycling in geological and biological systems. Despite intensive research for the two last decades, the structure of Fh is still a subject of debate. In the present study, we report extended X-ray absorption fine structure (EXAFS) spectroscopy data collected on a large set of ferrihydrites and model compounds samples including especially nano-crystalline maghemite (Mh), goethite (Gt), and akaganeite (Aka). This set of EXAFS data recorded at cryogenic temperature over a wide energy range allows us to precisely determine the Fe-O mean distance (〈Fe-O〉) in the first coordination shell of iron for this large set of iron (oxyhydr)oxides. Our EXAFS analysis includes both classical shell-by-shell fits of Fourier-filtered and unfiltered data as well as analysis of Fe-O distance distribution in the first coordination shell of iron using the Landweber iteration method. 〈Fe-O〉 determined by these complementary EXAFS analyses are similar: 〈Fe-O〉 is shorter in Mh (1.96 ± 0.01 Å) that contains 37.5% of tetrahedral iron, than in Gt (2.01 ± 0.01 Å), Aka (2.00 ± 0.01 Å) and hematite (Hm) (2.01 ± 0.01 Å) that do not contain tetrahedral iron. 〈Fe-O〉 for the five Fh samples investigated (1.97 ± 0.01 Å) was found to be slightly longer than in Mh and significantly shorter than those in Gt, Aka and Hm. This short 〈Fe-O〉 distance in Fh indicates the presence of significant amount of tetrahedrally coordinated iron(III) in all Fh samples studied, which ranges between 20 ± 5% and 30 ± 5% of total iron. In addition, our analysis of Fe-Fe distances observed by EXAFS is consistent with a Keggin-like motif at a local scale (∼5 Å) in the Fh structure.     

The significance of stretching lineations in terms of progressive deformation and finite strain

Abstract

For a given increment of deformation, stretching lineations can be defined either by old grains or by new grains.

Progressive strain accumulated in a matrix causes reorientation of old grains. The velocity field acting within a grain depends on the degree of non-coaxiality of the progressive strain in the matrix, and on the competence contrast between grain and matrix (e.g. Lister & Williams, 1983). Deformed populations of old grains do not systematically track the principal directions of finite stretch; this depends on the mechanical behavior of the grains. On the other hand, these populations may be good markers of finite strain magnitude, provided that the initial distribution is known.

In contrast, the statistical shape orientation distribution of population of new grains cannot be related in a simple way to the finite strain magnitude, but their preferred orientation is considered to be the best indicator of the principal directions of finite stretch.

An example is considered from the schistes lustrés near Kenestrelle (Val Chisone, Western Alps), where the observed mineral lineation is attributed to a late E-W stretching event in the alpine orogenic history.     

Suitability of a lumped rainfall–runoff model for flashy tropical watersheds in New Caledonia

ABSTRACT

The GR4H lumped hourly rainfall–runoff model was assessed for its integration in a ridge-to-reef modelling framework. Particular attention was paid to rainfall representation, robustness of parameter estimates and ability to reproduce the main runoff features. The study was conducted in four tropical mountainous watersheds in New Caledonia, which are exposed to intense rainfall events, large annual climatic variations triggered by El Niño oscillation, and wildfires. The inverse distance and elevation weighting algorithm outperformed other classical rainfall interpolation methods under data-limited conditions. The time span of data needed for robust calibration was site specific and varied from 6–7 years to 10 years, which may be linked to El Niño events and to wildfires. With sufficient data, simulation quality was equivalent during the calibration and validation periods. The GR4H model was generally able to simulate both flash floods and large annual variations. The model was more reliable when simulating wet years and watersheds not subject to land-cover changes.