Catchments as reactors: a comprehensive approach for water fluxes and solute turnover

Sustainable water quality management requires a profound understanding of water fluxes (precipitation, run-off, recharge, etc.) and solute turnover such as retention, reaction, transformation, etc. at the catchment or landscape scale. The Water and Earth System Science competence cluster (WESS, http://www.wess.info/) aims at a holistic analysis of the water cycle coupled to reactive solute transport, including soil–plant–atmosphere and groundwater–surface water interactions. To facilitate exploring the impact of land-use and climate changes on water cycling and water quality, special emphasis is placed on feedbacks between the atmosphere, the land surface, and the subsurface. A major challenge lies in bridging the scales in monitoring and modeling of surface/subsurface versus atmospheric processes. The field work follows the approach of contrasting catchments, i.e. neighboring watersheds with different land use or similar watersheds with different climate. This paper introduces the featured catchments and explains methodologies of WESS by selected examples.     

Structural characterization of vitrinite-rich and inertinite-rich Permian-aged South African bituminous coals

Two South African coals of the same rank and age, but different in maceral composition were subjected to extensive structural analyses. Inertinite-rich Highveld coal (dominated by semifusinite) and vitrinite-rich Waterberg coal were studied to determine structural differences and similarities. The two coals had similar carbon content ( 84%, dmmf) and vitrinite reflectance (mean-maximum 0.71% for vitrinite-rich vs. 0.75% for inertinite-rich), but differed in hydrogen content (6.23% for vitrinite-rich and 4.53% for inertinite-rich). The inertinite-rich coal was more aromatic (86% for inertinite-rich and 76% for vitrinite-rich) and more polycondensed (indicated by a higher bridgehead carbon content). The inertinite-rich coal was structurally more ordered, with a higher degree of crystalline stacking. Both coals had similar average aromatic cluster sizes (16 carbons for vitrinite-rich and 18 carbons for inertinite-rich) and number of cluster attachments (6 attachments for vitrinite-rich and 5 attachments for inertinite-rich). Mass spectrometry showed that both coals consist of similar molecular weight distributions; ranging to approximately 1700 m/z with a maximum abundance of  450 m/z for the vitrinite-rich coal and  550 m/z for the inertinite-rich coal. Compared to the Argonne Premium coals the South African vitrinite-rich Waterberg coal was comparable to the coals in the high-volatile bituminous range and inertinite-rich Highveld was closer to the medium- to low-volatile bituminous range. Both coals were surprisingly similar in bulk characterization, although inertinite-rich Highveld coal was structurally more ordered, hydrogen deficient, and more aromatic.     

印度南部麻粒岩地体Namakkal陆块新太古代钙硅酸盐岩的岩石学和锆石U-Pb年代学研究

本文对印度南部麻粒岩地体Namakkal陆块Tammampatti地区方柱石石榴子石钙硅酸盐岩进行了详细的岩石学、锆石U-Pb年代学和变质相平衡模拟研究,以研究其岩石成因和地质意义。岩相学观察识别出两阶段变质矿物组合:第一阶段为石榴子石+方柱石+斜长石+榍石+钛铁矿;第二阶段为石榴子石边部的绿帘石和方柱石边缘的方解石、斜长石和石英冠状体。CL图像分析显示锆石可分为两种,分别为高亮度和低亮度的变质锆石。LA-ICP-MS锆石U-Pb定年得到高亮度变质锆石~(207)Pb/~(206)Pb加权平均年龄为2562±17Ma,而低亮度变质锆石的~(207)Pb/~(206)Pb加权平均年龄稍年轻,为2495±15Ma。基于相平衡模拟计算了2个样品18ID-24和18ID-25的P-T视剖面图,确定它们峰期变质PT条件分别为4.3～7.1kbar、800～960℃和4.0～7.8kbar、750～854℃。高亮度变质锆石年龄2562±17Ma与Namakkal陆块紫苏花岗岩的原岩结晶年龄相当,其代表了紫苏花岗岩的原岩侵入导致的接触交代变质作用形成方柱石石榴子石钙硅酸盐岩的时代;低亮度变质锆石年龄2495±15Ma与该地区大约2530～2440Ma的高温-超高温变质作用时代相吻合,因此认为其代表区域性变质作用叠加的时代。根据全岩成分以及矿物组合,我们推测该岩石为中酸性岩浆岩(紫苏花岗岩原岩)与碳酸盐岩发生交代变质作用的产物。     

Marine radar interrogator-transponder

The use of ship's radar for collision avoidance presents a fundamental problem in threat detection and identification since all vessel radar returns ("paints") look alike. As a result, when a ship master caught in a fog is trying to use his radio-telephone to work out a maneuvering plan with another vessel, it is difficult for him to identify which blip on the planar position indicator PPI is the source of the voice on the radio. One solution now receiving worldwide attention is to fit all vessels with active transponders. The marine radar interrogator-transponder (MRIT) is an advanced form of transponder which includes an integral interrogator and works in coordination with the ship radar to provide not only target identity and "clutter-free" target paints, but also maneuvering information and such data as target's course, speed, draft, safe or dangerous cargo, etc. Mounted on a fixed navigation aid, the transponder portion alone can also function as a racon (radar beacon). This paper describes the operational parameter and reviews the system bench tests and sea trials.     

Rare earth elements in the phosphatic-enriched sediment of the Peru shelf

Apatite-enriched materials from the Peru shelf have been analyzed for their major oxide and rare earth element (REE) concentrations. The samples consist of (1) the fine fraction of sediment, mostly clay material, (2) phosphatic pellets and fish debris, which are dispersed throughout the fine-grained sediment, (3) tabular-shaped phosphatic crusts, which occur within the uppermost few centimeters of sediment, and (4) phosphatic nodules, which occur on the seafloor. The bulk REE concentrations of the concretions suggest that these elements are partitioned between the enclosed detrital material and the apatite fraction. Analysis of the fine-grained sediment with which the samples are associated suggested that this detrital fraction in the concretions should have shale REE values; the analysis of the fish debris suggested that the apatite fraction might have seawater values. The seawater contribution of REE's is negligible in the nodules and crust, in which the apatite occurs as a fine-grained interstitial cement. That is, the concentration of REE's and the REE patterns are predominantly a function of the amount of enclosed fine-grained sediment. By contrast, the REE pattern of the pelletal apatite suggests a seawater source and the absolute REE concentrations are relatively high. The REE/P₂O₅ ratios of the apatite fraction of these samples thus vary from approximately zero (in the case of the crust and nodules) to as much as approximately 1.2 × 10⁻³ (in the case of the pellets). The range of this ratio suggests that rather subtle variations in the depositional environment might cause a significant variation in the REE content of this authigenic fraction of the sediment.

Pelletal glauconite was also recovered from one sediment core. Its REE concentrations closely resemble those of the fish debris.     

Remote Sensing Data Acquisition,Platforms and Sensor Requirements

Although data available from various earth observation systems have been routinely used in many resource applications, however there have been gaps, and data needs of applications at different levels of details have not been met. There is a growing demand for availability of data at higher repetivity, at higher spatial resolution, in more and narrower spectral bands etc. Some of the thrust areas of applications particularly in the Indian context are;

1. Management of natural resources to ensure sustainable increase in agricultural production,
2. Study the state of the environment, its monitoring and assessment of the impact of. various development actions on the environment,
3. Updating and generation of large scale topographical maps.
4. Exploration/exploitation of marine and mineral resources and
5. Operational meteorology and studying various land and oceanic processes to understand/predict global climate changes.

Each of these thrust area of application has many components, related to basic resource areas such as agriculture, forestry, water resources, minerals, marine resources etc. and the field of cartography. Observational requirements for major applications have been summarized as under. Monitoring vegetation health from space remains the most important observational parameter with applications, in agriculture, forestry, environment, hydrology etc. Vegetation extent, quantity and temporal changes are the three main requirements which are not fully realized with RS data available. Vegetation productivity, forest biomass, canopy moisture status, canopy biogeochemistry are some examples. Crop production forecasting is an important application area. Remotely sensed data has been used for identification of crops and their acreage estimation. Fragmented holdings, large spread in crop calendars and different management practices continue to pose a challenge lo remote sensing. Remotely sensed data at much higher spatial resolution than hitherto available as well as at greater repetivity are required to meet this need. Non-availability of cloud-free data in the kharif season is one of the serious problems in operational use of remote sensing for crop inventory. Synthetic aperture radar data al X & Ku bands is necessary to meet this demand. Nutrient stress/disease detection requires observations in narrow spectral bands. In case of forestry applications, multispectral data at high spatial resolution of the order of 5 to 10 metres is required to make working plans at forest compartment level. Observations from space for deriving tree height are required for volume estimation. Observations in the middle infrared region would greatly enhance capability of satellite remote sensing in forest fire detection. Temporal, spatial and spectral observational requirements in various applications on vegetation viewing are diverse, as they address processes at different spatial and time scales. Hence, it would be worthwhile to address this issue in three broad categories. a) Full coverage, moderate spatial resolution with high repetivity (drought, large scale deforestation, forest phenology....). b) Full coverage, moderate to high spatial resolution and high repetivity (crop forecasting, vegetation productivity). c) Selected viewing at high spatial resolution, moderate to high repetivity and with new dimensions to imaging (narrow spectral bands, different viewing angles). A host of agrometeorological parameters are needed to be measured from space for their effective use in development of yield models. Estimation of root-zone soil moisture is an important area requiring radar measurements from space. Surface meteorological observations from space at the desired spatial and temporal distributions has not developed because of heavy demands placed on the sensor as well as analytical operational models. Agrometeorology not only provides quantitative inputs to other applications such as crop forecasting, hydrological models but also could be used for farmer advisory services by local bodies. Mineral exploration requires information on geological structures, geomorphology and lithology. Surface manifestation over localized regions requires large scale mapping while the lithology can be deciphered from specific narrow bands in visible. NIR, MIR and TIR regions. Sensors identified for mapping/cartography in conjunction with imaging spectrometer would seem to cover requirements of this application. Narrow spectral bands in the short regions which provide diagnostics of relevant geological phenomenon are necessary for mineral exploration. Thermal inertia measurements help in better discrimination of different rock units. Measurements from synthetic aperture data which would provide information on geological structures and geomorphology are necessary for mineral exploration. The applications related to marine environment fall in three major areas: (i) Ocean colour and productivity, biological resources; (ii) Land-ocean interface, this includes coastal landforms, bathymetry, littoral transport processes, etc. and; (iii) Physical oceanography, sea surface temperature, winds, wave spectra, energy and mass exchange between atmosphere and ocean. Measurement of chlorophyll concentration accurately on daily basis, sea surface temperature with an accuracy of 0.5 °K. and information on current patterns arc required for developing better fishery forecast models. Improved spatial resolution data are desirable for studying sediment and other coastal processes. Cartography is another important application area. The major problems encountered in relation to topographic map updation are location and geometric accuracy and information content. Two most important requirements for such an application are high spatial resolution data of 1 to 2 metre and stereo capability to provide vertical resolution of 1 metre. This requirement places stringent demands on the sensor specifications, geometric processing, platform stability and automated digital cartography. The requirements for the future earth observation systems based on different application needs can be summarized as follows:

1. Moderate spatial resolution (l50-300m), high repetivity (2 Days), minimum set of spectral bands (VIS, NIR, MIR. TIR) full coverage.
2. Moderate to high spatial resolution (20-40m), high repetivity (4-6 Days), spectral bands (VIS, MR, MIR, TIR) full coverage.
3. High spatial resolution (5-10m) muitispectral data with provision for selecting specific narrow bands (VIS, N1R. MIR), viewing from different angles.
4. Synthetic aperture radar operating in at least two frequencies (C, X, Ku), two incidence angles/polarizations, moderate to high spatial resolution (20-40m), high repetivity (4-6 Days).
5. Very high spatial resolution (1-2m) data in panchromatic band to provide terrain details at cadastral level (1:10,000).
6. Stereo capability (1-2m height resolution) to help planning/execution of development plans.
7. Moderate resolution sensor operating in VIS, NIR, MIR on a geostationary platform for observations at different sun angles necessary for the development of canopy reflectance inversion models.
8. Diurnal (at least two i.e. pre-dawn and noon) temperature measurements of the earth surface.
9. Ocean colour monitor with daily coverage.
10. Multi-frequency microwave radiometer, scatterometer. altimeter, atmospheric sounder, etc.

     

Competition between iron- and carbon-based colloidal carriers for trace metals in a freshwater assessed using flow field-flow fractionation coupled to ICPMS

Flow field-flow fractionation (FlFFF) coupled to an inductively coupled plasma mass spectrometer (ICPMS) has been used to determine the chemical composition of colloids from a freshwater sample as a function of size. Organic carbon and iron are the most abundant colloidal components, and are considered as the major carrier phases for other chemical elements present. The size distribution of organic carbon colloids shows a single peak with an estimated hydrodynamic diameter between 1 and 1.5 nm, while the iron colloids show a more complex distribution centred at larger colloid sizes with estimated hydrodynamic diameters up to 5 nm. The association of 32 trace elements with these two carrier colloids has been quantified by deconvolution analysis, and the resulting distributions are shown to be chemically consistent. The observed distributions are also shown to be broadly consistent with predictions from speciation modelling for the subset of 8 elements for which appropriate stability constants are available.     

Chandra Detection of Massive Black Holes in Galactic Cooling Flows

Anticipating forthcoming Chandra X-ray observations, we describe the continuation of interstellar cooling flows deep into the cores of elliptical galaxies. Interstellar gas heated to T>1 keV in the potential of massive black holes (r less, similar50 pc) should be visible unless thermal heating is diluted by nonthermal pressure. Since our flows are subsonic near the massive black holes, distributed cooling continues within approximately 300 pc. Dark, low-mass stars formed in this region may be responsible for some of the mass attributed to central black holes.     

Modelling plumes of overland flow from logging tracks

Most land‐based forestry systems use extensive networks of unsealed tracks to access the timber resource. These tracks are normally drained by constructing cross‐banks, or water bars, across the tracks immediately following logging. Cross‐banks serve three functions in controlling sediment movement within forestry compartments:

• 1. they define the specific catchment area of the snig track (also known as skid trails) so that the overland flow does not develop sufficient energy to cause gullies, and sheet and rill erosion is reduced;
• 2. they induce some sediment deposition as flow velocity reduces at the cross‐bank;
• 3. they redirect overland flow into the adjacent general harvesting area (GHA) so that further sediment deposition may take place.

This paper describes a simple model that predicts the third of these functions in which the rate of runoff from the track is combined with spatial attributes of the track and stream network. Predictions of the extent of the overland flow plumes and the volume of water delivered to streams is probabilistically presented for a range of rainfall‐event scenarios with rainfall intensity, time since logging and compartment layout as model inputs. Generic equations guiding the trade‐off between intercross‐bank length and flow path distance from cross‐bank outlet to the stream network needed for infiltration of track runoff are derived. Copyright © 2002 John Wiley & Sons, Ltd. Copyright © 2002 John Wiley & Sons, Ltd.     

A comparison between thomson scatter and meteor radar wind measurements in the 65–105 km altitude region at Arecibo

The results of simultaneous meteor and Thomson scatter radar wind measurements in the 65–105 km altitude region are presented. The two radars are located in Puerto Rico where the 430-MHz Thomson scatter radar at Arecibo Observatory is employed along with the French (CNET) portable meteor radar which is at a 40-km distance. The two sets of wind measurements compare quite favorably during periods of coincident observation. The meteor radar yields continuous results while the Thomson scatter radar is usable only during daylight hours. The Thomson scatter results, on the other hand, extend down to 65 km altitude and are available with better height and time resolutions than the meteor radar results. The two measurement techniques are therefore complementary.