The early diagenesis of aliphatic hydrocarbons and organic matter in sedimentary particulates from Dabob Bay,Washington

Aliphatic hydrocarbon compositions were quantitatively characterized in plankton, sediment trap-collected particulate materials and sediments from Dabob Bay using high resolution glass capillary gas chromatography. The average net accumulation of individual hydrocarbons measured in a 1-yr series of sediment traps was compared with the net accumulation of corresponding compounds measured in three depth intervals of ²¹⁰Pb-dated bottom sediments. Systematic and rapid decreases in the net accumulation of individual hydrocarbons were observed from the sediment traps to the sediments. Most pronounced decreases were measured for planktonically derived hydrocarbon constituents (e.g. pristane and two unsaturated compounds) which are rapidly remineralized at or near the sediment-water interface. Consequently, the amount of each compound measured in deposited sediments is not necessarily a quantitative indication of its initial flux to the sediments. The n-alkanes (C_25,27,29,31). characteristic of terrestrial plant waxes, are the predominant hydrocarbons measured by 4–6 cm depth in these sediments and show reasonably constant net accumulation below this interval.Significant diagenetic alteration of the bulk organic matter contained in the average sediment trap particulate material is also noted through comparison with bottom sediments on the basis of organic C/N and δ¹³C measurements. Organic matter elementally similar to marine plankton is preferentially remineralized upon deposition of the sedimentary particulates. The residual organic matter remaining and buried in the bottom sediments closely resembles terrestrial organic matter.     

The Influence of Place on the Willingness to Pay for Ecosystem Services

Sense of place, including an individual’s attitudes toward specific geographic settings, is generally predicted to influence willingness to engage in place-protective behaviors. Relatively little research, however, has empirically examined the influence of people’s attitudes toward a place on their willingness to pay for environmental protection. Using the example of a payment for ecosystem services (PES) initiative in the McKenzie River watershed, Oregon, USA, we found that place attitudes were a significant predictor of respondents’ willingness to pay for a program designed to benefit drinking water quality. These results suggest that connecting conservation actions to landscapes that are meaningful to people may increase their financial support for PES and other conservation programs. While program managers have little or no influence over stakeholders’ political ideology, gender, or income, managers may be able to influence prospective PES buyers’ awareness and attitudes through targeted communications, thereby potentially increasing support for place-based conservation efforts.     

Radiative association in Li+H revisited: the role of quasi-bound states

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.     

Effect of discharge on the chlorophylla distribution in the tidally-influenced Potomac River

In the tidal Potomac River, high river discharges during the spring are associated with high chlorophylla concentrations in the following in the following summer, assuming that summertime light and temperature conditions are favorable. Spring floods deliver large loads of particulate N and P to the tidal river. This particulate N and P could be mineralized by bacteria to inorganic N and P and released to the water column where it is available for phytoplankton use during summertime. However, during the study period relatively low concentrations of chlorophylla (less than 50 μg l^?1 occurred in the tidal river if average monthly discharge during July or August exceeded 200 m³s^?1. Discharge and other conditions combined to produce conditions favorable for nuisance levels of chlorophylla (greater than 100 μg l^?1 approximately one year out of four. Chlorophylla maxima occurred in the Potomac River transition zone and estuary during late winter (dinoflagellates) and spring (diatoms). Typical seasonal peak concentrations were achieved at discharges as high as 970 m³ s^?1, but sustained discharges greater than 1,100 m³ s^?1 retarded development. Optimum growth conditions occurred following runoff events of 10 to 15 d duration which produced transit times to the transition zone of 7 to 10 d. Wet years with numerous moderate-sized runoff events, such as 1980, tend to produce greater biomass in the transition zone and estuary than do dry years such as 1981.     

Movement patterns of an endangered fishery species,Lithognathus lithognathus (Sparidae), and the role of no-take marine protected areas as a management tool

Understanding movement behaviour is essential for effective management of fishery species. Dart tags were used to study coastal movement patterns of white steenbras Lithognathus lithognathus, an overexploited seabream (Sparidae) in South Africa. In total, 6 962 fish (190–1 080 mm fork length) were tagged throughout the species’ distributional range, in four long-term fish-tagging programmes. The predominant behaviour recorded was residency, with relatively short-ranging movements. More than 60% of the 351 recaptured fish were recaptured within 1 km of their tagging site, some of which were at liberty in excess of three years. Most of the juveniles (93.9%), subadults (71.7%) and adults (64.0%) were recaptured within 10 km. Occasional long-distance movements of up to 800 km were recorded. Recapture distances were positively, but weakly, correlated with fish fork length (n = 257 fish measured at recapture; r² = 0.166, p < 0.001). Low levels of connectivity among coastal areas suggest that large-scale annual spawning migrations, as previously hypothesised for this species, are unlikely, which raises the possibility of multiple spawning sites. Seventy-seven percent of L. lithognathus tagged within three marine protected areas (MPAs) were recaptured within the same MPA, suggesting that area closures provide protection for L. lithognathus through the post-estuarine juvenile, subadult and adult life stages. We confirm that the country’s current network of coastal MPAs plays a vital role in sustaining this species, and suggest that additional closures, or otherwise substantial reductions in catch rates, are necessary for the species’ recovery.     

Ecological status of seagrass ecosystems: An uncertainty analysis of the meadow classification based on the Posidonia oceanica multivariate index (POMI)

Quantifying the uncertainty associated with monitoring protocols is essential to prevent the misclassification of ecological status and to improve sampling design. We assessed the Posidonia oceanica multivariate index (POMI) bio-monitoring program for its robustness in classifying the ecological status of coastal waters within the Water Framework Directive. We used a 7-year data set covering 30 sites along 500 km of the Catalonian coastline to examine which version of POMI (14 or 9 metrics) maximises precision in classifying the ecological status of meadows. Five factors (zones within a site, sites within a water body, depth, years and surveyors) that potentially generate classification uncertainty were examined in detail. Of these, depth was a major source of uncertainty, while all the remaining spatial and temporal factors displayed low variability. POMI 9 matched POMI 14 in all factors, and could effectively replace it in future monitoring programs.     

Gold mineralisation at the Lady Bountiful Mine,Western Australia: An example of a granitoid-hosted Archaean lode gold deposit

The Lady Bountiful granitoid-hosted lode gold deposit, located in the mid-greenschist facies metamorphosed Ora Banda greenstone sequence, is hosted predominantly by the late-tectonic Liberty Granodiorite. Gold mineralisation is localised along quartz-veined, sinistral, brittle fault-zone(s) that transect the boundary between the Liberty Granodiorite and Mt Pleasant sill. Quartz vein textures indicate two stages of a single gold-related vein-development event, with high-grade gold mineralisation restricted to the second stage. Ore minerals include pyrite, chalcopyrite, pyrrhotite, galena, sphalerite, Au−Ag−Bi−Pb-tellurides, and native gold. Fluid infitration has resulted in narrow (<1 m) bleached wallrock alteration envelopes to the fault zones comprising albite-K-mica ±chlorite±calcite±rutile assemblages. Temperature-pressure conditions varied from Stage I (300°±50°C, ≈2 kbar) to Stage II (250°±50°C, ≈0.5 to 2 kbar), with the hydrothermal fluid in both stages characterised by X(CO₂)≤0.15 and moderate salinity (≈1.28 m NaCl). Intermittent phase separation of Stage II mineralising fluids, initiated by pressure fluctuations in dilational sites, and/or fluid-dominated fluid: wallrock interaction, are invoked as the dominant depositional mechanisms. The granitoid-hosted Lady Bountiful lode gold deposit shares many features with other granitoid-hosted lode gold deposits in the Yilgarn Craton and the Superior Province. Granitoid-hosted lode gold deposits, such as the Lady Bountiful deposit, provide additional evidence that the dominant control on the localisation of gold mineralisation within a granitoid host is structure, with competency contrasts playing a significant role. Furthermore, the hydrothermal wallrock alteraction and orefluid chemistry characteristics of the granitoid-hosted lode gold deposits are comparable to those established for greenstone-hosted lode gold mineralisation.     

Hydrothermal activity on the southern Mid-Atlantic Ridge: Tectonically- and volcanically-controlled venting at 4–5°S

We report results from an investigation of the geologic processes controlling hydrothermal activity along the previously-unstudied southern Mid-Atlantic Ridge (3–7°S). Our study employed the NOC (UK) deep-tow sidescan sonar instrument, TOBI, in concert with the WHOI (USA) autonomous underwater vehicle, ABE, to collect information concerning hydrothermal plume distributions in the water column co-registered with geologic investigations of the underlying seafloor. Two areas of high-temperature hydrothermal venting were identified. The first was situated in a non-transform discontinuity (NTD) between two adjacent second-order ridge-segments near 4°02′S, distant from any neovolcanic activity. This geologic setting is very similar to that of the ultramafic-hosted and tectonically-controlled Rainbow vent-site on the northern Mid-Atlantic Ridge. The second site was located at 4°48′S at the axial-summit centre of a second-order ridge-segment. There, high-temperature venting is hosted in an  18 km² area of young lava flows which in some cases are observed to have flowed over and engulfed pre-existing chemosynthetic vent-fauna. In both appearance and extent, these lava flows are directly reminiscent of those emplaced in Winter 2005−06 at the East Pacific Rise, 9°50′N and reference to global seismic catalogues reveals that a swarm of large (M 4.6−5.6) seismic events was centred on the 5°S segment over a  24 h period in late June 2002, perhaps indicating the precise timing of this volcanic eruptive episode. Temperature measurements at one of the vents found directly adjacent to the fresh lava flows at 5°S MAR (Turtle Pits) have subsequently revealed vent-fluids that are actively phase separating under conditions very close to the Critical Point for seawater, at  3000 m depth and 407 °C: the hottest vent-fluids yet reported from anywhere along the global ridge crest.     

An Open,Object-Based Framework for Generating Anisotropy in Sedimentary Subsurface Models

The spatial distribution of hydraulic properties in the subsurface controls groundwater flow and solute transport. However, many approaches to modeling these distributions do not produce geologically realistic results and/or do not model the anisotropy of hydraulic conductivity caused by bedding structures in sedimentary deposits. We have developed a flexible object-based package for simulating hydraulic properties in the subsurface—the Hydrogeological Virtual Realities (HyVR) simulation package. This implements a hierarchical modeling framework that takes into account geological rules about stratigraphic bounding surfaces and the geometry of specific sedimentary structures to generate realistic aquifer models, including full hydraulic-conductivity tensors. The HyVR simulation package can create outputs suitable for standard groundwater modeling tools (e.g., MODFLOW), is written in Python, an open-source programming language, and is openly available at an online repository. This paper presents an overview of the underlying modeling principles and computational methods, as well as an example simulation based on the Macrodispersion Experiment site in Columbus, Mississippi. Our simulation package can currently simulate porous media that mimic geological conceptual models in fluvial depositional environments, and that include fine-scale heterogeneity in distributed hydraulic parameter fields. The simulation results allow qualitative geological conceptual models to be converted into digital subsurface models that can be used in quantitative numerical flow-and-transport simulations, with the aim of improving our understanding of the influence of geological realism on groundwater flow and solute transport.     

The behavior of 232Th and the 238U decay chain nuclides during magma formation and volcanism

Concentrations of the members of the ²³⁸U decay chain and ²³²Th were determined in volcanic rocks from convergent plate margins, intraplate volcanoes and oceanic spreading centers. Contemporary and historical volcanic rocks from Mt. St. Helens, Arenal, El Chichon, Hawaii and Iceland and submarine basaltic glass from the Galapagos spreading center all show no fractionation of U and Th in the mantle source or during magma formation at least for the past 300,000 years. Mauna Kea (Hawaii) rocks of alkaline composition greater than 4000 years old and an old submarine basalt show disequilibrium for several of the nuclides in the ²³⁸U decay chain. We interpret these as resulting from post-emplacement processes.