Fluidization of buried mass-wasting deposits in lake sediments and its relevance for paleoseismology: Results from a reflection seismic study of lakes Villarrica and Calafquén (South-Central Chile)

A dense grid of very-high resolution seismic profiles on Lake Villarrica provides a quasi-3D view on intercalated lenses of low-amplitude reflections, which are connected by acoustic wipe-out patches and fractures to an underlying voluminous mass-wasting deposit. The lenses are interpreted as being created by earthquake-triggered liquefaction in this buried mass-wasting deposit and subsequent sediment fluidization and extrusion at the paleo-lake bottom. These sediment volcanoes are mapped in detail. They have a rather uniform circular geometry and show a linear relationship between apparent width and maximum thickness on a seismic section. The largest sediment volcanoes are up to 80 m wide and 1.9 m thick. Their slope angles designate a syn- to post-depositional sagging of most sediment volcanoes. Sediment volcano detection and mapping from nearby Lake Calafquén further strengthen the revealed geometrical relationships. Locally, some of the sediment/fluid escape structures extend to a higher position in the stratigraphy, which points to a polyphase escape process associated with multiple multi-century spaced strong earthquakes. Thickness and morphology of the source layer seem to exert a dominant control in the production of sediment/fluid extrusions. This study shows that reflection seismic profiling allowed recognizing 4 different seismic events in the studied stratigraphic interval, which are evidenced by mass-wasting deposits and/or fluidization features.     

Large-scale distributed deformation controlled topography along the western Africa–Eurasia limit: Tectonic constraints

In the interior of the Iberian Peninsula, the main geomorphic features, mountain ranges and basins, seems to be arranged in several directions whose origin can be related to the N–S plate convergence which occurred along the Cantabro–Pyrenean border during the Eocene–Lower Miocene time span. The Iberian Variscan basement accommodated part of this plate convergence in three E–W trending crustal folds as well as in the reactivation of two left-lateral NNE–SSW strike-slip belts. The rest of the convergence was assumed through the inversion of the Iberian Mesozoic Rift to form the Iberian Chain. This inversion gave rise to a process of oblique crustal shortening involving the development of two right lateral NW–SE shear zones. Crustal folds, strike-slip corridors and one inverted rift compose a tectonic mechanism of pure shear in which the shortening is solved vertically by the development of mountain ranges and related sedimentary basins. This model can be expanded to NW Africa, up to the Atlasic System, where N–S plate convergence seems also to be accommodated in several basement uplifts, Anti-Atlas and Meseta, and through the inversion of two Mesozoic rifts, High and Middle Atlas. In this tectonic situation, the microcontinent Iberia used to be firmly attached to Africa during most part of the Tertiary, in such a way that N–S compressive stresses could be transmitted from the collision of the Pyrenean boundary. This tectonic scenario implies that most part of the Tertiary Eurasia–Africa convergence was not accommodated along the Iberia–Africa interface, but in the Pyrenean plateboundary. A broad zone of distributed deformation resulted from the transmission of compressive stresses from the collision at the Pyrenean border. This distributed, intraplate deformation, can be easily related to the topographic pattern of the Africa–Eurasia interface at the longitude of the Iberian Peninsula.Shortening in the Rif–Betics external zones – and their related topographic features – must be conversely related to more “local” driven mechanisms, the westward displacement of the “exotic” Alboran domain, other than N–S convergence. The remaining NNW–SSE to NW–SE, latest Miocene up to Present convergence is also being accommodated in this zone straddling Iberia and Morocco, at the same time as a new ill-defined plate boundary that is being developed between Europe and Africa.     

川滇黔桂地区二叠纪不同成因盆地层序地层模型

通过不同类型沉积盆地层序界面性质、层序类型、结构、组成、完整性、对称性以及层序发育特征和控制因素研究表明,不同成因沉积盆地,其层序内部构型及成因格架各异.克拉通盆地层序发育主要受全球海平面变化及碳酸盐自旋回控制,LST以陆上暴露不整合面及其上风化残积相为特征,TST以海侵上超不整合面上相对薄的超覆型退积准层序组为特色,HST表现为厚层加-进积丘礁滩组合;对于被动陆缘裂谷盆地,主控因素包括全球海平面变化和同沉积断裂活动,LST期,孤台以陆上暴露不整合面及残积相为标志,台盆表现为水下间断不整合面及上覆混屑浊积岩,TST以台盆硅灰岩-硅岩退积准层序组不断向斜坡和孤台上超为特征,HST期,孤台以加积-进积丘礁滩组合为主,台盆为加积型钙屑重力流沉积,弧后裂谷盆地层序特征与被动陆缘裂谷盆地相似,但其台盆加深加宽,层序以硅质岩及火山碎屑浊积岩为主,揭示层序发育主要受同沉积断裂活动、全球海平面变化及火山活动控制;被动陆缘走滑盆地层序发育主要受控于不同沉积断裂活动及全球海平面变化,层序组成以放射虫硅质岩和深水泥岩为主;前陆盆地LST以造山侵蚀不整合面及盆底扇沉积为特征,TST表现为巨厚层浊积扇-扇三角洲弱进积-弱退积充填型准?     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Mechanical Behavior of Microbially Induced Calcite Precipitation Cemented Sand

Geotechnical and Geological Engineering - New sustainable ground improvement techniques have been recently required for applications in onshore and offshore geotechnical structures. The...     

Major neotectonic features of eastern Marmara region,Turkey: development of the Adapazarı–Karasu corridor and its tectonic significance

Eastern Marmara region consists of three different morphotectonic units: Thrace–Kocaeli Peneplain (TKP) and Çamdağ–Akçakoca Highland (ÇAH) in the north, and Armutlu–Almacık Highland in the south of the North Anatolian Fault Zone (NAFZ). The geologic‐morphologic data and seismic profiles from the Sakarya River offshore indicate that the boundary between the TKP in the west and ÇAH in the east is a previously unrecognized major NNE–SSW‐trending strike‐slip fault zone with reverse component. The fault zone is a distinct morphotectonic corridor herein named the Adapazarı–Karasu corridor (AKC) that runs along the Sakarya River Valley and extends to its submarine canyon along the southern margin of the Black Sea in the north. It formed as a transfer fault zone between the TKP and ÇAH during the Late Miocene; the former has been experiencing extensional forces and the latter compressional forces since then. East–West‐trending segments of the NAFZ cuts the NE–SW‐trending AKC and their activity has resulted in the formation of a distinct fault‐bounded morphology, which is characterized by alternating E–W highlands and lowlands in the AKC. Furthermore, this activity has resulted in the downward motion of an ancient delta and submarine canyon of the Sakarya River in the northern block of the NAFZ below sea level so that the waters of the Black Sea invaded them. The NE–SW‐trending faults in the AKC were reactivated with the development of the NAFZ in the Late Pliocene, which then caused block motions and microseismic activities throughout the AKC. Copyright © 2004 John Wiley & Sons, Ltd.     

Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.