Activity-composition relations in the system CaCO3-MgCO3 predicted from static structure energy calculations and Monte Carlo simulations

Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO₃ − x · MgCO₃, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries.     

Correction to: Simulated effects of land immersion on regional arid climate: a case study of the pre-Saharan playa of Chott el-Jerid (South of Tunisia)

Theoretical and Applied Climatology - In the original article, the last panel of Fig. 10 should be labeled “h”. Also some data and Table 2 caption were unfortunately incorrect.     

Heat waves in the United States: definitions, patterns and trends

High temperatures and heat waves are related but not synonymous concepts. Heat waves, generally understood to be acute periods of extreme warmth, are relevant to a wide range of stakeholders because of the impacts that these events have on human health and activities and on natural environments. Perhaps because of the diversity of communities engaged in heat wave monitoring and research, there is no single, standard definition of a heat wave. Experts differ in which threshold values (absolute versus relative), duration and ancillary variables to incorporate into heat wave definitions. While there is value in this diversity of perspectives, the lack of a unified index can cause confusion when discussing patterns, trends, and impacts. Here, we use data from the North American Land Data Assimilation System to examine patterns and trends in 15 previously published heat wave indices for the period 1979–2011 across the Continental United States. Over this period the Southeast region saw the highest number of heat wave days for the majority of indices considered. Positive trends (increases in number of heat wave days per year) were greatest in the Southeast and Great Plains regions, where more than 12 % of the land area experienced significant increases in the number of heat wave days per year for the majority of heat wave indices. Significant negative trends were relatively rare, but were found in portions of the Southwest, Northwest, and Great Plains.     

Globalization,Pacific Islands,and the paradox of resilience

On April 2nd, 2007 a 12 m tsunami struck Simbo, a relatively remote island in Western Province, Solomon Islands. Although Simbo's population continues to depend on their own food production and small-scale governance regimes regulate access to resources, the island's way of life over the last century has increasingly been affected by processes associated with globalization. In this context of a rapidly globalizing world, this article examines the island's resilience and vulnerability to the tsunami and the adaptive capacities that enabled the response and recovery. The tsunami completely destroyed two villages and damaged fringing coral reefs, but casualties were low and social–ecological rebound relatively brisk. By combining social science methods (household surveys, focus group and ethnographic interviews) and underwater reef surveys we identify a number of countervailing challenges and opportunities presented by globalization that both nurture and suppress the island's resilience to high amplitude, low-frequency disturbances like tsunamis. Analysis suggests that certain adaptive capacities that sustain general system resilience come at the cost of more vulnerability to low-probability hazards. We discuss how communities undergoing increasingly complex processes of change must negotiate these kinds of trade-offs as they manage resilience at multiple spatial and temporal scales. Understanding the shifting dynamics of resilience may be critical for Pacific Island communities who seek to leverage globalization in their favor as they adapt to current social–ecological change and prepare for future large-scale ecological disturbances.     

我即我食vs.我非我食——稳定同位素示踪人体代谢异常初探

稳定同位素分析揭示古代（现代）人群的食物结构,其原理为"我即我食",即人体组织的稳定同位素比值,与其消化吸收转化而来的食物组分,存在着一一对应关系。然而,当人体代谢发生异常时,这种对应关系将被打破,产生"我非我食"现象。目前,探究"我非我食"与古代（现代）人体的健康之联系,已成为生物医学和生物考古界的研究热点。颇为遗憾的是,迄今为止,我国尚无学者对此有所关注。为此,本文以中国北方地区2名代谢性异常患者（直肠癌为例）头发样本为研究对象,通过对人发系列的C、N稳定同位素分析,追踪癌症患者头发同位素值的变化趋势,探讨其生理病理因素与稳定同位素之间的内在关系。研究结果显示：人发C、N同位素比值的变化,与其健康状况密切相关。在直肠癌发病初期,患者的δ13C与δ15N值均呈现出上升趋势,这可能是癌细胞代谢活跃、更多地利用机体中的14N和12C所致,或者与癌细胞具有未知的、独特的代谢途径相关。最后,详细阐述了"我即我食"和"我非我食"的区别和联系,并对如何在我国开展此领域的研究进行了展望。     

Clustering and visualization of earthquake data in a grid environment

We present a web client-server service WEB-IS, which we have developed for remote analysis and visualization of seismic data consisting of both small magnitude events and large earthquakes. We show that the problem-solving environment (PSE) intended for prediction of large magnitude earthquakes can be based on this WEB-IS idea. The clustering schemes, feature generation, feature extraction techniques and rendering algorithms form a computational framework of this environment. On the other hand, easy and fast access both to the seismic data distributed among distant computing resources and to computational and visualization resources can be realized in a GRID framework. We discuss the usefulness of NaradaBrokering (iNtegrated Asynchronous Real-time Adaptive Distributed Architecture) as a middleware, allowing for flexibility and high throughput for remote visualization of geophysical data. The WEB-IS functionality was tested both on synthetic and the actual earthquake catalogs. We consider the application of similar methodology for tsunami alerts.     

Hiatus of wetland methane emissions associated with recent La Niña episodes in the Asian monsoon region

The variability of methane emissions from wetlands in the tropics and northern temperate regions can explain more than 70% of the interannual variation in global wetland methane emissions, which are largely driven by climate variability. We use climate reanalysis, remote sensing wetland area dataset and simulations from 11 land models contributing to Global Methane Budget to investigate the interannual variation and anomalies of wetland methane emissions in the Asian Monsoon region. Methane emissions in this region steadily increased over 2000–2012. However, abnormally low methane emissions were found in equatorial fully humid (Af), warm temperate winter dry (Cw), and warm temperate fully humid (Cf) Asian Monsoon climate sub-regions in 2008, 2009 and 2011, respectively. These spatially-shifting low emissions occurred simultaneously with observed wetland area shrinkage due to abnormally low precipitation. Interannual variability of wetland methane emissions in Asian Monsoon region are primarily driven by South Asian Monsoon system. However, the abnormally low emissions are related to strong La Niña events, and its accompanying effect of weakened East Asian Monsoon system and eastward Western Pacific subtropical high, which drives the shifting pattern of rainfall, and thus the spatial pattern of methane emission anomalies.     

The geochemistry of gem opals as evidence of their origin

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.     

Inflation along Kilauea's Southwest Rift Zone in 2006

We report on InSAR and GPS results showing the first crustal inflation along the southwest rift zone at Kilauea volcano in over 20 years. Two independent interferograms (May 2–August 2, 2006 and June 22–Nov 7, 2006) from the ALOS PALSAR instrument reveal domal uplift located southwest of the main caldera. The uplift is bounded on the northeast by the caldera and follows the southwest rift zone for about 12 km. It is approximately 8 km wide. We use data derived from permanent GPS stations to calibrate the InSAR displacement data and estimate uplift of 7.7 cm during the first interferogram and 8.9 cm during the second with line-of-sight volumes of 2.8 × 10⁶ m³ and 3.0 × 10⁶ m³ respectively. The earthquake record for the periods before, during, and after inflation shows that a swarm of shallow earthquakes (z < 5 km) signaled the beginning of the uplift and that elevated levels of shallow seismicity along the rift zones occurred throughout the uplift period. GPS data indicate that the inflation occurred steadily over nine months between mid-January and mid-October, 2006 making injection of a sill unlikely. We attribute the inflation to recharge of a shallow ductile area under the SWRZ.