Homogeneous nucleation of amorphous solid water particles in the upper mesosphere

Condensed water particles are known to exist in the high latitude upper mesosphere during the summer months. However, the mechanism or mechanisms through which they nucleate remains uncertain. It is postulated here that particles of amorphous solid water (ASW, condensed water with a non-crystalline structure) may nucleate homogeneously in the summer mesosphere. Using classical nucleation theory and a one-dimensional model, it is shown that more than 10⁵ cm^?3 amorphous solid water particles can nucleate homogeneously under mesopause conditions. Furthermore, it is shown that homogeneous nucleation competes with heterogeneous nucleation on meteoric smoke particles when the cooling rate is >0.5 K/h. The homogeneous nucleation of amorphous solid water could provide an explanation for the high density of ice particles (many thousands per cm³) thought to be required for electron depletions in the upper mesosphere. A parameterisation for homogeneous nucleation is presented which can be used in other mesospheric cloud models.     

Fouling community of the Loxahatchee River estuary,Florida, 1980–81

Monthly growth of the fouling community at eight test panel sites in the Loxahatchee River Estuary was related to salinity and temperature. Growth was lowest in January 1981 (averaging 23 g per m², dry weight), and increased during spring and early summer with increasing water temperature. Maximum growth occurred during early or midsummer at upstream locations, before river or canal discharge substantially reduced salinity, and in late summer at downstream locations. Growth was greatest at salinities slightly less than that of seawater and decreased at salinities less than about 10‰. Growth was suppressed throughout the estuary in August 1981, probably because of the sudden decrease in temperature and salinity, and perhaps the increase in physical scouring, caused by runoff from Tropical Storm Dennis. Large loads of nutrients transported to the estuary from storm runoff, however, may have subsequently stimulated growth, which increased in September 1981 to the maximum for the year (averaging 683 g per m², dry weight).     

Crystal nucleation and growth produced by continuous decompression of Pinatubo magma

High-temperature decompression experiments demonstrate that crystal textures preserve a record of the style and rate of magmatic ascent. To reinforce this link, we performed a suite of isothermal decompression experiments using starting material from the climactic 1991 Pinatubo eruption. We decompressed experiments from 220 MPa to final, quench pressures of 75 or 30 MPa using continuous decompression rates of 100, 30, 10, 3, 1, and 0.3 MPa h^?1. Amphibole, clinopyroxene, and plagioclase crystallized during the experiments, with plagioclase microlites dominating the assemblage. Total microlite number densities range from 10^7.6±0.4 up to 10^8.2±0.2 cm^?3, with plagioclase accounting for up to 65% of the total number. Plagioclase microlite area increased systematically from 19?±?8 to 937?±?487 µm² with increasing experiment duration. Our textures provide time-integrated records of crystal kinetics. Average nucleation and areal growth rates of plagioclase are highest in the fastest decompressions (~?10^7.5 cm^?3 h^?1 and 10.1?±?4.1 µm² h^?1, respectively) and more than an order of magnitude lower in the slowest experiments (~?10^5.5 cm^?3 h^?1 and 0.8?±?0.2 µm² h^?1, respectively). Both nucleation and growth rates are highest at high degrees of disequilibrium. We find that peak supersaturation-dependent instantaneous rates are generally more than an order of magnitude faster than average rates. We use those instantaneous nucleation and growth rates to introduce an iterative model to evaluate the effects of different decompression rates, decompression paths (continuous, single-step or multistep), and the presence of phenocrysts on final crystallinity and microlite size distribution.     

Are livestock a troublesome commodity?

Rather than making a uniform case for understanding the neoliberalization of ranching and pastoralism, the articles in this volume show how everyday practices are made through historically and geographically specific struggles over the characteristics of production, exchange and rule, in which livestock play a particularly important role. Collectively, I believe the articles in this volume highlight the significant relationship between cattle and capitalism, and make a compelling argument that to understand the material implications of neoliberalism we need to pay more attention to livestock as an important and rapidly changing medium of livelihood production and accumulation strategy around the world.     

Development and Evaluation of Geostatistical Methods for Non-Euclidean-Based Spatial Covariance Matrices

Mathematical Geosciences - Customary and routine practice of geostatistical modeling assumes that inter-point distances are a Euclidean metric (i.e., as the crow flies) when characterizing spatial...     

Role of Fracturing in the Organization of the Karst Features of Azrou Plateau (Middle Atlas,Morroco) Studied by Remote Sensing Imagery

Karst formation geometry can be controlled by fractures and faults, and by other lithologies. Here we show the organization of kastic collapse features related to structures and to extensive basaltic lava flows in the Middle Atlas of Morocco. A lineament map of major faults and fractures has been created for the Middle Atlas using Landsat 7 ETM⁺ satellite images. This shows a dominant NE–SW regional direction and less prominent NNW–SSE and ENE–WSE directions. All these directions coincide with the alignments of karstic depressions that have formed in the Liassic limestones. The basaltic flows covering these formations on the Middle Atlas limestone plateau, have allowed the generation of cryptokarst, geometrically organized a long these major lineament directions. Karst landforms probabaly existed before the eruption of the lavas, but there were partly invaded by intrusions and volcanism. The extensive basaltic flows allowed for increased infiltration, and subsurface water flow, increasing the rate of kast formation after eruptions. Some basins show evidence of increased subsidence after lava emplacement (Aguelmam Sidi Ali Lake) and some maar-like craters also have subsided after eruption, by karts formation. We lay out the structural and lithological controls on Karstic formation in an intraplate volcanic field based on limestones and evaporites.     

Local Agenda 21 and Barriers to Sustainability at the Local Government Level in Victoria,Australia

At the 1992 Rio 'Earth Summit', Australia joined other nations in committing to processes leading to the formulation of 'Local Agenda 21s' (LA21s) by 1996. Subsequently, in the latter year, Whittaker carried out a national survey of local government authorities to evaluate what progress had been made. Whittaker's conclusion was that progress in Australia had been slow, but ten 'leading-edge' Victorian councils were identified through a self-reporting process. In this paper we discuss the concept of LA21, analyse in closer detail the 'progress' that has been made in the ten Victorian councils, and discuss some of the broader forces that, we argue, have made LA21 formulation increasingly difficult, particularly in the state of Victoria in the recent past.     

Testing the suitability of geologic frameworks for extrapolating hydraulic properties across regional scales

The suitability of geologic frameworks for extrapolating hydraulic conductivity (K) to length scales commensurate with hydraulic data is difficult to assess. A novel method is presented for evaluating assumed relations between K and geologic interpretations for regional-scale groundwater modeling. The approach relies on simultaneous interpretation of multiple aquifer tests using alternative geologic frameworks of variable complexity, where each framework is incorporated as prior information that assumes homogeneous K within each model unit. This approach is tested at Pahute Mesa within the Nevada National Security Site (USA), where observed drawdowns from eight aquifer tests in complex, highly faulted volcanic rocks provide the necessary hydraulic constraints. The investigated volume encompasses 40 mi³ (167 km³) where drawdowns traversed major fault structures and were detected more than 2 mi (3.2 km) from pumping wells. Complexity of the five frameworks assessed ranges from an undifferentiated mass of rock with a single unit to 14 distinct geologic units. Results show that only four geologic units can be justified as hydraulically unique for this location. The approach qualitatively evaluates the consistency of hydraulic property estimates within extents of investigation and effects of geologic frameworks on extrapolation. Distributions of transmissivity are similar within the investigated extents irrespective of the geologic framework. In contrast, the extrapolation of hydraulic properties beyond the volume investigated with interfering aquifer tests is strongly affected by the complexity of a given framework. Testing at Pahute Mesa illustrates how this method can be employed to determine the appropriate level of geologic complexity for large-scale groundwater modeling.     

Phytate as a novel phosphorus-specific paleo-indicator in aquatic sediments

A reliable geochemical paleo-indicator for phosphorus remains elusive, despite the importance of understanding historical changes in the nutrient status of aquatic ecosystems. We assessed the potential of phytate (salts of myo-inositol hexakisphosphate) as a novel phosphorus-specific paleo-indicator by measuring its concentrations in dated sediments from an embayment in Helsinki, Finland, with a known 200-year history of trophic changes. Phytate was extracted in a solution containing sodium hydroxide and EDTA and detected by solution ³¹P NMR spectroscopy with spectral deconvolution. Concentrations varied markedly with sediment depth and paralleled previously determined changes in diatom assemblages and geochemical indicators linked to trophic status. In contrast, total sediment phosphorus did not reflect phosphorus inputs to the embayment, presumably due to the mobilization of inorganic phosphate under anoxic conditions during periods of high pollutant loading. Importantly, phytate appeared to be stable in these brackish sediments, in contrast to other organic and inorganic phosphates which declined abruptly with depth. We therefore conclude that phytate represents a potentially important indicator of historical changes in phosphorus inputs to water bodies, although additional studies are required to confirm its stability under conditions likely to be encountered in lakes and coastal ecosystems.