Trapped Ar isotopes in meteorite ALH 84001 indicate Mars did not have a thick ancient atmosphere

Water is not currently stable in liquid form on the martian surface due to the present mean atmospheric pressure of ～7 mbar and mean global temperature of ～220 K. However, geomorphic features and hydrated mineral assemblages suggest that Mars’ climate was once warmer and liquid water flowed on the surface. These observations may indicate a substantially more massive atmosphere in the past, but there have been few observational constraints on paleoatmospheric pressures. Here we show how the ⁴⁰Ar/³⁶Ar ratios of trapped gases within martian meteorite ALH 84001 constrain paleoatmospheric pressure on Mars during the Noachian era [～4.56–3.8 billion years (Ga)]. Our model indicates that atmospheric pressures did not exceed ～1.5 bar during the first 400 million years (Ma) of the Noachian era, and were <400 mbar by 4.16 Ga. Such pressures of CO₂ are only sufficient to stabilize liquid water on Mars’ surface at low latitudes during seasonally warm periods. Other greenhouse gases like SO₂ and water vapor may have played an important role in intermittently stabilizing liquid water at higher latitudes following major volcanic eruptions or impact events.     

Ecohydrographic constraints on biodiversity and distribution of phytoplankton and zooplankton in coral reefs of the Red Sea,Saudi Arabia

An integral concept of ecological research is the constraint of biodiversity along latitudinal and environmental gradients. The Red Sea features a natural example of a latitudinal gradient of salinity, temperature and nutrient richness. Coral reefs along the Red Sea coasts are supported with allochthonous resources such as oceanic and neritic phytoplankton and zooplankton; however, relatively little is known about how the ecohydrography correlates with plankton biodiversity and abundance. In this article we present the biodiversity of phytoplankton and zooplankton in Red Sea coral reefs. Oceanographic data (temperature, salinity), water samples for nutrient analysis, particulate organic matter, phytoplankton and zooplankton, the latter with special reference to Copepoda (Crustacea), were collected at nine coral reefs over ~1500 km distance along the Red Sea coast of Saudi Arabia. The trophic state of ambient waters [as indicated by chlorophyll a (Chl a)] changed from strong oligotrophy in the north to mesotrophy in the south and was associated with increasing biomasses of Bacillariophyceae, picoeukaryotes and Synechococcus as indicated by pigment fingerprinting (CHEMTAX) and flow cytometry. Net‐phytoplankton microscopy revealed a Trichodesmium erythraeum (Cyanobacteria) bloom north of the Farasan Islands. Several potentially harmful algae, including Dinophysis miles and Gonyaulax spinifera (Dinophyceae), were encountered in larger numbers in the vicinity of the aquaculture facilities at Al Lith. Changes in zooplankton abundance were mainly correlated to the phytoplankton biomass following the latitudinal gradient. The largest zooplankton abundance was observed at the Farasan Archipelago, despite high abundances of copepodites, veligers (Gastropoda larvae) and Chaetognatha at Al Lith. Although the community composition changed over latitude, biodiversity indices of phytoplankton and zooplankton did not exhibit a systematic pattern. As this study constitutes the first current account of the plankton biodiversity in Red Sea coral reefs at a large spatial scale, the results will be informative for ecosystem‐based management along the coastline of Saudi Arabia.     

Crustal thickness estimation beneath the southern central Andes at 30°S and 36°S from S wave receiver function analysis

We have used the S wave receiver function (SRF) technique to investigate the crustal thickness beneath two seismic profiles from the CHARGE project in the southern central Andes. A previous study employing the P wave receiver function method has observed the Moho interface beneath much of the profiles. They found, however, that the amplitude of the P to S conversion was diminished in the western part of the profiles and have attributed it to a reduction of the impedance contrast at the Moho due to lower crustal ecologitization. With SRF, we have successfully detected S to P converted waves from the Moho as well as possible conversions from other lithospheric boundaries. The continental South American crust reaches its maximum thickness of ∼70 km (along 30°S between 70°W and 68.5°W) beneath the Principal Cordillera and the Famatina system and becomes thinner towards the Sierras Pampeanas with a thickness of ∼40 km. Negative phases, possibly related to the base of the continental and oceanic lithosphere, can be recognized in the summation traces at different depths. By comparing our results with data obtained from previous investigations, we are able to further constrain the thickness of the crust and lithosphere beneath the central Andes.     

Simulated effects of land immersion on regional arid climate: a case study of the pre-Saharan playa of Chott el-Jerid (south of Tunisia)

The potential effects on the regional climate induced by partially immersing the arid pre-Saharan playa basin of Chott el-Jerid (south of Tunisia) are investigated by comparing two multi-year (1991–2011) sets of numerical simulations each consisting of ten-member ensemble and performed using the WRF regional climate model. The first WRF ensemble is performed under current land use and land cover, while the second is carried out after introducing a virtual large and shallow surface water reservoir (a lake) in Chott el-Jerid. The most pronounced effects generated by the artificial lake are circumscribed over its surface and slightly spread downwind to the other parts of the Chott. The lake has a clear moderating effect on near-surface air temperatures by increasing (decreasing) the wintertime (summertime) air temperatures. Sensible heat fluxes are remarkably increased in winter and decreased in summer over the lake following the temperature gradient between the lake surface and the overlying atmosphere. Latent heat fluxes, moisture convergence, and water vapor mixing ratio are increased over the lake throughout the year, especially in winter. The lake also induces domain-wide decreased (increased) surface pressures and land (lake) breeze circulation in winter (summer). Simulated rainfall amounts are most increased over the lake in winter likely because of an enhanced atmospheric instability, while they slightly decrease in summer.     

Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.     

A model for oxygen and sulfur isotope fractionation in sulfate during bacterial sulfate reduction processes

We present a model of bacterial sulfate reduction that includes equations describing the fractionation relationship between the sulfur and the oxygen isotope composition of residual sulfate (δ³⁴S_{SO4_residual}, δ¹⁸O_{SO4_residual}) and the amount of residual sulfate. The model is based exclusively on oxygen isotope exchange between cell-internal sulfur compounds and ambient water as the dominating mechanism controlling oxygen isotope fractionation processes. We show that our model explains δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} patterns observed from natural environments and from laboratory experiments, whereas other models, favoring kinetic isotope fractionation processes as dominant process, fail to explain many (but not all) observed δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} patterns. Moreover, we show that a “typical” δ³⁴S_{SO4_residual} vs. δ¹⁸O_{SO4_residual} slope does not exist. We postulate that measurements of δ³⁴S_{SO4_residual} and δ¹⁸O_{SO4_residual} can be used as a tool to determine cell-specific sulfate reduction rates, oxygen isotope exchange rates, and equilibrium oxygen isotope exchange factors. Data from culture experiments are used to determine the range of sulfur isotope fractionation factors in which a simplified set of equations can be used. Numerical examples demonstrate the application of the equations. We postulate that, during denitrification, the oxygen isotope effects in residual nitrate are also the result of oxygen isotope exchange with ambient water. Consequently, the equations for the relationship between δ³⁴S_{SO4_residual}, δ¹⁸O_{SO4_residual}, and the amount of residual sulfate could be modified and used to calculate the fractionation-relationship between δ¹⁵N_{NO3_residual}, δ¹⁸O_{NO3_residual}, and the amount of residual nitrate during denitrification.     

Local Agenda 21 and Barriers to Sustainability at the Local Government Level in Victoria,Australia

At the 1992 Rio 'Earth Summit', Australia joined other nations in committing to processes leading to the formulation of 'Local Agenda 21s' (LA21s) by 1996. Subsequently, in the latter year, Whittaker carried out a national survey of local government authorities to evaluate what progress had been made. Whittaker's conclusion was that progress in Australia had been slow, but ten 'leading-edge' Victorian councils were identified through a self-reporting process. In this paper we discuss the concept of LA21, analyse in closer detail the 'progress' that has been made in the ten Victorian councils, and discuss some of the broader forces that, we argue, have made LA21 formulation increasingly difficult, particularly in the state of Victoria in the recent past.     

Hillslopes in humid-tropical climates aren't always wet: Implications for hydrologic response and landslide initiation in Puerto Rico

The devastating impacts of the widespread flooding and landsliding in Puerto Rico following the September 2017 landfall of Hurricane Maria highlight the increasingly extreme atmospheric disturbances and enhanced hazard potential in mountainous humid-tropical climate zones. Long-standing conceptual models for hydrologically driven hazards in Puerto Rico posit that hillslope soils remain wet throughout the year, and therefore, that antecedent soil wetness imposes a negligible effect on hazard potential. Our post-Maria in situ hillslope hydrologic observations, however, indicate that while some slopes remain wet throughout the year, others exhibit appreciable seasonal and intra-storm subsurface drainage. Therefore, we evaluated the performance of hydro-meteorological (soil wetness and rainfall) versus intensity-duration (rainfall only) hillslope hydrologic response thresholds that identify the onset of positive pore-water pressure, a predisposing factor for widespread slope instability in this region. Our analyses also consider the role of soil-water storage and infiltration rates on runoff generation, which are relevant factors for flooding hazards. We found that the hydro-meteorological thresholds outperformed intensity-duration thresholds for a seasonally wet, coarse-grained soil, although they did not outperform intensity-duration thresholds for a perennially wet, fine-grained soil. These end-member soils types may also produce radically different stormflow responses, with subsurface flow being more common for the coarse-grained soils underlain by intrusive rocks versus infiltration excess and/or saturation excess for the fine-grained soils underlain by volcaniclastic rocks. We conclude that variability in soil-hydraulic properties, as opposed to climate zone, is the dominant factor that controls runoff generation mechanisms and modulates the relative importance of antecedent soil wetness for our hillslope hydrologic response thresholds.