Neoproterozoic chemostratigraphy

Chemostratigraphy has diverse applications to investigating the rock record, such as reconstructing paleoenvironments, determining the tectonic setting of sedimentary basins, indirect dating, and establishing regional or global correlations. Chemostratigraphy is thus an integral component of many investigations of the ancient sedimentary record. In this contribution, we review the principle inorganic geochemical methods that have been applied to the Neoproterozoic sedimentary record. Analysis of the traditional stable and radiogenic isotope systems, such as δ¹³C, δ¹⁸O, δ³⁴S, and ⁸⁷Sr/⁸⁶Sr, is routine, particularly in successions rich in carbonate. These mainstay applications have yielded invaluable data and information bearing on the chronology and evolution of this eventful era in Earth history. Alongside the growing database of traditional data, a series of novel geochemical techniques have given rise to important new models and constraints on Neoproterozoic biogeochemical change. In particular, a range of proxies for water column redox, mainly obtained from black shales, have shed light on the pace and tempo of Neoproterozoic oxygenation and its link to the appearance of early animal evolution. Increased integration of diverse geochemical, sedimentological, and paleontological datasets, and the gradual radiometric calibration of the stratigraphic record promise to bring the details of the evolution of the Neoproterozoic Earth system into ever greater focus.     

Glycol Ethers As Groundwater Contaminants

Ether derivatives of dihydroxy alcohols, which are formed from ethylene or propylene, comprise an important group of groundwater contaminants known as glycol ethers. Compounds in this group are used as solvents, cleaning agents, and emulsifiers in many chemical products and manufacturing operations. Glycol ethers have been associated with a variety of toxic effects, and some compounds in the group are relatively potent teratogens. The limited information available suggests that glycol ethers are contaminants in groundwater, especially in anaerobic plumes emanating from disposal of mixed industrial and household waste. Most methods used to analyze groundwater samples cannot adequately detect 7g/’ (ppb) concentrations of glycol ethers, and the existing methods perform worst for the most widely used and toxic species. A new method capable of analyzing 7g/’ concentrations of glycol ethers was recently developed, and its use is recommended for groundwater samples where glycol ethers are likely to be present. Résumé. Les éthers glycol, polluants des eaux souterraines. Les dérivés d'éther de dihydroxy-alcool, formés à partir de l'éthylène ou du propylène, constituent un important groupe de polluants des eaux souterraines connus sous le nom d'éthers glycol. Les composés de ce groupe sont utilisés comme solvants, comme agents de nettoyage et comme émulsifiants dans de nombreux produits chimiques et dans de nombreux processus de fabrication. Des effets toxiques variés ont été attribués aux éthers glycol et certains des composés sont des agents tératogènes relativement puissants. Les données disponibles, qui sont limitées, indiquent que les éthers glycol sont des polluants communs dans les eaux souterraines, particulièrement dans les panaches anaéorobies émis par les décharges mixtes de déchets industriels et domestiques. La plupart des méthodes d'analyse d'échantillons d'eau souterraine ne sont pas capables de détecter convenablement des concentrations en éthers glycol de l'ordre du 7g/l (ppb); les méthodes actuelles sont médiocres pour doser les espèces toxiques les plus courantes. Une nouvelle méthode permettant de doser des concentrations en éthers glycol de l'ordre du 7 g/l a été récemment mise au point; son utilisation est préconisée pour les échantillons d'eau souterraine contenant des éthers glycol.     

Using simulated hydrologic response to revisit the 1973 Lerida Court landslide

Hydrologically driven mass wasting in the form of landslides on steep slopes is a worldwide occurrence. High-profile events in, for example, Brazil, Chile, the Philippines, Puerto Rico, and Venezuela during the last three decades all clearly illustrate, based upon significant losses of life and property, that hydrologically driven slope instability in developed (urban) areas can be a major geologic/environmental hazard. The focus of this study is the 1973 hydrologically driven Lerida Court landslide in Portola Valley, CA, USA. Physics-based hydrologic-response simulation, with the comprehensive Integrated Hydrology Model, was employed to forensically estimate the spatiotemporal pore pressure distributions for the Lerida Court site. Slope stability, driven by the simulated pore pressure dynamics, was estimated for the Lerida Court site with the infinite slope/Factor of Safety approach. The pore pressure dynamics for the Lerida Court site were reasonably captured by the hydrologic-response simulation. The estimated time of slope failure for the Lerida Court site compares well with field observations. A recommendation is made that hydrologically driven slope stability estimates including variably saturated subsurface flow be standard protocol for development sites in steep urban settings.     

Sulfur cycling at the Mid-Atlantic Ridge: A multiple sulfur isotope approach

The role of sulfur in two hydrothermal vent systems, the Logatchev hydrothermal field at 14°45′N/44°58′W and several different vent sites along the southern Mid-Atlantic Ridge (SMAR) between 4°48′S and 9°33′S and between 12°22′W and 13°12′W, is examined by utilizing multiple sulfur isotope and sulfur concentration data. Isotope compositions for sulfide minerals and vent H₂S from different SMAR sites range from + 1.5 to + 8.9‰ in δ³⁴S and from + 0.001 to + 0.051‰ in Δ³³S. These data indicate mixing of mantle sulfur with sulfur from seawater sulfate. Combined δ³⁴S and Δ³³S systematics reveal that vent sulfide from SMAR is characterized by a sulfur contribution from seawater sulfate between 25 and 33%. This higher contribution, compared with EPR sulfide, indicates increased seawater sulfate reduction at MAR, because of a deeper seated magma chamber and longer fluid upflow path length, and points to fundamental differences with respect to subsurface structures and fluid evolution at slow and fast spreading mid-ocean ridges.Additionally, isotope data uncover non-equilibrium isotopic exchange between dissolved sulfide and sulfate in an anhydrite bearing zone below the vent systems at fluid temperatures between 335 and 400 °C. δ³⁴S values between + 0.2 to + 8.8‰ for dissolved and precipitated sulfide from Logatchev point to the same mixing process between mantle sulfur and sulfur from seawater sulfate as at SMAR. δ³⁴S values between ? 24.5 and + 6.5‰ and Δ³³S values between + 0.001 and + 0.125‰ for sulfide-bearing sediments and mafic/ultramafic host rocks from drill cores taken in the region of Logatchev indicate a clear contribution of biogenic sulfides formed via bacterial sulfate reduction. Basalts and basaltic glass from SMAR sites with Δ³³S = ? 0.008‰ reveal lower Δ³³S lower values than suggested on the basis of previously published isotopic measurements of terrestrial materials.We conclude that the combined use of both δ³⁴S and Δ³³S provides a more detailed picture of the sulfur cycling in hydrothermal systems at the Mid-Atlantic Ridge and uncovers systematic differences to hydrothermal sites at different mid-ocean ridge sites. Multiple sulfur isotope measurements allow identification of incomplete isotope exchange in addition to isotope mixing as a second important factor influencing the isotopic composition of dissolved sulfide during fluid upflow. Furthermore, based on Δ³³S we are able to clearly distinguish biogenic from hydrothermal sulfides in sediments even when δ³⁴S were identical.     

Effect of rod friction on vane shear tests in very soft organic harbour mud

Very soft organic harbour mud is increasingly used as a filling and construction material in harbour construction and reorganization. The undrained shear strength of such soft sediments is the critical geotechnical soil parameter with regard to any specific construction design. Field and laboratory vane shear testing is a standard method to quickly determine this important parameter. So far, the effect of rod friction on vane shear tests in very soft organic soils is unclear. In this study we present results from laboratory experiments on harbour mud from a construction site in northern Germany. Relations among vane and rod geometry, penetration depth, water content, rod friction and undrained shear strength are derived. Based on these relations the influence of rod friction on vane shear test results is investigated. The results indicate that field and laboratory vane shear test measurements may be significantly influenced by rod friction. Methods are proposed to correct for the rod influence, which is shown to increase with rising water contents.     

Web-cam’s potential for collaborative activities in the Earth sciences

We report here our experiences from using easily acquired web-cam components for collaborative ventures in the Earth sciences. We have used a variety of hardware and different software. We demonstrate from various locations in the U.S.A. the feasibility of using web-cam in multitudinous activities, relevant for conducting research and knowledge dissemination. We summarize the quality of the connections from the various combinations of communicating parties. Today, web-cams can be utilized as an economical and viable means of point-to-point communication in the Earth science community. Greater bandwidth is sorely needed for activities such as multi-party conferencing on the present internet network. We propose that web-cam can be readily deployed as a web-service for facilitating collaborative research over the GRID infrastructure, using the middleware Narada-Brokering. Web-cam will play an important role in the emerging field of geoinformatics.     

Urban land transformation for pro-poor economies

The transformation of land into a setting for clustering local economies can become an important cornerstone of poverty policy. This transformation has several functional aspects, which in turn have important institutional and political aspects. Underlying both the functional and institutional factors is the role of local government and local democracy. Such a conceptualization puts to center stage several paradoxes: A terrain that seems “slum-like” turns out to be highly productive and employment generating. Complex tenure forms and mixed land use seen as “unplanned” turn out to be pre-requisites for economic development. There are institutional paradoxes that contrast efforts at “transparency” and managerial “best practices”. Here, the messiness of local bureaucracies in municipal government turns out to be critical for poor groups to influence interventions in their favor. Influencing the public process may be more effective in stealth-like ways rather taking a more visible approach. Most fundamentally these issues remind us that the potential of cities to reinforce or reduce poverty moved far beyond projects and programs and the normative frameworks used by planners and administrators. Instead, it is the transformative process of turning land into economic settings that might be at the center stage. This is a stage where poor groups are the central actors who stealth-like draw on complex alliances across ethnic and class lines to shapes cities in their interests.     

Correction to: Simulated effects of land immersion on regional arid climate: a case study of the pre-Saharan playa of Chott el-Jerid (South of Tunisia)

Theoretical and Applied Climatology - In the original article, the last panel of Fig. 10 should be labeled “h”. Also some data and Table 2 caption were unfortunately incorrect.     

Simulation of the annual and diurnal cycles of rainfall over South Africa by a regional climate model

The capability of a current state-of-the-art regional climate model for simulating the diurnal and annual cycles of rainfall over a complex subtropical region is documented here. Hourly rainfall is simulated over Southern Africa for 1998–2006 by the non-hydrostatic model weather research and forecasting (WRF), and compared to a network of 103 stations covering South Africa. We used five simulations, four of which consist of different parameterizations for atmospheric convection at a 0.5 × 0.5° resolution, performed to test the physic-dependency of the results. The fifth experiment uses explicit convection over tropical South Africa at a 1/30° resolution. WRF simulates realistic mean rainfall fields, albeit wet biases over tropical Africa. The model mean biases are strongly modulated by the convective scheme used for the simulations. The annual cycle of rainfall is well simulated over South Africa, mostly influenced by tropical summer rainfall except in the Western Cape region experiencing winter rainfall. The diurnal cycle shows a timing bias, with atmospheric convection occurring too early in the afternoon, and causing too abundant rainfall. This result, particularly true in summer over the northeastern part of the country, is weakly physic-dependent. Cloud-resolving simulations do not clearly reduce the diurnal cycle biases. In the end, the rainfall overestimations appear to be mostly imputable to the afternoon hours of the austral summer rainy season, i.e., the periods during which convective activity is intense over the region.