Subsurface transport in water and gas

Current designs for nuclear-waste repositories rely primarily upon subsurface geologic barriers for long-term containment. Because water and air are generally considered to be the mechanisms most likely to transport radioactivity to the surface environment, flow and transport models are important tools in repository assessment. Most models assume that the geologic medium can be treated as a continuum. A substantial body of recent work has focused on applying these models to difficult-to-solve problems, such as the simulation of variably dense or variably saturated flow and transport, large and complex flow systems, sharp solute concentration fronts, and fractured rock systems. The complex chemical interactions between the transport fluid and solid particles within the system have been analyzed using geochemical flow models, most of which assume that the system is at chemical equilibrium. The role of colloids in contaminant transport is a relatively new area of research. The large-scale effects of small-scale variability within the geologic system have been the subject of intense investigation. Inherent limitations of the continuum approach have prompted the design of models in which the flow occurs in discrete fractures. The difficulty and complexity of simulating transport has led to the development of network transport models, which represent the flow field as a series of 1-D path segments. The widespread use of models for prediction and analysis has prompted investigations of their reliability and relative merits.     

Ammonium excretion by benthic invertebrates and sediment-water nitrogen flux in the Gulf of Mexico near the Mississippi River outflow

Benthic macroinvertebrate biomass and ammonium excretion rates were measured at four stations in the Gulf of Mexico near the Mississippi River mouth. Calculated areal excretion rates were then compared to sediment-water nitrogen fluxes measured in benthic bottom lander chambers at similar stations to estimate the potential importance of macroinvertebrate excretion to sediment nitrogen mineralization. Excretion rates for individual crustaceans (amphipods and decapods) was 2–21 nmoles NH₄ ⁺ (mg dry weight)^?1 h^?1. The mean excretion rates for the polychaetes, Paraprionaspio pinnata [6–12 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1] and Magelona sp. [27–53 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1], were comparable or higher than previous measurements for similar size benthic or pelagic invertebrates incubated at the same temperature (22±1°C). Although the relatively high rates of excretion by these selective feeders may have been partially caused by experimental handling effects (e.g., removal from sediment substrates), they probably reflected the availability of nitrogen-rich food supplies in the Mississippi River plume. When the measured weight-specific rates were extrapolated to total areal biomass, areal macroinvertebrate excretion estimates ranged from 7 μmole NH₄ ⁺ m^?2h^?1 at a 40-m deep station near the river mouth to 18 μmole NH₄ ⁺ m^?2h^?1 at a shallower (28-m deep) station further from the river mouth. The net flux of ammonium and nitrate from the sediments to the water measured in bottom lander chambers in the same region were 15–53 μmole NH₄ ⁺ m^?2h^?1 and ?25–21 μmole NO₃ ^? m^?2h^?1. These results suggest that excretion of NH₄ ⁺ by macroinvertebrates could be a potentially important component of benthic nitrogen regeneration in the Mississippi River plume-Gulf shelf region.     

Characteristics and mitigation of the snow avalanche hazard in Kaghan Valley,Pakistan Himalaya

Snow avalanche hazards in mountainous areas of developing countries have received scant attention in the scientific literature. The purpose of this paper is to describe this hazard and mitigative measures in Kaghan Valley, Pakistan Himalaya, and to review alternatives for future reduction of this hazard. Snow avalanches have long posed a hazard and risk to indigenous populations of the Himalaya and Trans-Himalaya mountains. Land use intensification due to population growth, new transportation routes, military activity and tourism is raising levels of risk. The history of land use in the study area is such that investigations of avalanche hazard must rely on different theoretical bases and data than in most industrialised countries. Despite the intensive use of valley-bottom land which is affected by avalanches, a number of simple measures are currently employed by the indigenous population to mitigate the hazard. Out-migration during the winter months is the most important one. During the intensive use period of summer avalanche-transported snow provides numerous resources for the population. In Kaghan the avalanche hazard is increasing primarily as a result of poorly located new buildings and other construction projects. The large scale of avalanche activity there rules out any significant improvement or protection of the currently difficult winter access. Instead, future mitigation of the hazard should focus on protecting the small number of winter inhabitants and minimising property damage.     

Weighting of Observed Heads for the Inverse Problem

In using least-squares parameter estimation techniques to solve for hydrogeologic parameters, one may use a weighting function to reflect differing reliabilities of head measurements. In studies published to date, the weighting function has been used in an ad boc manner or not at all. The inverse square of the observed hydraulic gradient, adjusted to reflect the modeler's perception of geologic heterogeneity and data reliability, is typically an appropriate weighting function.     

The antiferromagnetic-paramagnetic transition in αFe2O3 in the single prism approximation of the cluster variation method

The single prism approximation SPA of the cluster variation method has been used to model the antiferromagnetic-paramagnetic transition in hematite. This calculation yields insight into the accuracy of the SPA and other approximate methods for modeling order-disorder phenomena. Published values of the magnetic coupling constants were used to calculate the Néel temperature, sublattice magnetization, and magnetic specific heat. The calculated Néel temperature is found to be 1.21 times the observed value, as compared to 1.36 times observed for a mean field theory approximation, an improvement that reflects the superior treatment of configurational entropy in the SPA. Qualitative to semiquantitative agreement is obtained between observed and calculated values for sublattice magnetization and magnetic specific heat; however we find that previously published values for the magnetic specific heat are too large by a factor of two.     

Carbon and oxygen isotope composition of pedogenic CaCO3 from soil profiles in Nevada and New Mexico,U.S.A.

Stable carbon and oxygen isotope measurements have been obtained from ten calcareous soil profiles developed on noncalcareous parent materials in Nevada and New Mexico. Despite the number of variables that can affect the isotopic composition of soil carbonate, most of these profiles show remarkably little variation in δ ¹³C and δ ¹⁸O with depth. This tendency towards uniformity is attributed to the fact that pedogenic carbonate forms by the incremental accumulation of a large number of small aliquots of CaCO₃. As the number of aliquots of CaCO₃ increases, the composition of their sum, which is the calcareous horizon itself, tends to converge to the long-term average of the individual aliquots. A mathematical model is presented to show how the time required for convergence is affected by the amplitude and period of aliquot variation and the extent of dissolution and reprecipitation of previously deposited carbonate. Calculations further indicate that in some cases the variation in δ ¹⁸O of soil carbonates may be moderated by the opposing effects of temperature change on the H₂OCaCO₃ fractionation factor and on the extent of evapotranspiration.The data of this study indicate that soil carbonates from sites within a homogeneous climatic region show relatively little site-to-site variation in δ ¹⁸O as compared to geographical variation in δ ¹³C. This suggests that the δ ¹⁸O of soil carbonates is primarily controlled by broad climatic factors (rainfall composition and temperature) whereas site factors (e.g., soil CO₂) have a strong effect on δ ¹³C. In Nevada and New Mexico the δ ¹⁸O of Pleistocene calcareous profiles is 2.0–4.0‰ lighter than that of nearby Holocene soil carbonate, suggesting that old well-developed profiles may have formed dominantly under cooler pluvial conditions.