Incorporating spatially heterogeneous infiltration capacity into hydrologic models with applications for simulating post‐wildfire debris flow initiation

Soils in post‐wildfire environments are often characterized by a low infiltration capacity with a high degree of spatial heterogeneity relative to unburned areas. Debris flows are frequently initiated by run‐off in recently burned steeplands, making it critical to develop and test methods for incorporating spatial variability in infiltration capacity into hydrologic models. We use Monte Carlo simulations of run‐off generation over a soil with a spatially heterogenous saturated hydraulic conductivity (K_s) to derive an expression for an aerially averaged saturated hydraulic conductivity ( ) that depends on the rainfall rate, the statistical properties of K_s, and the spatial correlation length scale associated with K_s. The proposed method for determining is tested by simulating run‐off on synthetic topography over a wide range of spatial scales. Results provide a simplified expression for an effective saturated hydraulic conductivity that can be used to relate a distribution of small‐scale K_s measurements to infiltration and run‐off generation over larger spatial scales. Finally, we use a hydrologic model based on to simulate run‐off and debris flow initiation at a recently burned catchment in the Santa Ana Mountains, CA, USA, and compare results to those obtained using an infiltration model based on the Soil Conservation Service Curve Number.     

ISCO for Groundwater Remediation: Analysis of Field Applications and Performance

A critical analysis of in situ chemical oxidation (ISCO) projects was performed to characterize situations in which ISCO is being implemented, how design and operating parameters are typically employed, and to determine the performance results being achieved. This research involved design of a database, acquisition and review of ISCO project information, population of the database, and analyses of the database using statistical methods. Based on 242 ISCO projects included in the database, ISCO has been used to treat a variety of contaminants; however, chlorinated solvents are by far the most common. ISCO has been implemented at sites with varied subsurface conditions with vertical injection wells and direct push probes being the most common delivery methods. ISCO has met and maintained concentrations below maximum contaminant levels (MCLs), although not at any sites where dense nonaqueous phase liquids (DNAPL) were presumed to be present. Alternative cleanup levels and mass reduction goals have also been attempted, and these less stringent goals are met with greater frequency than MCLs. The use of pilot testing is beneficial in heterogeneous geologic media, but not so in homogeneous media. ISCO projects cost $220,000 on average, and cost on average $94/yd³ of target treatment zone. ISCO costs vary widely based on the size of the treatment zone, the presence of DNAPL, and the oxidant delivery method. No case studies were encountered in which ISCO resulted in permanent reductions to microbial populations or sustained increases in metal concentrations in groundwater at the ISCO-treated site.     

Structural and Hydrogeological Controls on Hydrocarbon and Brine Migration into Drinking Water Aquifers in Southern New York

Environmental concerns regarding the potential for drinking water contamination in shallow aquifers have accompanied unconventional energy development in the northern Appalachian Basin. These activities have also raised several critical questions about the hydrogeological parameters that control the naturally occurring presence and migration of hydrocarbon gases in shallow aquifers within petroliferous basins. To interrogate these factors, we analyzed the noble gas, dissolved ion, and hydrocarbon gas (molecular and isotopic composition) geochemistry of 98 groundwater samples from south‐central New York. All samples were collected ?1km from unconventional drilling activities and sample locations were intentionally targeted based on their proximity to various types of documented fault systems. In agreement with studies from other petroliferous basins, our results show significant correlations between elevated levels of radiogenic [⁴He], thermogenic [CH₄], and dissolved ions (e.g., Cl, Br, Sr, Ba). In combination, our data suggest that faults have facilitated the transport of exogenous hydrocarbon‐rich brines from Devonian source rocks into overlying Upper Devonian aquifer lithologies over geologic time. These data conflict with previous reports, which conclude that hydrodynamic focusing regulates the occurrence of methane and salt in shallow aquifers and leads to elevated levels of these species in restricted flow zones within valley bottoms. Instead, our data suggest that faults in Paleozoic rocks play a fundamental role in gas and brine transport from depth, regulate the distribution of their occurrence in shallow aquifers, and influence the geochemistry of shallow groundwater in this petroliferous basin.     

The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.     

Direct relationships of discharges to the mean and standard deviation of the intervals between their exceedences

Abstract

This article paves a way for assessing flood risk by the use of two-parameter distributions, for the intervals between threshold exceedences rather than by the traditional exponential distribution. In a case study, the apparent properties of intervals between exceedences of runoff events differ from those anticipated for exponentially distributed series. A procedure is proposed to relate two statistical parameters of the intervals to threshold discharges. It considers partial duration series (PDS) with thresholds equal to all high enough observed discharges. To avoid unnecessary assumptions on the behaviour of those parameters and effects of dependence between parameters for different PDS, a non-parametric trend-free pre-whitened scheme is applied. It leads to power-law relationships between a discharge and the mean and standard deviation of the intervals between its exceedences. Predicted mean inter-exceedence intervals, for the highest observed discharges at the stations, are closer to the observational periods than those predicted by GEV distributions fitted to AMS, and by GP distributions to fitted PDS. In the present case, the latter predictions are longer than the observational periods whereas some of the predicted mean inter-exceedences are shorter than the corresponding observational periods and some others are longer.

Citation Ben-Zvi, A. & Azmon, B. (2010) Direct relationships of discharges to the mean and standard deviation of the intervals between their exceedences. Hydrol. Sci J. 55(4), 565–577.     

The concentration control of soluble copper in a mine tailings stream

Comparison of decreasing total copper content and increasing pH of an abandoned copper mine drainage stream to the stability fields of malachite, tenorite, and cupric hydroxide indicates that soluble copper is not lost by precipitation but by sorption on the stream sediments.     

An Upper Cretaceous (Campanian-Maastrichtian) actinopterygian fish assemblage from the marginal marine Adaffa Formation of Saudi Arabia

Actinopterygian remains have been recovered from Upper Cretaceous (lower Campanian to lower Maastrichtian) marginal marine deposits of the Adaffa Formation in northwestern Saudi Arabia. The fossils comprise gars (Lepisosteidae), pachycormids (cf. Protosphyraena sp.), indeterminate pycnodontiforms, enchodontid teleosts (cf. Enchodus sp.) and other indeterminate Teleostei. This assemblage is significant because it includes a novel occurrence for the Middle East (Pachycormidae) together with taxa (Lepisosteidae, Pycnodontiformes, Enchodontidae) that have been previously recorded from Late Cretaceous faunas elsewhere in the Mediterranean Tethyan region.