Geochemical evidence of the 8.2 ka event and other Holocene environmental changes recorded in paleolagoon sediments,southeastern Brazil

The paleoclimatic record of Juréia Paleolagoon, coastal southeastern Brazil, includes cyclic and gradual changes with different intensities and frequencies through geological time, and it is controlled by astronomical, geophysical, and geological phenomena. These variations are not due to one single cause, but they result from the interaction of several factors, which act at different temporal and spatial scales. Here, we describe paleoenvironmental evidence regarding climatic and sea level changes from the last 9400 cal yr BP at the Juréia Paleolagoon — one of the main groups of protected South Atlantic ecosystems. Geochemical evidences were used to identify anomalies from multi-proxy analyses of a paleolagoon sediment core. The anomalies of centennial scale were correlated to climate and transgression–regression cycles from the Holocene period. Decadal scale anomalous oscillations in the Quaternary paleolagoon sediments occur between 9400 and 7500 cal yr BP, correlated with long- and short-term natural events, which generated high sedimentation rates, mainly between 8385 and 8375 cal yr BP (10 cm/yr). Our results suggest that a modern-day short-duration North Atlantic climatic event, such as the 8.2 ka event, could affect the environmental equilibrium in South America and intensify the South American Summer Monsoon.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Non-monotonic Responses of Phytoplankton Biomass Accumulation to Hydrologic Variability: A Comparison of Two Coastal Plain North Carolina Estuaries

Freshwater inputs often play a more direct role in estuarine phytoplankton biomass (chlorophyll a) accumulation than nitrogen (N) inputs, since discharge simultaneously controls both phytoplankton residence time and N loading. Understanding this link is critical, given potential changes in climate and human activities that may affect discharge and watershed N supply. Chlorophyll a (chla) relationships with hydrologic variability were examined in 3-year time series from two neighboring, shallow (<5?m), microtidal estuaries (New and Neuse River estuaries, NC, USA) influenced by the same climatic conditions and events. Under conditions ranging from drought to floods, N concentration and salinity showed direct positive and negative responses, respectively, to discharge for both estuaries. The response of chla to discharge was more complex, but was elucidated through conversion of discharge to freshwater flushing time, an estimate of transport time scale. Non-linear fits of chla to flushing time revealed non-monotonic, unimodal relationships that reflected the changing balance between intrinsic growth and losses through time and along the axis of each estuary. Maximum biomass occurred at approximately 10-day flushing times for both systems. Residual analysis of the fitted data revealed positive relationships between chla and temperature, suggesting enhanced growth rates at higher temperatures. N loading and system-wide, volume-weighted chla were positively correlated, and biomass yields per N load were greater than other marine systems. When combined with information on loss processes, these results on the hydrologic control of phytoplankton biomass will help formulate mechanistic models necessary to predict ecosystem responses to future climate and anthropogenic changes.     

Quantifying internal variability in a regional climate model: a case study for Southern Africa

This study aims at presenting various methodologies to separate the reproducible and irreproducible components of seasonal and intraseasonal climate variability simulated by a regional climate model over Southern Africa (south of 15°S), during an austral summer rainy season representative of the climatology. To that end, a 30-member ensemble simulation is performed using WRF laterally forced by the ERA40 reanalyses. Retained metrics include the analysis of weather regimes, signal-to-noise ratio, inter-member standard deviation and coefficient of variation. At the seasonal timescale, simulated rainfall amounts generally show a strong reproducibility, except in the subtropics and over the southern part of the Mozambique Channel. There, the number of rainy days is roughly similar in all members, while their average intensity varies extensively. At the intraseasonal timescale, the chronology of weather regimes, derived from the 500?hPa geopotential height, is highly reproducible. Rainfall variability is much less reproducible, especially in the central parts of the domain and near its outflow boundaries. Analysis of a South African regional index nonetheless indicates that both wet and dry spells tend to be accurately simulated and occur in phase in most members, demonstrating that they are embedded in large-scale variability patterns. Internal variability is lastly related to the lateral forcings along the domain boundaries. An objective classification of inflow/outflow mass fluxes allows identification of the recurrent synoptic configurations that favor strong or weak regional reproducibility. The main uncertainties concern the basic morphological features of rain-bearing systems (i.e., their spatial extension, location and propagation speed). Consequences for tropical-temperate interactions are then discussed.     

Using atmospheric fallout to date organic horizon layers and quantify metal dynamics during decomposition

High concentrations of metals in organic matter can inhibit decomposition and limit nutrient availability in ecosystems, but the long-term fate of metals bound to forest litter is poorly understood. Controlled experiments indicate that during the first few years of litter decay, Al, Fe, Pb, and other metals that form stable complexes with organic matter are naturally enriched by several hundred percent as carbon is oxidized. The transformation of fresh litter to humus takes decades, however, such that current datasets describing the accumulation and release of metals in decomposing organic matter are timescale limited. Here we use atmospheric ²¹⁰Pb to quantify the fate of metals in canopy-derived litter during burial and decay in coniferous forests in New England and Norway where decomposition rates are slow and physical soil mixing is minimal. We measure ²¹⁰Pb inventories in the O horizon and mineral soil and calculate a 60-630 year timescale for the production of mobile organo-metallic colloids from the decomposition of fresh forest detritus. This production rate is slowest at our highest elevation (∼1000 m) and highest latitude sites (>63°N) where decomposition rates are expected to be low.We calculate soil layer ages by assuming a constant supply of atmospheric ²¹⁰Pb and find that they are consistent with the distribution of geochemical tracers from weapons fallout, air pollution, and a direct ²⁰⁷Pb application at one site. By quantifying a gradient of organic matter ages with depth in the O horizon, we describe the accumulation and loss of metals in the soil profile as organic matter transforms from fresh litter to humus. While decomposition experiments predict that Al and Fe concentrations increase during the initial few years of decay, we show here that these metals continue to accumulate in humus for decades, and that enrichment occurs at a rate higher than can be explained by quantitative retention during decomposition alone. Acid extractable Al and Fe concentrations are higher in the humus layer of the O horizon than in the mineral soil immediately beneath this layer: it is therefore unlikely that physical soil mixing introduces significant Al and Fe to humus. This continuous enrichment of Al and Fe over time may best be explained by the recent suggestion that metals are mined from deeper horizons and brought into the O horizon via mycorrhizal plants. In sharp contrast to Al and Fe, we find that Mn concentrations in decomposing litter layers decrease exponentially with age, presumably because of leaching or rapid uptake, which may explain the low levels of acid extractable Mn in the mineral soil. This study quantifies how metals are enriched and lost in decomposing organic matter over a longer timescale than previous studies have been able to characterize. We also put new limits on the rate at which metals in litter become mobile organo-metallic complexes that can migrate to deeper soil horizons or surface waters.     

Granitic magmatism,basement ages,and provenance indicators in the Malay Peninsula: Insights from detrital zircon U–Pb and Hf-isotope data

The Malay Peninsula lies on two continental blocks, Sibumasu and East Malaya, which are intruded by granitoids in two provinces: the Main Range and Eastern. Previous models propose that Permian–Triassic granitoids are subduction-related and syn-to post-collisional. We present 752 U–Pb analyses that were carried out on zircons from river sands in the Malay Peninsula; of these, 243 grains were selected for Hf-isotope analyses. Our data suggest a more complex Sibumasu–East Malaya collision history. ¹⁷⁶Hf/¹⁷⁷Hf_i ratios reveal that Permian–Triassic zircons were sourced from three magmatic suites: (a) Permian crustally-derived granitoids, (b) Early-Middle Triassic granitoids with mixed mantle–crust sources, and (c) Late Triassic crustally-derived granitoids. This suggests three Permian–Triassic episodes of magmatism in the Malay Peninsula, two of which occurred in the Eastern Province. Although the exact timing of the Sibumasu–East Malaya collision remains unresolved, current data suggest that it occurred before the Late Triassic, probably in Late Permian–Early Triassic. Our data also indicate that Sibumasu and East Malaya basements are chronologically heterogeneous, but predominantly of Proterozoic age. Some basement may be Neoarchaean but there is no evidence for basement older than 2.8 Ga. Finally, we show that Hf-isotope signatures of Triassic zircons can be used as provenance indicators.     

Longitudinal and depth variation of bacterioplankton productivity and related factors in a temperate estuary

Bacterioplankton productivity (BP) spatial variation was investigated in relation to potential resources, including primary productivity and dissolved organic matter, in the micro-tidal Neuse River–Pamlico Sound estuarine system, North Carolina, USA. Estuarine BP was predicted to correlate with the trophic gradient, decreasing along the salinity gradient in parallel with the decrease in organic matter and primary productivity. This prediction was tested over four years at spatial scales ranging from kilometers to meters along the riverine axis and with depth. The general pattern of BP across the salinity gradient was unimodal and matched the phytoplankton patterns in peak location and variability. Peak locations varied with discharge, especially in 2003 when above average discharge moved peaks downstream. Spatial coherence of BP with other variables was much less at short time scales. The effect of temperature, nutrients, and phytoplankton on BP varied by location, especially fresh versus brackish stations, although only temperature explained more than 20% of the BP variation. Depth variation of BP was as great as longitudinal variation and bottom samples were often higher than surface. BP was strongly correlated with particulate organic carbon at the pycnocline and bottom, highlighting the importance of particulate matter as a resource. Station-averaged BP and phytoplankton data corresponded well with two published meta-analyses, although the offset of the freshwater station suggested longitudinal differences in community composition or resource availability.     

Woodland expansion’s influence on belowground carbon and nitrogen in the Great Basin U.S.

Vegetation changes associated with climate shifts and anthropogenic disturbance can have major impacts on biogeochemical cycling and soils. Much of the Great Basin, U.S. is currently dominated by sagebrush (Artemisia tridentate (Rydb.) Boivin) ecosystems. Sagebrush ecosystems are increasingly influenced by pinyon (Pinus monophylla Torr. & Frém and Pinus edulis Engelm.) and juniper (Juniperus osteosperma Torr. and Juniperus occidentalis Hook.) expansion. Some scientists and policy makers believe that increasing woodland cover in the intermountain western U.S. offers the possibility of increased organic carbon (OC) storage on the landscape; however, little is currently known about the distribution of OC on these landscapes, or the role that nitrogen (N) plays in OC retention. We quantified the relationship between tree cover, belowground OC, and total below ground N in expansion woodlands at 13 sites in Utah, Oregon, Idaho, California, and Nevada, USA. One hundred and twenty nine soil cores were taken using a mechanically driven diamond tipped core drill to a depth of 90 cm. Soil, coarse fragments, and coarse roots were analyzed for OC and total N. Woodland expansion influenced the vertical distribution of root OC by increasing 15-30 cm root OC by 2.6 Mg ha⁻¹ and root N by 0.04 Mg ha⁻¹. Root OC and N increased through the entire profile by 3.8 and 0.06 Mg ha⁻¹ respectively. Woodland expansion influenced the vertical distribution of soil OC by increasing surface soil (0-15 cm) OC by 2.2 Mg ha⁻¹. Woodland expansion also caused a 1.3 Mg ha⁻¹ decrease in coarse fragment associated OC from 75-90 cm. Our data suggests that woodland expansion into sagebrush ecosystems has limited potential to store additional belowground OC, and must be weighed against the risk of increased wildfire and exotic grass invasion.     

26Al‐26Mg isotope systematics of the first solids in the early solar system

High‐precision bulk aluminum‐magnesium isotope measurements of calcium‐aluminum‐rich inclusions (CAIs) from CV carbonaceous chondrites in several laboratories define a bulk ²⁶Al‐²⁶Mg isochron with an inferred initial ²⁶Al/²⁷Al ratio of approximately 5.25 × 10^?5, named the canonical ratio. Nonigneous CV CAIs yield well‐defined internal ²⁶Al‐²⁶Mg isochrons consistent with the canonical value. These observations indicate that the canonical ²⁶Al/²⁷Al ratio records initial Al/Mg fractionation by evaporation and condensation in the CV CAI‐forming region. The internal isochrons of igneous CV CAIs show a range of inferred initial ²⁶Al/²⁷Al ratios, (4.2–5.2) × 10^?5, indicating that CAI melting continued for at least 0.2 Ma after formation of their precursors. A similar range of initial ²⁶Al/²⁷Al ratios is also obtained from the internal isochrons of many CAIs (igneous and nonigneous) in other groups of carbonaceous chondrites. Some CAIs and refractory grains (corundum and hibonite) from unmetamorphosed or weakly metamorphosed chondrites, including CVs, are significantly depleted in ²⁶Al. At least some of these refractory objects may have formed prior to injection of ²⁶Al into the protosolar molecular cloud and its subsequent homogenization in the protoplanetary disk. Bulk aluminum and magnesium‐isotope measurements of various types of chondrites plot along the bulk CV CAI isochron, suggesting homogeneous distribution of ²⁶Al and magnesium isotopes in the protoplanetary disk after an epoch of CAI formation. The inferred initial ²⁶Al/²⁷Al ratios of chondrules indicate that most chondrules formed 1–3 Ma after CAIs with the canonical ²⁶Al/²⁷Al ratio.