Parascandolaite,KMgF3, a new perovskite-type fluoride from Vesuvius

The new mineral parascandolaite, isotypic to cubic perovskites, space group Pm \(\overline{3}\) m (no. 221) is the natural analog of the synthetic fluoride KMgF₃ and is related to neighborite, NaMgF₃. It was found as a volcanic sublimate at Vesuvius volcano on 1944 eruption lava scoria, associated with opal, cerussite, mimetite, phoenicochroite and coulsellite. It occurs as transparent colorless to white cubic crystals up to 0.5 mm in length with vitreous luster. The density measured by flotation in a diiodomethane–toluene mixture is 3.11(1) g/cm³; that calculated from the empirical formula and single-crystal X-ray data is 3.123 g/cm³. The mineral is isotropic with n = 1.395(5) (580 nm). The six strongest reflections in the X-ray powder diffraction pattern are: [d _obs in Å(I)(h k l)] 2.001(100)(2 0 0), 2.831(83)(1 1 0), 2.311(78)(1 1 1), 1.415(56)(2 2 0), 1.633(35)(2 1 1) and 1.206(22)(3 1 1). The unit-cell parameter is a = 4.0032(9) Å. The structure was refined to a final R(F) = 0.0149 for 35 independent observed reflections [I > 2σ(I)]. The mineral is named after the Italian mineralogist Antonio Parascandola (1902–1977).     

Geomorphology and tectonics of uplifted coasts: New chronostratigraphical constraints for the Quaternary evolution of Tyrrhenian North Calabria (southern Italy)

The Tyrrhenian coastal sector of North Calabria, stretching between Torre S. Nicola and the Lao river, belongs to the inner extensional sector of the Neogene Apennines thrust belt. It is characterised by a stair of Quaternary marine and fluvial terraces representing the geomorphic response to the interaction between the Quaternary sea level fluctuations and the regional trend of tectonic uplift experienced by the margins of the Tyrrhenian back-arc basin. Since the last century, several authors studied the North Calabria coasts, where the flight of terraces preserves significant marine and continental successions, and proposed several paleo-geomorphological and tectonic reconstructions. In this paper we present a new stratigraphic and morphostructural setting of the North Calabria coasts based on both chronostratigraphical constraints obtained from marine deposits and detailed geomorphological analysis. A ten order stair of marine terraces, stepping between 240 and 0 m a.s.l., was recognized and time-constrained by the age of the Fornaci S. Nicola marine succession which was ascribed by integrated paleoecological, biostratigraphical and paleomagentic analyses to the early Middle Pleistocene (MIS 19–15). In particular, the 240, 200 and 160 m a.s.l. high strandlines were ascribed to the Early Pleistocene and the ones between 100 and 15 m a.s.l. to the Middle Pleistocene. The total amount of the vertical motion experienced by the studied area was estimated, and evaluation of the average rates of uplift for the Middle and Late Pleistocene times were also given. Considering the elevation a.s.l. of the oldest terraces, a tectonic uplift of at least 240 m was calculated for the North Calabria coasts since the Early Pleistocene times, 100 m of which gained from the beginning of the Middle Pleistocene. On the other hand, the 8-m high Late Pleistocene strandlines display a negligible vertical displacement affecting the area during the last 130 ka. The entire staircase of terraces preserves a record of slowing down in the rate of uplift, which attained an average value of 0.15 mm/year during the Middle Pleistocene.     

The nationalization of electoral change in a geographical perspective: the case of Italy (2006–2008)

This paper assesses the nationalization of electoral change in a setting of major changes at the party level. After discussing the theoretical difference between the configuration of the electorate and its movement, the Italian case is examined. In order to check whether strategic voting dynamics took place between the 2006 and 2008 Italian Parliamentary elections, the swing voters’ estimates are obtained. After having shown that the Italian electorate behaved strategically, we investigated whether the swing had a national or a territorial pattern. The findings show that the switching occurred in Italy between the 2006 and the 2008 elections can be considered national.     

Historical seismicity of the southeastern Caribbean and tectonic implications

We have relocated the twenty-eight largest magnitude (4.3M _s 7.3) historical (1922–1963) earthquakes of the southeastern Caribbean. We also present new focal mechanisms for seven of these events. The relocations are based on reported ISSP andS arrival times that we analyzed using generalized linear inversion techniques. The new focal mechanisms were constrained by first motionP polarities as reported by the ISS and as picked by us where records were available, and by the polarities and ratios ofSH andsSH, andSV andsSV arrivals that we determined from seismograms. The results of the relocations are commensurate with the distribution of seismicity observed in the recent era: hypocenters are shallow and intermediate in depth (0–200 km), and the events occur almost exclusively in areas known to be currently seismic. The frequent seismic activity in the vicinity of the Paria Peninsula, Venezuela, is clearly a persistent feature of the regional earthquake pattern; intermediate depth earthquakes indicative of subduction beneath the Caribbean plate occur here and along the Lesser Antilles arc. The Grenadines seismic gap is confirmed as an area of low seismic moment release throughout the historical era. Trinidad and the eastern Gulf of Paria were also largely quiescent.The new focal mechanisms, despite being a sparse data set, give significant insight into both subduction processes along the Lesser Antilles arc and into the shallow deformation of the Caribbean-South America plate boundary zone. The largest earthquake to have occurred in this region, the 19 March 1953 event (M _m =7.01), is a Lesser Antilles slab deformation event, and another earthquake in this region of the Lesser Antilles is probably a rarely-observed interplate thrust event. Shallow deformation in the plate boundary zone is complex and, near the Paria Penninsula, involves mixed southeastward thrusting and dextral strike-slip on east-striking faults, and secondarily, normal faulting. Bending of the subducting Atlantic-South American plate also seems to generate seisms. The rather high ratio of intraplate deformation to interplate deformation observed along the Lesser Antilles subduction zone in the more recent era seems to have been operative in the historical era as well.     

Revised photometric elements of the eclipsing systems BS Draconis and CD Tauri

The recently published two-colour photoelectric light curves of the double-lined spectroscopic binaries CD Tauri and BS Draconis have been analysed using the Wilson and Devinney (1971) method of solution. With respect to previous solutions, CD Tau shows small but appreciable differences, while for BS Dra the old elements are confirmed. The absolute elements, computed using Popper's spectroscopic data, show that both binaries have normal Main Sequence components, and the comparison of their relative radii with the Roche lobes allows us to classify them as geometrically detached.     

Assessment of Managed Aquifer Recharge Site Suitability Using a GIS and Modeling

We completed a two‐step regional analysis of a coastal groundwater basin to (1) assess regional suitability for managed aquifer recharge (MAR), and (2) quantify the relative impact of MAR activities on groundwater levels and sea water intrusion. The first step comprised an analysis of surface and subsurface hydrologic properties and conditions, using a geographic information system (GIS). Surface and subsurface data coverages were compiled, georeferenced, reclassified, and integrated (including novel approaches for combining related datasets) to derive a spatial distribution of MAR suitability values. In the second step, results from the GIS analysis were used with a regional groundwater model to assess the hydrologic impact of potential MAR placement and operating scenarios. For the region evaluated in this study, the Pajaro Valley Groundwater Basin, California, GIS results suggest that about 7% (15 km²) of the basin may be highly suitable for MAR. Modeling suggests that simulated MAR projects placed near the coast help to reduce sea water intrusion more rapidly, but these projects also result in increased groundwater flows to the ocean. In contrast, projects placed farther inland result in more long‐term reduction in sea water intrusion and less groundwater flowing to the ocean. This work shows how combined GIS analysis and modeling can assist with regional water supply planning, including evaluation of options for enhancing groundwater resources.     

Pedestrian hazard criteria for flooded urban areas

Urban floods are sudden phenomena normally characterized by short flooding durations and devastating effects due to the high concentrations of persons, goods, and properties located in urban areas. In these cases, uncontrolled runoff can flow on urban streets, creating a significant hazard for pedestrians and vehicles. The safety of people can be compromised when they are exposed to flows that exceed their ability to remain standing or to traverse flow paths. With the aim of studying the stability of pedestrians in flooded street during storm events, a model representing an urban street in real scale was designed and built. Following a specific protocol that considering several flow rates (up to 500 l/s) and different longitudinal slopes (up to 10 %), 834 tests, using 23 human subjects, were carried out in good and poor light conditions. Hazard conditions were classified into three groups (low, medium, and high), and the parameters for which these conditions occurred were recorded. Results showed that for subjects weighing 50–60 daN (50–60 kg mass) and flow depths between 9 and 16 cm, velocities of 1.5–2 m/s can generate loss of stability due to phenomena of dragging or overturning. Empirical expressions were proposed to relate human subject characteristics (weight and height) and limiting flow conditions at which loss of stability occurs.     

Archaeo-Geophysics Surveys in Pompeii

Within the extraordinary archaeological site of Pompeii, the Porta Nocera necropolis represents one of the most important sites with funerary monuments, burials and associated graves. The inherent informative potential of the archaeological/monumental heritage present in the Porta Nocera necropolis poses notable problems for the conservation and restoration of the structures and surfaces of the funerary monuments. Brought to light at different times during the second half of last century, they show signs of degradation caused by atmospheric agents and the rising level of the water table, which threatens the foundations. Other important monuments could be still buried. In order to verify both the state of preservation of the foundations of funerary buildings, the presence of still active causes of deterioration and the probable presence of other buried archaeological structures, integrated geophysical surveys, with ground penetrating radar (GPR), passive (Self Potential—SP) and active electrical resistivity tomography (ERT), were undertaken. Furthermore a three-dimensional model of the entire necropolis was created. This involved the creation of a specific survey methodology, combining laser scanning with ortho-photogrammetry using shots taken on the ground and from the air by the use of a drone. The integration of the acquired data allows us to plan future interventions of restoration.