Mechanical Stability Of Mt. Vesuvius Volcano: Effects Of Asymmetries On The Stress Field

The effect of nonaxisymmetric elasticheterogeneities on the mechanical stability of a nearly axisymmetricvolcanic structure, with particular reference to Mt. Vesuvius (Italy) is investigated. This is done solving numerical models using a finite element codein the framework of linear elasticity. The models include gravity,anisotropic depth-dependent regional stress, the edifice, thepossible presence of a pressurized feeding system and of heterogeneities inthe elastic behavior of country rocks. The criteria to assessinstability are the development of tensile stresses and, in compression, theNavier–Coulomb criterion. The presence of asymmetric heterogeneous structureswith lateral elastic contrast has been considered by solvingthree-dimensional (3D) models. To have computationally tractable models, axis-symmetric models were solved first, considering lateral symmetricheterogeneities of different shapes and sizes around the symmetry axis. This allowed us to assess the minimum size of smallermodels (submodels) to be developed in 3D. Thesubmodels were then solved including asymmetrical heterogeneities.In all the analyzed cases, the main characteristics of theinstabilities/stabilities found with the 3D asymmetric models are verysimilar to those found by the analogous symmetric models.Moreover, the presence of sharp lateral elastic contrast at shallow depthappear to produce a greater instability on the flanks of the volcanicedifice.     

Detection of CO and Ethane in Comet 21P/Giacobini-Zinner: Evidence for Variable Chemistry in the Outer Solar Nebula

Ethane and carbon monoxide were detected in a short-period comet of probable Kuiper Belt origin. Ethane is substantially less abundant compared with Hyakutake and Hale-Bopp, two comets from the giant-planet region of the solar nebula, suggesting a heliocentric gradient in ethane in precometary ices. It is argued that processing by X-rays from the young Sun may be responsible.     

Geochemical comparisons of silicified rhyolites from two prehistoric quarries and 11 prehistoric projectile points,Socorro County,New Mexico,U.S.A.

This paper documents the results of nondestructive X‐ray fluorescence (XRF) geochemical analyses and comparisons of silicified rhyolites from the Black Canyon and Sedillo Hill prehistoric quarries near Socorro, New Mexico, and subsequent comparisons of the quarry rhyolites with 11 temporally diagnostic projectile points. At the current level of analysis, findings indicate that (1) the two quarries are chemically distinct and (2) the lithic materials of two projectile points match the silicified rhyolite from the Black Canyon quarry, suggesting quarry use during the Early Archaic period (4800–3200 B.C.) and the Late Archaic period (1800–800 B.C.). A close match between the Black Canyon rhyolite and one other point provides tentative support for use of the quarry during the Clovis Paleoindian period (9500–9000 B.C.). Additional geochemical analyses of the two quarries and other regional sources should be undertaken to verify these results and further expand our understanding of prehistoric mobility in the Southwest. © 2004 Wiley Periodicals, Inc.     

Radionuclides as tracers of water fronts in the South Indian Ocean—ANTARES IV Results

Anthropogenic ⁹⁰Sr, ^239,240Pu and ²⁴¹Am were used as tracers of water mass circulation in the Crozet Basin of the South Indian Ocean, represented by three main water fronts—Agulhas (AF), Subtropical (STF) and Subantarctic (SAF). Higher ⁹⁰Sr concentrations observed north of 43°S were due to the influence of AF and STF, which are associated with the south branch of the Subtropical gyre, which acts as a reservoir of radionuclides transported from the North to the South Indian Ocean. On the other hand, the region south of 43°S has been influenced by SAF, bringing to the Crozet Basin Antarctic waters with lower radionuclide concentrations. The ²³⁸Pu/^239,240Pu activity ratios observed in water and zooplankton samples indicated that, even 35 years after the injection of ²³⁸Pu to the Indian Ocean from the burn-up of the SNAP-9A satellite, the increased levels of ²³⁸Pu in surface water and zooplankton are still well visible. The radionuclide concentrations in seawater and their availability to zooplankton are responsible for the observed ²¹⁰Po, ^239,240Pu and ²⁴¹Am levels in zooplankton.     

Development of marine water quality criteria for the USA

The US Environmental Protection Agency has developed guidelines for deriving numerical national water quality criteria for the protection of aquatic organisms and their uses. These guidelines provide the method for deriving water quality criteria, including minimum data base requirements, data evaluation procedures, and calculations. The guidelines have been in place for a long time, and states have used them to derive water quality standards for their water bodies. More recent efforts have been directed towards the development of technical guidance based on the concept that bioassessment and biocriteria programs for estuaries and near coastal waters are interrelated and are critical components of comprehensive water resource protection and management. This is a holistic approach to protection and management, integrating biological assessments into traditional chemical and physical evaluations and augmenting the established water quality criteria. The method for deriving water quality criteria and the approach for biocriteria development for marine systems are described.     

Water in the near-infrared spectrum of comet 8P/Tuttle

High-resolution spectra of comet 8P/Tuttle were obtained in the frequency range 3449.0–3462.2 cm⁻¹ on 2008 January 3 ut using CGS4 with echelle grating on United Kingdom Infrared Telescope. In addition to observing solar pumped fluorescent lines of H₂O, the long integration time (152 min on target) enabled eight weaker H₂O features to be assigned, most of which had not previously been identified in cometary spectra. These transitions, which are from higher energy upper states, are similar in character to the so-called SH lines recorded in the post Deep Impact spectrum of comet Tempel 1. We have identified certain characteristics that these lines have in common, and which in addition to helping to define this new class of cometary line give some clues to the physical processes involved in their production. Finally, we derive an H₂O rotational temperature of     and a water production rate of  (1.4 ± 0.3) × 10²⁸  molecules s⁻¹.     

The organic composition of Comet C/2001 A2 (LINEAR): I. Evidence for an unusual organic chemistry

We used the NIRSPEC instrument on the Keck-2 telescope atop Mauna Kea, HI to observe Comet C/2001 A2 (LINEAR) in a Target of Opportunity campaign on UT 2001 July 9.5, 10.5 August 4.4, 10.5. We measured seven organic parent volatiles (C₂H₆, C₂H₂, HCN, CH₄, CO, CH₃OH, H₂CO) simultaneously with H₂O. We obtained absolute production rates and relative abundances for parent volatiles, and also measured rotational temperatures for several of these species. The chemical composition of C/2001 A2 differs substantially from any comet we have observed to date. The abundances we measure (relative to H₂O) for C₂H₆, C₂H₂, HCN, and CH₃OH are enriched by a factor of ∼2 to 3 in C/2001 A2 compared with most comets in our database. Other molecular species were detected within the typical range of measured abundances. C/2001 A2 presented a unique opportunity to study the chemistry of a fragmenting comet where pristine areas are exposed to the Sun.     

Improving digital tools for Quaternary field survey: a case study of the Rodoretto Valley (NW Italy)

In the modern geological mapping activities geomatics technologies can facilitate data collection during field survey and avoid practical problems related to the transposition of that data onto topographic maps. This paper describes an innovative tool (the Solid True OrthoPhoto; STOP) for the structured acquisition and recording of geological field survey data that is immediately available in a GIS framework. An experimental software graphical interface has been developed to manage the STOP application during the survey. The benefits of the STOP system were tested by producing a digital map of the Quaternary formations and landforms in a 3-km² sector of the Rodoretto Valley, a minor tributary of the Germanasca Valley, northwestern Italy.     

A landslide in stiff,intact clay

A landslide in a stiff clay formation, interrupting the excavation of a tunnel for a major railway in Sicily, is reported. Limit equilibrium and FEM undrained and drained analyses of the slope before tunnel excavation agree in showing that the slope was stable with a relatively high factor of safety and the critical slip surface is located well above the tunnel. The undrained stability of the tunnel checked both via FEM and via standard analytical solutions for face stability is also verified. The FEM analyses of the slope have been repeated considering the excavation of the tunnel in undrained and drained conditions. The advancement of the tunnel face is simulated in a plane strain analysis by the Panet method. In undrained conditions, the system keeps stable. In drained conditions with a stress release factor of 50 %, the slope is on the verge of failing with a very low safety factor, while with a stress release factor of 80 %, it fails following a complex mechanism that matches the observed failure surface. These findings are discussed and some conclusions attempted.     

Parascandolaite,KMgF3, a new perovskite-type fluoride from Vesuvius

The new mineral parascandolaite, isotypic to cubic perovskites, space group Pm \(\overline{3}\) m (no. 221) is the natural analog of the synthetic fluoride KMgF₃ and is related to neighborite, NaMgF₃. It was found as a volcanic sublimate at Vesuvius volcano on 1944 eruption lava scoria, associated with opal, cerussite, mimetite, phoenicochroite and coulsellite. It occurs as transparent colorless to white cubic crystals up to 0.5 mm in length with vitreous luster. The density measured by flotation in a diiodomethane–toluene mixture is 3.11(1) g/cm³; that calculated from the empirical formula and single-crystal X-ray data is 3.123 g/cm³. The mineral is isotropic with n = 1.395(5) (580 nm). The six strongest reflections in the X-ray powder diffraction pattern are: [d _obs in Å(I)(h k l)] 2.001(100)(2 0 0), 2.831(83)(1 1 0), 2.311(78)(1 1 1), 1.415(56)(2 2 0), 1.633(35)(2 1 1) and 1.206(22)(3 1 1). The unit-cell parameter is a = 4.0032(9) Å. The structure was refined to a final R(F) = 0.0149 for 35 independent observed reflections [I > 2σ(I)]. The mineral is named after the Italian mineralogist Antonio Parascandola (1902–1977).