Polar Compounds from the Dissolution of Weathered Diesel

Hydrocarbon and nonhydrocarbon components dissolving in water from fresh diesel and field samples of highly weathered diesel (spilled up to 50 years ago) from two sites were investigated. The fresh and weathered diesels were equilibrated with water using a slow-stirring method, and the product and equilibrated aqueous water samples analyzed by a range of analytical procedures. The water phase equilibrated with weathered diesels had higher total dissolved organics concentrations (96 and 8.6 mg/L at the two sites) compared to the water phase equilibrated with fresh diesel (average of 3.4 mg/L). Compound class characterization of dissolved organics in water from the weathered diesel showed that polar components were a significant compound class (98% and 42% at the two sites) and appeared largely as an unresolved complex mixture (UCM) in the total ion chromatograms (TICs). Identification of 1-adamantanol in the polar fraction of both weathered diesel samples (3.6 and 0.3 μg/L at the two sites) suggested that at least some of the associated polar components are from a petroleum source. The analysis of total petroleum hydrocarbons (TPH) is aimed at measuring only dissolved carbon and hydrogen-containing compounds, and dissolved polar compounds present as a UCM are often assumed to be from natural organic matter (NOM) and removed. This may result in a gross underestimation of the total soluble organic material in water associated with weathered diesels. In addition, the risk posed by these fuel-derived polar compounds is unknown.     

野生鲈鱼亲鱼的驯养

鲈鱼(Lateolabraxjaponicus)又称花鲈、寨花,是我国广大沿海地区土池和网箱养殖的优良品种之一,具有广温、广盐、生长快、肉质鲜美等优良品质。　　鲈鱼人工育苗的关键在于优良亲本的获得。实践证明,在鲈鱼的繁殖季节,很难捕获性腺发育良好(期、期)的野生亲鱼,使得利用海捕亲鱼进行人工授精培育苗种的工作很难实行。培育人工亲鱼的方法虽然较为困难,但势在必行。我国南方沿海由于网箱养殖条件优越,无需越冬,人工养殖4～5a可以成为优质的亲鱼。而北方尤其是山东沿海,由于存在着越冬的障碍,致使养殖业户难以坚持养殖数年,以培育出鲈鱼亲鱼。…     

The importance of population,climate change and CO2 plant physiological forcing in determining future global water stress

Future levels of water stress depend on changes in several key factors including population, climate-change driven water availability, and a carbon dioxide physiological-forcing effect on evaporation and run-off. In this study we use an ensemble of the HadCM3 climate model forced with a range of future emissions scenarios combined with a simple water scarcity index to assess the contribution of each of these factors to the projected population living in water stress over the 21st century.Population change only scenarios increase the number of people living in water stress such that at peak global population 65% of people experience some level of water stress. Globally, the climate model ensemble projects an increase in water availability which partially offsets some of the impacts of population growth. The result is 1 billion fewer people living in water stress by the 2080s under the high end emissions scenarios than if population increased in the absence of climate change.This study highlights the important role plant-physiological forcing has on future water resources. The effect of rising CO₂ is to increase available water and to reduce the number of people living in high water stress by around 200 million compared to climate only projections. This effect is of a similar order of magnitude to climate change.     

Landscapes of flexibility or landscapes of marginality? spaces of livelihood formation in a changing South African city

This article examines the idea of ‘flexibility’ within the context of a city. It uses the idea of livelihoods to contribute to the debates on flexibility, particularly on the role that ordinary people play in the transformative potential of cities. A closer examination of ordinary people’s activities show that although livelihoods are crucial to how they adapt to the changing social and economic conditions, such activities largely constitute survival strategies. Importantly, and without subscribing to a paradigm that promotes a city as a closed space, the continuing socio-spatial divisions in the city of Rustenburg, South Africa underscore the fact that ordinary people’s remarkable resourcefulness occurs under circumstances of marginality.     

Remagnetization in the Tennessee salient, Southern Appalachians, USA: Constraints on the timing of deformation

The Appalachian fold–thrust belt is characterized by a sinuous trace in map-view, creating a series of salients and recesses. The kinematic evolution of these arcuate features remains a controversial topic in orogenesis. Primary magnetizations from clastic red beds in the Pennsylvania salient show Pennsylvanian rotations that account for about half of the curvature, while Kiaman-aged (Permian) remagnetizations display no relative rotation between the limbs. The more southern Tennessee salient shows a maximum change in regional strike from ~ 65° in Virginia to ~ 10° in northern Georgia. Paleomagnetic results from thirty-two sites in the Middle to Upper Ordovician Chickamauga Group limestones and twenty sites from the Middle Cambrian Rome Formation red beds were analyzed to constrain the relative age of magnetization as well as the nature of curvature in the Tennessee salient. Results from three sites of the Silurian Red Mountain Formation were added to an existing dataset in order to determine whether the southern limb had rotated.After thermal demagnetization, all three sample suites display a down and southeasterly direction, albeit carried by different magnetic minerals. The syn-tilting direction of the Chickamauga limestones lies on the Pennsylvanian segment of the North American apparent polar wander path (APWP), indicating that deformation was about half completed by the Late Pennsylvanian. The Rome and Red Mountain Formations were also remagnetized during the Pennsylvanian. Both the Chickamauga limestones and Rome red beds fail to show a correlation between strike and declination along the salient, suggesting either that the salient was a primary, non-rotational feature or that secondary curvature occurred prior to remagnetization, as it did in Pennsylvania. Moreover, remagnetized directions from the Red Mountain sites show no statistical difference between the southern limb of the salient and the more northeasterly trending portion of the fold–thrust belt in Alabama. Thus, all of the studied units in the Tennessee salient are remagnetized and show no evidence for rotation. This confirms that remagnetization was widespread in the southern Appalachians and that any potential orogenic rotation must have occurred prior to the Late Pennsylvanian.     

Circumplanetary disc properties obtained from radiation hydrodynamical simulations of gas accretion by protoplanets

We investigate the properties of circumplanetary discs formed in three-dimensional, self-gravitating radiation hydrodynamical models of gas accretion by protoplanets. We determine disc sizes, scaleheights, and density and temperature profiles for different protoplanet masses, in solar nebulae of differing grain opacities.
We find that the analytical prediction of circumplanetary disc radii in an evacuated gap  ( R _Hill/3)  from Quillen & Trilling yields a good estimate for discs formed by high-mass protoplanets. The radial density profiles of the circumplanetary discs may be described by power laws between   r ⁻²  and   r ^−3/2  . We find no evidence for the ring-like density enhancements that have been found in some previous models of circumplanetary discs. Temperature profiles follow a  ∼ r ^−7/10  power law regardless of protoplanet mass or nebula grain opacity. The discs invariably have large scaleheights  ( H / r > 0.2)  , making them thick in comparison with their encompassing circumstellar discs, and they show no flaring.