Evidence of diverse depletion and metasomatic events in harzburgite–lherzolite mantle xenoliths from the Iberian plate (Olot, NE Spain): Implications for lithosphere accretionary processes

Mantle xenoliths from the Olot volcanic district (NE Spain) comprise a bi-modal suite consisting of protogranular spinel lherzolites (cpx 12–14%) sometimes with pargasitic amphibole, and highly refractory spinel harzburgites (cpx ≤ 1%) with coarse-grained granular textures. The lherzolites range from slightly depleted to moderately LREE-enriched with flat HREE patterns between 1.5 and 2.7 × chondrite (Ch). In contrast, the harzburgites are extremely depleted in HREE (down to 0.2 × Ch) and strongly LREE-enriched (La_N/Yb_N = 12.3–17.2). LA-ICP-MS analyses of clinopyroxene and amphibole of the lherzolites highlight variable degrees of LREE depletion (HREE up to 13 × Ch, La_N/Yb_N down to 0.01), with the exception of a single sample in which both clinopyroxene and amphibole are LREE-enriched (La_N/Yb_N up to 19). In the harzburgites, clinopyroxenes display totally different REE distributions, characterized by extreme HREE depletion (down to 0.4 × Ch) and upward convex positively fractionated middle-light REE patterns (Nd_N/Yb_N up to 20.7 × Ch; La_N/Yb_N up to 12 × Ch). Sr–Nd–Hf isotopic data for both whole-rocks and cpx separates, coherently indicate depleted mantle (DM) compositions for the lherzolites (εSr = − 15 to − 26, εNd = + 9 to + 17, εHf = + 18 to + 68) and enriched mantle (EM) compositions for the harzburgites (εSr = − 10 to + 36, εNd = − 1 to − 6, εHf = + 3 to + 8). Modelling of the clinopyroxene REE data and isotopic systematics suggest that some lherzolites were affected by pre-Paleozoic (0.6–1 By) low-degree partial melting processes, while others probably reflect some extent of refertilization of the mantle protolith by metasomatizing melts similar to the Triassic rift-related tholeiites reported from several Pyrenean localities. The harzburgites represent extreme refractory residua, resulting from a complex depletion history due to multistage melt extraction as often observed in the cratonic mantle. The distinctive REE patterns and isotopic systematics of their clinopyroxenes suggest that the harzburgites were formed by the interaction of an ultra-depleted peridotite matrix with highly alkaline basic melts similar in composition to the Permo-Triassic alkaline lamprophyres which are widespread within the Iberian plate. Lherzolites possibly represent younger lithosphere (accreted asthenosphere?) up-lifted and juxtaposed to the older subcontinental lithospheric mantle (harzburgites) during the post-Variscan rifting of the Iberian margin. These two genetically different, but adjoining, mantle domains intimately mingled along the northern Iberian margin during the subsequent plate convergence processes, leading to the close association of harzburgites and lherzolites observed in the Olot mantle xenoliths and in some Pyrenean peridotite massifs.     

Latest Pleistocene paleoecology of Jefferson's ground sloth (Megalonyx jeffersonii) and elk-moose (Cervalces scotti) in northern Illinois

New records of Jefferson's ground sloth (Megalonyx jeffersonii) and elk-moose (Cervalces scotti) from Lang Farm provide the first precise temporal correlation of these taxa with the specific environments inhabited by them near the time of their extinction. Six AMS ¹⁴C measurements establish an age of 11,405 ± 50 ¹⁴C yr B.P. for Lang Farm Cervalces and an age of 11,430 ± 60 or 11,485 ± 40 ¹⁴C yr B.P. for the Megalonyx. These measurements represent the youngest ¹⁴C dates for these two genera based on direct dating. Comparison of the dates with pollen data from northern Illinois indicates that these species inhabited a nonanalog environment that was transitional from mid-latitude tundra to mixed conifer and deciduous woodland. Although spruce (Picea sp.) was dominant, it was less abundant than prior to 12,500 ¹⁴C yr B.P. The presence of black ash (Fraxinus nigra) and fir (Abies sp.) indicates a wet climate and heavy winter precipitation. This may have been the preferred habitat for Cervalces because of its narrow geographic range. However, this habitat type was only one of many occupied by Megalonyx as indicated by its broad geographic distribution.     

Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ¹¹B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.     

The abundance of volatiles in Hawaiian tholeiitic submarine basalts

High-temperature mass spectrometric studies have been made to determine the distribution of volatiles within glassy rims of submarine pillow basalts dredged from the east rift zone of Kilauea volcano, Hawaii. The CO₂/H₂O mole ratio for glass-vapor inclusions within olivine phenocrysts in the glassy rims is greater than 30 : 1 compared to 0.06 for matrix glasses. Enclosing matrix glasses contain 0.53–0.74 wt.% H₂O, 0.02–0.04 wt.% carbon, 0.08–0.12 wt.% sulfur, 0.012–0.028 wt.% chlorine and 0.012–0.077 wt.% fluorine.     

The actinolite-hornblende series in metabasites and the so-called miscibility gap: A review

Variation of calcic amphibole chemistry with increasing grade of metamorphism in different metamorphic facies series is reviewed, and the nature of reactions generating hornblende in natural assemblages is discussed. Recent publications on the variation of calcic amphibole composition with metamorphic grade have provided a variety of conflicting evidence regarding the reality or otherwise of a miscibility gap within the calcic amphibole series. It is here concluded that, in most cases, composition gaps may be better ascribed to disequilibrium and kinetic factors, and to abrupt or discontinuous changes in the compositions of, or in the appearance or disappearance of, other phases involved in proposed reactions occurring at the actinolite-hornblende transition. The weight of current evidence does not support the existence of a miscibility gap.     

"Parametric-historic" Procedure for Probabilistic Seismic Hazard Analysis Part II: Assessment of Seismic Hazard at Specified Site

—A new methodology for probabilistic seismic hazard analysis is described. The approach combines the best features of the "deductive" (Cornell, 1968) and "historic" (Veneziano et al., 1984) procedures. It can be called a "parametric-historic" procedure. The maximum regional magnitude mmax is of paramount importance in this approach and Part I of the authors’ work (Kijko and Graham, 1998) was dedicated to developing efficient statistical procedures that can be used for the evaluation of this parameter. In Part II the approach of a probabilistic seismic hazard assessment at a given site is described. The approach permits the utilization of incomplete earthquake catalogues. It is assumed that a typical catalogue contains two types of information historical macroseismic events that occurred over a period of a few hundred years and recent, instrumental data. The historical part of the catalogue contains only the strongest events, whereas the complete part can be divided into several subcatalogues, each assumed complete above a specified threshold of magnitude. The author’s approach also takes into account uncertainty in the determination of the earthquake magnitude. The technique has been developed specifically for the estimation of seismic hazard at individual sites, without the subjective judgment involved in the definition of seismic source zones, in which specific active faults have not been mapped and identified, and where the causes of seismicity are not well understood. As an example of the application of the new technique, the results of a typical hazard analysis for a hypothetical engineering structure located in the territory of South Africa are presented. It was assumed that the only reliable information in the assessment of the seismic hazard parameters in the vicinity of the selected site comes from a knowledge of past seismicity. The procedure was applied to seismic data that were divided into an incomplete part, containing only the largest events, and two complete parts, containing information obtained from instruments. The simulation experiments described in Part I of our study have shown that the Bayesian estimator K-S-B tends to perform very well, especially in the presence of inevitable deviations from the simple Gutenberg–Richter model. In the light of this fact value &gif1; = 6.66 - 0.44, which was obtained from the K-S-B technique, was regarded as the best choice. At an exceedance probability of 10^х per annum, the median value of peak ground acceleration on rock at the site is 0.31g, and at an exceedance probability of 10^ц per annum, the median peak ground acceleration at the site is 0.39g. The median value of the maximum possible acceleration at the site is 0.40g, which was calculated from attenuation formulae by assuming the occurrence of the strongest possible earthquake, e.g., with magnitude &gif1; = 6.66 at distance 10 km.     

North Sea troughs and plate tectonics

Interlinked roughly trilete shaped (plan) predominantly sub-Upper Cretaceous trough systems extending north-south for more than 1200 km are described for the North Sea Basin. Palimpsest tectonic controls are rejected as a major explanation of their development and an explanation in terms of lithospheric plate development is offered. The trilete trough patterns are seen as failed arms, superficial manifestations and consequences of plume or hotspot generated crestal uplifts initiated mainly in Late Carboniferous and Early Permian times over an area extending from Hatton and Rockall Banks in the west to the Skagerrak in the east. The Tertiary and Late Cretaceous broad basinal development of the North Sea Basin is seen as an inner continental margin development of the Bott and Watt type related to Cenozoic spreading of the North Atlantic and development of the Cenozoic continental margin. The Mainz trilete system may be part of the overall pattern but data is inconclusive. Close relationships exist between trough and trap formation, geothermal history and the generation, maturation and accumulation of hydrocarbons.     

Metabasite amphiboles of the Scottish Dalradian

Blue-green hornblendes are observed in metabasite assemblages throughout the chlorite, biotite and garnet zones of the southwest Scottish Highlands. Actinolites are common in more Mg-rich metabasites in these zones. At low grade, hornblendes are relatively edenite-rich, and may sometimes occur together with a more Mg-rich, Al-poor actinolite. Within the garnet zone, hornblendes are pargasitic, showing extensive tschermakite substitution. Textural and chemical evidence do not indicate the presence of any miscibility gap between hornblende and actinolite within the chlorite to garnet zones in the southwest Highlands. The occurrence of hornblende-actinolite pairs in metabasites of the Scottish Dalradian, and perhaps also in other metamorphic terrains, is considered to reflect the incomplete chemical equilibration of lower grade actinolitic amphibole during prograde metamorphism, rather than a miscibility gap. The paucity of amphibole compositions intermediate between hornblende and actinolite in many metamorphic terrains is thought to reflect the rapid but continuous change of stable amphibole compositions in metabasites over a small range of increased metamorphic grade.