Geochemistry of overbank and high-order stream sediments in Belgium and Luxembourg: a way to assess environmental pollution

A geochemical survey of Belgium and Luxembourg was carried out as part of an international research project entitled ‘Regional geochemical mapping of Western Europe towards the year 2000'. The aim of this research was to map regional background geochemical patterns based on pristine or at least pre-industrial overbank samples and to deduce regional information on the degree of environmental pollution of floodplain and present-day river sediments. Over the entire study area (about 33,000 km²), 66 overbank sites have been sampled. Catchment areas range between 60 and 600 km². At each site an overbank profile has been dug out in the immediate vicinity of the river and described in detail. A first composite sample was taken 5–25 cm below the surface. This sample is supposed to represent deposition over the last centuries. Human interferences in this interval are often inferable based on changed sedimentary characteristics and the presence of anthropogenic particles such as charcoal, slags and brick fragments. A second composite sample was taken at depth, usually >1.5 m below the surface over an interval of about 20 cm. In most sites, the profile characteristics allowed to assume pre-industrial or even pristine conditions for this lower overbank sample. In some profiles this was confirmed by ¹⁴C-dating and/or by the absence of anthropogenic particles. Finally, a present-day stream sediment was sampled on the site to infer the actual pollution status. After drying at 80°C, disaggregation and sieving, the <125 μm fractions of the three sediment samples were analysed by XRF for major elements and several trace elements. Lower overbank samples generally show a direct link with the geological substrate and allow to assess natural background concentrations. Results from the mapping exercise as well as from the statistical analyses display a clear contrast between the northern part of Belgium where Cenozoic unconsolidated sandy and silty formations dominate which are especially vulnerable for erosion, and the southern part of Belgium and Luxembourg where Paleozoic and Mesozoic sandstones, carbonates, marls and shales are the prevalent lithologies. Here the shales are the most intensively eroded lithologies. This is especially reflected in the element patterns of Al₂O₃, MgO, K₂O, Ga, Ni, Rb, Sc and V which negatively correlate with SiO₂. Despite the human related pollution, the geological contrast between north and south Belgium is still recognisable in the geochemical pattern of the upper overbank and present-day stream sediment samples for the above-mentioned elements. Furthermore there is a clear increase in heavy metal contents (Zn, Cd, Pb, Cu), As and in certain locations in Ba from the lower to the upper overbank sediment, as well as to the present-day stream sediment. The relative increase in element content allows to assess the degree of pollution and helps to define those drainage areas where more detailed research is needed.     

Precursory slope distress prior to the 2010 Mount Meager landslide,British Columbia

In 2010, the south flank of Mount Meager failed catastrophically, generating the largest (53 ± 3.8 × 10⁶ m³) landslide in Canadian history. We document the slow deformation of the edifice prior to failure using archival historic aerial photographs spanning the period 1948–2006. All photos were processed using Structure from Motion (SfM) photogrammetry. We used the SfM products to produce pre-and post-failure geomorphic maps that document changes in the volcanic edifice and Capricorn Glacier at its base. The photographic dataset shows that the Capricorn Glacier re-advanced from a retracted position in the 1980s then rapidly retreated in the lead-up to the 2010 failure. The dataset also documents 60 years of progressive development of faults, toe bulging, and precursory failures in 1998 and 2009. The 2010 collapse was conditioned by glacial retreat and triggered by hot summer weather that caused ice and snow to melt. Meltwater increased pore water pressures in colluvium and fractured rocks at the base of the slope, causing those materials to mobilize, which in turn triggered several secondary failures structurally controlled by lithology and faults. The landslide retrogressed from the base of the slope to near the peak of Mount Meager involving basement rock and the overlying volcanic sequence. Elsewhere on the flanks of Mount Meager, large fractures have developed in recently deglaciated areas, conditioning these slopes for future collapse. Potential failures in these areas have larger volumes than the 2010 landslide. Anticipated atmospheric warming over the next several decades will cause further loss of snow and glacier ice, likely producing additional slope instability. Satellite- and ground-based monitoring of these slopes can provide advanced warning of future landslides to help reduce risk in populated regions downstream.     

Spatial data for landslide susceptibility, hazard, and vulnerability assessment: An overview

The aim of this paper is to discuss a number of issues related to the use of spatial information for landslide susceptibility, hazard, and vulnerability assessment. The paper centers around the types of spatial data needed for each of these components, and the methods for obtaining them. A number of concepts are illustrated using an extensive spatial data set for the city of Tegucigalpa in Honduras. The paper intends to supplement the information given in the “Guidelines for Landslide Susceptibility, Hazard and Risk Zoning for Land Use Planning” by the Joint ISSMGE, ISRM and IAEG Technical Committee on Landslides and Engineered Slopes (JTC-1). The last few decades have shown a very fast development in the application of digital tools such as Geographic Information Systems, Digital Image Processing, Digital Photogrammetry and Global Positioning Systems. Landslide inventory databases are becoming available to more countries and several are now also available through the internet. A comprehensive landslide inventory is a must in order to be able to quantify both landslide hazard and risk. With respect to the environmental factors used in landslide hazard assessment, there is a tendency to utilize those data layers that are easily obtainable from Digital Elevation Models and satellite imagery, whereas less emphasis is on those data layers that require detailed field investigations. A review is given of the trends in collecting spatial information on environmental factors with a focus on Digital Elevation Models, geology and soils, geomorphology, land use and elements at risk.     

Baja California 边缘PC14 岩芯海水表层温度及生产力变化的百年尺度记录

加利福尼亚流是北太平洋环流的重要组成部分,它的变化对全球气候及碳循环有重要影响.对位于东北太平洋低纬区BajaCalifornia外海的PC14柱状样进行了有机地球化学分析,重建了过去14ka来这一地区百年尺度的海水表面温度及生产力变化,发现其存在明显的B/A(Bling-Aller)和YD(Younger Drays)事件,但B/A和YD事件温度变化幅度小于中纬度地区.与中纬度加利福尼亚流系早中全新世温度降低不同,PC14全新世温度无明显变化趋势.这些结果表明了东太平洋低纬地区对高纬地区的气候响应以及沿岸上升流和ENSO现象对加利福尼亚流系中纬和低纬地区的影响不同.从冰消期到全新世,PC14生产力呈现阶段上升趋势,指示了由E1 Nino气候向La Nifia气候的转化以及沿岸上升流加强的总体趋势.在全新世中后期(6.5-3.8ka)生产力的降低,则可能是受ENSO加强的影响.在B/A暖期,PC14生产力增加不多,但氧最小层强度增加,这表明生产力变化不是东太平洋边缘海的氧最小层强化的控制因素.     

Diet shifts of Caribbean grunts (Haemulidae) and snappers (Lutjanidae) and the relation with nursery-to-coral reef migrations

The spatial size distribution of grunts and snappers have previously indicated the separation of juveniles in nursery habitats from the adults on the coral reef. This implies life cycle migrations from nursery habitats (such as seagrass beds and mangroves) to the coral reef. If diet shifts are related to such migrations, then the diets of these fish must change before or around the fish size at which such migrations take place. A wide size range of juveniles of two grunt species (Haemulon sciurus and Haemulon flavolineatum) and of two snapper species (Lutjanus apodus and Ocyurus chrysurus) were caught in seagrass beds and mangroves, and their gut contents identified and quantified. Regression analysis between fish size and dietary importance of small crustaceans showed a negative relationship in all four species. Positive relations were found for H. sciurus, L. apodus and O. chrysurus between fish length and the dietary importance of decapods, and for L. apodusand O. chrysurus between fish length and prey fish importance. Critical changes in the fish diets with fish size were examined by application of a Canonical Correspondence Analysis (CCA). The CCA yielded three clusters of size-classes of fishes with similar diets, and application of a Mantel test showed that each of these clusters had significantly different diets, and that each cluster diet was significantly specialised. The size at which a fish species ‘switched’ from one cluster to another was compared with size-at-maturity data and with the typical size at which these species migrate from the nursery habitats to the coral reef. H. sciurus and H. flavolineatum may be prompted to migrate from the nursery habitats to coral reef habitats because of dietary changes, or because of the development of the gonads. For L. apodus and O. chrysurus, a dietary changeover forms a more likely explanation for nursery-to-reef migrations than does sexual maturation because these species reach maturity at sizes much larger than the maximum size of individuals found in nursery habitats. Although other factors may theoretically initiate or promote the migration patterns, the results of this study indicate that ontogenetic dietary changes may crucially influence the nursery-to-coral reef migrations of these reef fish species.     

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.     

Remotely sensed estimation of forest canopy density: A comparison of the performance of four methods

In recent years, a number of alternative methods have been proposed to predict forest canopy density from remotely sensed data. To date, however, it remains difficult to decide which method to use, since their relative performance has never been evaluated. In this study the performance of: (1) an artificial neural network, (2) a multiple linear regression, (3) the forest canopy density mapper and (4) a maximum likelihood classification method was compared for prediction of forest canopy density using a Landsat ETM+ image. Comparison of confusion matrices revealed that the regression model performed significantly worse than the three other methods. These results were based on a z-test for comparison of weighted kappa statistics, which is an appropriate statistic for analysis of ranked categories. About 89% of the variance of the observed canopy density was explained by the artificial neural networks, which outperformed the other three methods in this respect. Moreover, the artificial neural networks gave an unbiased prediction, while other methods systematically under or over predicted forest canopy density. The choice of biased method could have a high impact on canopy density inventories.