Scaling from stand to landscape scale of climate change mitigation by afforestation and forest management: a modeling approach

There is a gap between the increased scientific understanding of carbon pools and fluxes at individual trees/stand and that of forested landscape with complex structures (i.e. variety of species, age classes, site characteristic and management practices). The question about how results generated from a simulated physiologically distinct individual(s)/stands grown at a particular location (scale) can be extrapolated (scaling) across a diverse population in time and space with diverse environments, has been troubling scientists for many years. Scale and scaling present three problems in common: (a) spatial heterogeneity, (b) non-linearity in response and (c) disturbance regimes. Scale, in particular, presents other three problems: (d) threshold scale for processes, (e) dominant processes with scales and (f) emerging properties of the system. Scaling presents problems with (g) feedbacks between plants and environment and (h) plant interactions. The present study proposes a modeling framework linking a process-based model SECRETS – to overcome some of the scale and scaling problems (a, b, c, d and g) – to a C accounting model GORCAM – to integrate the effects of C stock in wood products and from fossil fuel substitution. The capabilities of the modeling framework are tested against three theoretical complex forested landscapes that combine some of the five following scenarios: existing multifunctional forest under (1) actual and (2) changing environmental conditions, and afforestation of an agricultural area with (3) a new multifunctional forest or with (4) a short rotation coppice (poplar) or with (5) an agricultural crop (miscanthus) for bioenergy production. Forest reserves calculations are included for completeness of the landscape C balance and as reference. Results, on the one hand, suggest that the framework is able to simulate C sequestration and stock in ecosystem pools, wood products and fossil fuel substitution of the scenarios under actual environmental conditions. However, comparison of results under changing environmental conditions, against specific plant literature suggest SECRETS formulation must be improved with recent development in photosynthesis, stomatal conductance and N balances. On the other hand, results also suggest that under actual environmental conditions, the optimum landscape scenario to sequester C and avoid fossil emissions to the atmosphere is composed by existing multifunctional forest, reserves and afforestation with short rotation coppice for bioenergy production.     

Differential transport and degradation of bulk organic carbon and specific terrestrial biomarkers in the surface waters of a sub-arctic brackish bay mixing zone

Detailed organic geochemical analyses were performed on surface water particulate samples of the lower Kalix River and northern Bothnian Bay collected during the spring flood of 2005. Both bulk geochemical and molecular biomarker analyses indicated a predominance of terrestrially-derived particulate organic matter (POM), both of higher plant and Sphagnum origin in the low salinity zone (LSZ) of the Kalix River estuary, with an increasing contribution of marine-derived POM in the offshore Bothnian Bay basin.Two-dimensional box modeling of the mixed surface layer in the LSZ indicated that 65% of the particulate organic carbon (POC) and between 73 and 93% of the terrestrial biomarker classes analyzed (high molecular weight n-alkanes, n-alkanoic acids and n-alkanols as well as sitosterol) were degraded in the course of their weeklong transit through the inner LSZ during the spring flood. This corresponds to field-based degradation rate constants for the biomarkers of 0.5 and 2.5 day^− 1, which are similar to results reported from mesocosm experiments for related compounds. The degradation rate constant for terrestrial POC of 0.38 day^− 1 was about 20 times larger than for DOC and suggests that POC mineralization stands for 44% of the total mineralization, which is much larger than previously considered.This sub-arctic river-export regime has a geochemistry resembling that of neighboring western Russian Arctic Rivers, suggesting that a large part of the OM coastally exported from northernmost Eurasian soils may be degraded within the vicinity of the river mouths and putatively be released as carbon dioxide. The 65% degradation of terrestrial POC in the coastal surface water of this sub-arctic recipient is substantially larger than a global-average of 35% used in recent budget estimates of the fate of terrestrially-exported POC on the pan-arctic shelves. Considering ongoing and predicted changes in the Arctic Region due to global warming a more efficient degradation of river-exported terrestrial POC may have far-reaching consequences for the large-scale biogeochemical cycling of carbon in the pan-arctic region and beyond.     

Dissolved organic matter tracers reveal contrasting characteristics across high arsenic aquifers in Cambodia:A fluorescence spectroscopy study

Organic matter in the environment is involved in many biogeochemical processes,including the mobilization of geogenic trace elements,such as arsenic,into groundwater.In this paper we present the use of fluorescence spectroscopy to characterize the dissolved organic matter(DOM)pool in heavily arsenicaffected groundwaters in Kandal Province,Cambodia.The fluorescence DOM(fDOM)characteristics between contrasting field areas of differing dominant lithologies were compared and linked to other hydrogeochemical parameters,including arsenic and dissolved methane as well as selected sedimentary characteristics.Absorbance-corrected fluorescence indices were used to characterize depth profiles and compare field areas.Groundwater fDOM was generally dominated by terrestrial humic and fulvic-like components,with relatively small contributions from microbially-derived,tryptophan-like components.Groundwater fDOM from sand-dominated sequences typically contained lower tryptophan-like,lower fulvic-like and lower humic-like components,was less bioavailable,and had higher humification index than clay-dominated sequences.Methane concentrations were strongly correlated with fDOM bioavailability as well as with tryptophan-like components,suggesting that groundwater methane in these arsenic-prone aquifers is likely of biogenic origin.A comparison of fDOM tracers with sedimentary OM tracers is consistent with the hypothesis that external,surface-derived contributions to the aqueous DOM pool are an important control on groundwater hydrogeochemistry.     

Bacteriohopanepolyol biomarker composition of organic matter exported to the Arctic Ocean by seven of the major Arctic rivers

Bacteriohopanepolyols (BHPs) are a diverse group of membrane lipids produced by a wide variety of bacteria and can be used as molecular biomarkers for bacterial processes and populations in both modern and ancient environments. A group of BHPs, including adenosylhopane and structurally related compounds, have been identified as being specific to soils, enabling the transport of terrestrial organic matter (terrOM) to the marine realm to be monitored. Estuary surface sediment samples were obtained from the five Great Russian Arctic Rivers (GRARs; Ob, Yenisey, Lena, Indigirka and Kolyma) and river sediments were obtained from two North American Rivers (Yukon and Mackenzie). Analysis of the BHP signatures, using high performance liquid chromatography–tandem mass spectrometry (HPLC–MSⁿ), indicated the presence of 15 different BHPs originating from a variety of different bacteria, as well as a significant presence of terrestrially derived OM. Total BHP abundance and the contribution of the “soil-marker” BHPs to the total BHP pool increased eastwards among the GRAR sediments. This suggests increasing terrestrial OM or increased preservation of OM as a result of shorter periods of permafrost thawing. The North American rivers showed greatly differing BHP levels between the Yukon and Mackenzie rivers, with a greater BHP input and thus a relatively higher soil OM contribution from the Yukon. The Indigirka River basin in the eastern Siberian Arctic appeared to be the epicentre in the pan-Arctic BHP distribution trend, with the highest “soil-marker” BHPs but the lowest tetrafunctionalised BHPs. Aminobacteriohopanepentol, an indicator of aerobic methane oxidation, was observed in all the sediments, with the source being either the marine environment or methane producing terrestrial environments.     

Upstream control of river anastomosis by sediment overloading,upper Columbia River,British Columbia,Canada

Anastomosing rivers, systems of multiple interconnected channels that enclose floodbasins, constitute a major category of rivers for which various sedimentary facies models have been developed. While the sedimentary products of anastomosing rivers are relatively well‐known, their genesis is still debated. A rapidly growing number of ancient alluvial successions being interpreted as of anastomosing river origin, including important hydrocarbon reservoirs, urge the development of robust models for the genesis of anastomosis, to facilitate better interpretation of ancient depositional settings and controls. The upper Columbia River, British Columbia, Canada, is the most‐studied anastomosing river and has played a key role in the development of an anastomosing river facies model. Two hypotheses for the origin of upper Columbia River anastomosis include the following: (i) downstream control by aggrading cross‐valley alluvial fans; and (ii) upstream control by excessive bedload input from tributaries. Both upstream and downstream control may force aggradation and avulsions in the upper Columbia River. In order to test both hypotheses, long‐term (millennia‐scale) floodplain sedimentation rates and avulsion frequencies are calculated using ¹⁴C‐dated deeply buried organic floodplain material from cross‐valley borehole transects. The results indicate a downstream decrease in floodplain sedimentation rate and avulsion frequency along the anastomosed reach, which is consistent with dominant upstream control by sediment overloading. The data here link recent avulsion activity to increased sediment supply during the Little Ice Age (ca 1100 to 1950 ad ). This link is supported by data showing that sediment supply to the upper Columbia study reach fluctuated in response to Holocene glacial advances and retreats in the hinterland. Upstream control of anastomosis has considerable implications for the reconstruction of the setting of interpreted ancient anastomosing systems. The present research underscores that anastomosing systems typically occur in relatively proximal settings with abundant sediment supplied to low‐gradient floodplains, a situation commonly found in intermontane and foreland basins.     

Reconstruction of eroded and deposited sediment volumes of the embanked River Waal,the Netherlands,for the period ad 1631–present

In the last few centuries humans have modified rivers, and rivers have responded with noticeable changes in sedimentary dynamics. The objective of this study is to assess these responses of the sedimentary dynamics. Therefore, we calculated a sediment budget for eroded and deposited sediment volumes in a ~12‐km long floodplain section of the largest semi‐natural embanked but still dynamic lower Rhine distributary, for ~50‐years time slices between ad 1631 and present. This is the period during which embanked floodplains were formed by downstream migration of meander bends between confining dykes. Our sediment budget involves a detailed reconstruction of vertical and lateral accretion rates and erosion rates of floodplain sediment. To do so, we developed a series of historical geomorphological maps, and lithogenetic cross‐sections. Based on the maps and cross‐sections, we divided the floodplain into building blocks representing channel bed and overbank sediment bodies. Chronostratigraphy within the blocks was estimated by interpretation of heavy metal profiles and from optically stimulated luminescence (OSL) dating results. Sediment budgets were hence calculated as a change of volume of each building block between time steps. The amount of lateral accretion initially increased, as a result of island and sand bar formation following embankment. From the eighteenth century onwards, there was a decrease of lateral processes in time, which is a result of straightening of the river by human activities, and a reduction of water and sediment supply due to the construction of a new upstream bifurcation. With straightening of the river, the floodplain area grew. Artificial fixation of the channel banks after ad 1872 prevented lateral activity. From then on, overbank deposition became the main process, leading to a continuous increase of floodplain elevation, and inherent decrease of flooding frequency and sediment accumulation rate. Copyright © 2014 John Wiley & Sons, Ltd.     

Late Quaternary stratigraphic signature, offshore from the Dutch barrier shoreline

More than 400 km of high-resolution, partially digitally acquired seismic data were collected in a 30 × 60 km area offshore from the Dutch mesotidal barrier island shoreline, in order to analyze the Holocene transgressive sequence.

The investigated area was subaerially exposed during the most recent (Weichselian) Pleistocene lowstand and glaciated during the previous (Saale/Illinoian) glacial period. Sea level was probably at a level comparable to that of the present during the intervening Eem/Sangamonian highstand.

The area's seismic signature is characterized by several levels of channelization, separated by major, area-wide high-amplitude reflectors. The lowermost aerial reflector represents the Saale boulder clay. The largest channel system, which cuts this reflector, was incised during the Older Dryas cooling event and filled during the Allerød warming period. It was subsequently re-incised during the Younger Dryas and refilled during the early Holocene. The most pronounced and extensive reflector represents the base of the Holocene, and almost everywhere equals the planed-off top of the Eem highstand section. This reflector is overlain by aggradational facies, separated by one level of channelization and one planed-off (ravinement?) surface. The most prominent type of seismic facies above the lowermost level of channelization is a set of progradational clinoforms, which is interpreted as a preserved ebb-tidal delta system. This system is associated with the first Holocene shoreline of ca. 7500 yrs BP.

The eastern part of the study area contains sand ridges with a complex pattern of internal cross-stratification. Ridge-crest sediments are very well-sorted with a mean grain size of 2.8-2.6 φ (ca. 0.15 mm), whereas sediments in the troughs are well-sorted with a mean grain size of 1.8-0.8 φ (0.25–0.5 mm). Origin of these ridges is tentatively thought to be related to reworking since 5000 yrs BP, when the dynamic regime was more or less similar to that of the present and sediment supply had decreased substantially.     

One‐year monitoring of the Z24‐Bridge: environmental effects versus damage events

When using the analysis of vibration measurements as a tool for health monitoring of bridges, the problem arises of separating abnormal changes from normal changes in the dynamic behaviour. Normal changes are caused by varying environmental conditions such as humidity, wind and most important, temperature. The temperature may have an impact on the boundary conditions and the material properties. Abnormal changes on the other hand are caused by a loss of stiffness somewhere along the bridge. It is clear that the normal changes should not raise an alarm in the monitoring system (i.e. a false positive), whereas the abnormal changes may be critical for the structure's safety. In the frame of the European SIMCES‐project, the Z24‐Bridge in Switzerland was monitored during almost one year before it was artificially damaged. Black‐box models are determined from the healthy‐bridge data. These models describe the variations of eigenfrequencies as a function of temperature. New data are compared with the models. If an eigenfrequency exceeds certain confidence intervals of the model, there is probably another cause than the temperature that drives the eigenfrequency variations, for instance damage. Copyright © 2001 John Wiley & Sons, Ltd.     

On volatile element trends in gas-rich meteorites

Study of 10 volatile elements (and non-volatile Co) in co-existing light and dark portions of 5 gas-rich chondrites indicates patterns of distinct but non-uniform enrichment of volatile elements. Only Cs is enriched in all samples; Hi and Tl enrichments covary. The observed enrichments are inconsistent with prior suggestions of admixture of C1 or C2 chondritic matter, whether pristine or partly devolatilized, but suggest that both light and dark portions of each chondrite represents a compositionally more extended sampling of parental nebular material than hitherto known.