Glacial meltwater cooling of the Gulf of Mexico: GCM implications for Holocene and present-day climates

An atmospheric general circulation model, the NCAR CCM, has been used to investigate the possible effects that reduced Gulf of Mexico sea surface temperatures (SST) could have on regional and hemispheric climates. ¹⁸O records and terrestrial evidence indicate at least two major glacial meltwater discharges into the Gulf of Mexico subsequent to the last glacial maximum. It is probable that these discharges reduced Gulf of Mexico SST. We have conducted three numerical experiments, with imposed gulf-wide SST coolings of 3°C, 6°C, and 12°C, and find in all three experiments significant reductions in the North Atlantic storm-track intensity, along with a strong decrease in transient eddy water vapor transport out of the Gulf of Mexico. Surface pressures are higher over the North Atlantic, indicating a reduction of the climatological Icelandic low. The region is generally cooler and drier, with a reduction in precipitation that agrees well with evidence from Greenland ice cores. Other statistically significant changes occur across the Northern Hemisphere, but vary between the three experiments. In particular, warmer, wetter conditions are found over Europe for both the 6°C and 12°C SST reductions, but cooler conditions are found for the 3°C reduction. This indicates a dependence, in both the sign and magnitude of the model response, on the magnitude of the imposed SST anomaly. The results suggest that the present-day North Atlantic storm track is dependent on warm Gulf of Mexico SST for much of its intensity. They also suggest that meltwater-induced coolings may help account, in part, for some of the climatic oscillations that occurred during the last glacial/interglacial transition.     

Convective instabilities in a variable viscosity fluid cooled from above

Whether in the mantle or in magma chambers, convective flows are characterized by large variations of viscosity. We study the influence of the viscosity structure on the development of convective instabilities in a viscous fluid which is cooled from above. The upper and lower boundaries of the fluid are stress-free. A viscosity dependence with depth of the form ν₀ + ν₁ exp(?γ.z) is assumed. After the temperature of the top boundary is lowered, velocity and temperature perturbations are followed numerically until convective breakdown occurs. Viscosity contrasts of up to 10⁷ and Rayleigh numbers of up to 10⁸ are studied.For intermediate viscosity contrasts (around 10³), convective breakdown is characterized by the almost simultaneous appearance of two modes of instability. One involves the whole fluid layer, has a large horizontal wavelength (several times the layer depth) and exhibits plate-like behaviour. The other mode has a much smaller wavelength and develops below a rigid lid. The “whole layer” mode dominates for small viscosity contrasts but is suppressed by viscous dissipation at large viscosity contrasts.For the “rigid lid” mode, we emphasize that it is the form of the viscosity variation which determines the instability. For steep viscosity profiles, convective flow does not penetrate deeply in the viscous region and only weak convection develops. We propose a simple method to define the rigid lid thickness. We are thus able to compute the true depth extent and the effective driving temperature difference of convective flow. Because viscosity contrasts in the convecting region do not exceed 100, simple scaling arguments are sufficient to describe the instability. The critical wavelength is proportional to the thickness of the thermal boundary layer below the rigid lid. Convection occurs when a Rayleigh number defined locally exceeds a critical value of 160–200. Finally, we show that a local Rayleigh number can be computed at any depth in the fluid and that convection develops below depth z_r (the rigid lid thickness) such that this number is maximum.The simple similarity laws are applied to the upper mantle beneath oceans and yield estimates of 5 × 10¹⁵?5 × 10¹⁶ m² s^?1 for viscosity in the thermal boundary layer below the plate.     

An aerosol climatology of Samoa

An atmospheric monitoring station is operated at Cape Matatula, American Samoa, by the Geophysical Monitoring for Climatic Change program under the National Oceanic and Atmospheric Administration. A nearly continuous record of condensation nucleus (CN) concentration and multiwavelength aerosol scattering extinction coefficient (_sp) is available from mid-1977 to the present. This report presents the 1977–1983 data. The long-term mean of CN concentration is 274 cm^-3 the long-term mean of _sp (550 nm) is 1.54×10^-5, and no significant long-term, annual, or diurnal trend is apparent in either data record.     

Natural tracers for sediment transport studies

The use of natural differences in composition between marine and fluvial sediments makes it possible to determine their mixing ratio in estuarine deposits. Differences in chemical, mineralogical and isotope geochemical composition can be used as tracers, provided that three criteria are met: conservative behaviour during transport, with time, and after deposition. Examples of the utility of natural tracers are presented, including their use for the interpretation of pollutant patterns in estuaries. The application of natural tracers has shown that marine sediments may be transported past the freshwater boundary in estuaries, and thus contribute to the sedimentation in freshwater tidal areas.     

X-Ray Fluorescence Determination of Trace Elements in 6 B.C.S. and 5 P.R.E. Reference Materials

The concentrations of 20 trace elements in 6 British Chemical Standards (BCS) reference materials and 5 European Federation of Refractories Producers (PRE) reference materials have been determined by X-ray fluorescence spectrometry.     

The contribution of humic substances to the acidity of colored natural waters

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.     

Lacustrine basin hydrocarbon exploration – current thoughts

Although much of the world's petroleum resource-base is associated with marine systems, regionally lacustrine petroleum systems are important. Individual accumulations may exceed several billion barrels. In each of these cases the oil is derived from a lacustrine source rock and may be produced from either nonmarine or marine reservoir rocks. The purpose of this paper is to describe the factors that control lacustrine source rock development and the nature of lacustrine reservoirs. Lacustrine oils display different physical and chemical characteristics than their marine counterparts. These differences can be related to the nature of their precursor material. Although the nature of the products are different, the geochemical threshold criteria for defining source rocks in both settings are the same because of common expulsion requirements. Commercially significant lacustrine systems require the presence of large, long-lived lakes. Such lake settings are tectonic in origin and restricted to climatic settings where precipitation exceeds evaporation. Within these large lake systems three primary factors determine source rock potential and quality. These factors are primary productivity level, organic preservation potential, and matrix sedimentation rate, which controls the dilution of preserved organic matter. Source rock potential is maximized where both productivity and preservation potential are maximized and sedimentation rate is minimized. To some degree these factors can compensate for each other. Hydrocarbon reservoir potential within lacustrine basins is partially impacted by overall tectonic setting. Within extensional settings, transport distances tend to be limited, with much of the sediment being transported away from the basin. The sediments delivered to the lake are poorly sorted and sedimentologically immature, commonly resulting in poor reservoirs due to both primary properties and their susceptibility to diagenesis. Within rifts better reservoirs tend to develop along platform or flexural margins. Stacking of reservoirs is important in lacustrine systems but baffles and barriers are often present between individual sand units. These barriers form as a result of lake level fluctuations. In compressional settings transport distances tend to be longer, resulting in more mature, better sorted sediments leading to higher quality reservoirs. These reservoirs typically develop in fluvial-deltaic and wave-dominated shoreline settings. Lacustrine carbonate reservoirs are locally important. These carbonates tend to develop during lake level lowstands and are dependent on diagenesis (dissolution and karstification) for porosity and permeability development. Lacustrine reservoirs are often stratigraphically and areally limited and display low individual well production rates. Within pure lacustrine systems exploration opportunities appear to be often restricted by either reservoir presence or quality (i.e., production rates). The best exploration opportunities in lacustrine basins appear to be associated with hybrid systems where a lacustrine source and marine reservoir exist.