Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.     

The oxygen isotopic composition of the fraction less than 2 microns (clay fraction) in Recent sediments from western Europe

The oxygen isotopic composition of the clay fraction in Recent argillaceous sediments in western Europe shows regional differences, the δ¹⁸_SMOW values varying between + 15.8 and + 21.7‰. This phenomenon is used for sediment-transport studies. In the Rhine-Meuse estuary a landward transport of marine sediments is observed. The clay fraction of the sediments in the Wadden Sea is only for a minor part derived from the rivers Rhine and Meuse.     

Sensitivity of crop yields and land resource potential to climatic change in Ontario,Canada

Increasing concentrations of atmospheric CO₂ and other greenhouse gases are expected to contribute to a global warming. This paper examines the potential implications of a climatic change corresponding to a doubling of atmospheric concentrations of CO₂ on crop production opportunities throughout Ontario, a major food producing region in Canada. The climate is projected to become warmer and drier, but the extent of these shifts are expected to vary from region to region within Ontario. The effect of this altered climate on crop yields and the area of land capable of supporting specific crops varies according to region, soil quality and crop type. Most notable are the enhanced opportunities for grains and oilseeds in the northern regions, and the diminished production prospects for most crops in the most southerly parts of Ontario.     

The freeze-thaw weathering regime at a section of the Niagara escarpment on the Bruce Peninsula,Southern Ontario,Canada

The bedrock freeze-thaw and moisture regimes at an actively eroding site on the Niagara Escarpment, Bruce Peninsula, southern Ontario, were monitored between December 1983 and April 1984, and the results compared with amounts of debris collected in an adjacent rock trap. Frost wedging in pre-existing rock fissures is the primary mechanism responsible for the observed rockfall events; hydration effects are negligible. Debris production was more closely related to the duration of the freezing leg of the freeze-thaw cycle than to intensity or to cycle frequency. Release also coincided with periods of high pore saturation (> 60 per cent) and the seepage of water from cracks and fissures. Fewer freeze-thaw cycles were recorded in the air than at 1 and 3.5 cm in the bedrock. The number of cycles that could be declared geomorphologically effective according to established temperature criteria was normally less than half the total number of freeze-thaw cycles recorded in both air and bedrock. Under the current temperature regime at the field site, few effective cycles are capable of penetrating more than 5 cm into the free face.     

A study of the geoelectrical properties of peatlands and their influence on ground-penetrating radar surveying1

Geophysical surveys and chemical analyses on cores were carried out in three Ontario peatlands, from which we have gained a better understanding of the peat properties that control the geophysical responses. The electrical conductivity depends linearly on the concentration of total dissolved solids in the peat pore waters and the pore waters in turn bear the ionic signatures of the underlying mineral sediments. The ionic concentration, and thus the electrical conductivity, increase linearly from the surface to basement. The average bulk electrical conductivity of peatlands at Ellice Marsh, near Stratford, and at Wally Creek Area Forest Drainage Project, near Cochrane, are of the order of 25 mS/m. The Mer Bleue peatland, near Ottawa, has extremely high electrical conductivity, reaching levels of up to 380 mS/m near the base of the peat. The Mer Bleue peatland water has correspondingly high values of total dissolved solids, which originate from the underlying Champlain Sea glaciomarine clays. The dielectric permittivity in peats is largely controlled by the bulk water content. Ground penetrating radar can detect changes in water content greater than 3%, occurring within a depth interval less than 15 cm. The principal peatland interfaces detected are the near-surface aerobic to anaerobic transition and the peat to mineral basement contact. The potential for the successful detection of the basement contact using the radar can be predicted using the radar instrument specifications, estimates of the peatland depth, and either the bulk peat or the peat pore water electrical conductivities. Predicted depths of penetration of up to 10 m for Ellice Marsh and Wally Creek exceed the observed depths of 1 to 2 m. At Mer Bleue, on the other hand, we observe that, as predicted, a 100 MHz signal will penetrate to the base of a 2 m thick peat but a 200 MHz signal will not.     

Energy market failure in road transport: Is there scope for ‘no regrets’ greenhouse gas reduction?

The Australian Government policy on reduction of greenhouse gas emissions announced in 1990 includes exploring the scope for immediate, low cost reductions. Such measures can be taken as including ‘no regrets’ policies: those that, in addition to mitigating potential climate change, confer economic gains (including other environmental benefits) which exceed their costs. Some possible ‘no regrets’ opportunities and policies are identified relevant to energy use by the road transport sector over the period to 2020. The MARKALMENSA multi-period linear programming model of the Australian energy sector is used to investigate the cost-effectiveness of these policies.     

Geoid anomalies over two South Atlantic fracture zones

Seasat altimetry profiles across the Falkland-Agulhas fracture zone (FZ) and the Ascension FZ in the South Atlantic were examined for evidence of step-like geoid offsets predicted from thermal modeling of the lithosphere. The geoid profiles exhibit much short-wavelength power and the step-like offsets are often small, making reliable estimation of the heights of the observed geoid offsets difficult. The offsets were estimated by the least-squares fitting of quadratic curves incorporating a step function to the altimetry profiles. A preferred offset value was determined for each profile by taking the average of step heights computed with various distances around the fracture zone excluded from the fit. The age of the crust surrounding the fracture zones, necessary for computing a theoretical geoid offset, was determined from surface ship magnetic anomaly data and from existing ocean floor age maps.Observed variations in geoid step height with age of the lithosphere are not consistent with those predicted from standard thermal plate models. For ages less than 30 Ma, the step offsets across both fracture zones decrease in a manner appropriate for an unusually thin plate with a thickness of 50–75 km. At greater ages, the offsets show complex behavior that may be due to bathymetric features adjacent to the fracture zones. Similar geoid patterns on opposite branches of the Falkland-Agulhas FZ are indicative of processes that act symmetrically on both sides of the Mid-Atlantic Ridge. This behavior of the geoid is consistent both with small-scale convection occurring beneath the lithosphere and with bathymetric features originally produced along the ridge crest and now located symmetrically on opposite sides of the ridge. The west flank of the Ascension FZ displays a regrowth in step height at about 40 Ma consistent with small-scale convection and in agreement with other studies of Pacific and South Atlantic fracture zones.     

SrNdPb geochemical morphology between 10° and 17°N on the Mid-Atlantic Ridge: A new MORB isotope signature

Basalts dredged along the Mid-Atlantic Ridge axis between 10°N and 17°N have been studied for their trace element characteristics [1]. To give complementary information on mantle source history and magma genesis, these samples have been analysed for their SrNdPb isotopic compositions. There is a good correlation between the structure of the ridge axis which shows a topographic anomaly centered around 14°N and hygromagmaphile element ratios such as Rb/Sr, (Nb/Zr)_N or Sm/Nd as well as isotopic ratios plotted as a function of latitude. The samples coming from the 14°N topographic high show new MORB SrNd isotopic characteristics which pictured in a classical mantle array diagram, put their representative points close to HIMU sources of ocean islands such as St. Helena, Tubuaïand Mangaia. The 14°N mantle source presents geochemical characteristics which indicate mantle differentiation processes and a mantle history that are more distinct than so far envisaged from typical MORB data. Pb data indicates that the 14°N mantle source cannot be the result of binary mixing between a depleted mantle and a HIMU-type source. Rather, the enriched endmember could itself be a mixture of Walvis-like and HIMU-like materials. The geochimical observations presented favour the model of an incipient ridge-centered plume, in agreement with [1].