Behandlung von anilinhaltigem Abwasser mit Fentons Reagenz Treatment of Aniline Containing Waste Water by Fenton's Reagent

A chemical-physical method for treatment of aniline containing waste water was developed. At the chemical stage aniline is polymerized by Fenton's reagent. Thus insoluble polyaniline precipitates. The best reaction conditions are: pH-value of 2–3, stepwise dosing of 60 mL H₂O₂ (30%) and 12 mL saturated FeSO₄-solution per litre waste water. The molar ratio Fe(II): H₂O₂ amounts to 0.3:10. The concentration of aniline is reduced by this chemical treatment from about 20 g/L to 30–40 mg/L. By adsorption at activated charcoal the concentration of aniline can be reduced further to 0.2 mg/L. The resulting sludge can easily be dewatered in a chamber filter press.     

Glacial meltwater cooling of the Gulf of Mexico: GCM implications for Holocene and present-day climates

An atmospheric general circulation model, the NCAR CCM, has been used to investigate the possible effects that reduced Gulf of Mexico sea surface temperatures (SST) could have on regional and hemispheric climates. ¹⁸O records and terrestrial evidence indicate at least two major glacial meltwater discharges into the Gulf of Mexico subsequent to the last glacial maximum. It is probable that these discharges reduced Gulf of Mexico SST. We have conducted three numerical experiments, with imposed gulf-wide SST coolings of 3°C, 6°C, and 12°C, and find in all three experiments significant reductions in the North Atlantic storm-track intensity, along with a strong decrease in transient eddy water vapor transport out of the Gulf of Mexico. Surface pressures are higher over the North Atlantic, indicating a reduction of the climatological Icelandic low. The region is generally cooler and drier, with a reduction in precipitation that agrees well with evidence from Greenland ice cores. Other statistically significant changes occur across the Northern Hemisphere, but vary between the three experiments. In particular, warmer, wetter conditions are found over Europe for both the 6°C and 12°C SST reductions, but cooler conditions are found for the 3°C reduction. This indicates a dependence, in both the sign and magnitude of the model response, on the magnitude of the imposed SST anomaly. The results suggest that the present-day North Atlantic storm track is dependent on warm Gulf of Mexico SST for much of its intensity. They also suggest that meltwater-induced coolings may help account, in part, for some of the climatic oscillations that occurred during the last glacial/interglacial transition.     

Convective instabilities in a variable viscosity fluid cooled from above

Whether in the mantle or in magma chambers, convective flows are characterized by large variations of viscosity. We study the influence of the viscosity structure on the development of convective instabilities in a viscous fluid which is cooled from above. The upper and lower boundaries of the fluid are stress-free. A viscosity dependence with depth of the form ν₀ + ν₁ exp(?γ.z) is assumed. After the temperature of the top boundary is lowered, velocity and temperature perturbations are followed numerically until convective breakdown occurs. Viscosity contrasts of up to 10⁷ and Rayleigh numbers of up to 10⁸ are studied.For intermediate viscosity contrasts (around 10³), convective breakdown is characterized by the almost simultaneous appearance of two modes of instability. One involves the whole fluid layer, has a large horizontal wavelength (several times the layer depth) and exhibits plate-like behaviour. The other mode has a much smaller wavelength and develops below a rigid lid. The “whole layer” mode dominates for small viscosity contrasts but is suppressed by viscous dissipation at large viscosity contrasts.For the “rigid lid” mode, we emphasize that it is the form of the viscosity variation which determines the instability. For steep viscosity profiles, convective flow does not penetrate deeply in the viscous region and only weak convection develops. We propose a simple method to define the rigid lid thickness. We are thus able to compute the true depth extent and the effective driving temperature difference of convective flow. Because viscosity contrasts in the convecting region do not exceed 100, simple scaling arguments are sufficient to describe the instability. The critical wavelength is proportional to the thickness of the thermal boundary layer below the rigid lid. Convection occurs when a Rayleigh number defined locally exceeds a critical value of 160–200. Finally, we show that a local Rayleigh number can be computed at any depth in the fluid and that convection develops below depth z_r (the rigid lid thickness) such that this number is maximum.The simple similarity laws are applied to the upper mantle beneath oceans and yield estimates of 5 × 10¹⁵?5 × 10¹⁶ m² s^?1 for viscosity in the thermal boundary layer below the plate.     

An aerosol climatology of Samoa

An atmospheric monitoring station is operated at Cape Matatula, American Samoa, by the Geophysical Monitoring for Climatic Change program under the National Oceanic and Atmospheric Administration. A nearly continuous record of condensation nucleus (CN) concentration and multiwavelength aerosol scattering extinction coefficient (_sp) is available from mid-1977 to the present. This report presents the 1977–1983 data. The long-term mean of CN concentration is 274 cm^-3 the long-term mean of _sp (550 nm) is 1.54×10^-5, and no significant long-term, annual, or diurnal trend is apparent in either data record.     

X-Ray Fluorescence Determination of Trace Elements in 6 B.C.S. and 5 P.R.E. Reference Materials

The concentrations of 20 trace elements in 6 British Chemical Standards (BCS) reference materials and 5 European Federation of Refractories Producers (PRE) reference materials have been determined by X-ray fluorescence spectrometry.     

The contribution of humic substances to the acidity of colored natural waters

An operationally defined carboxyl content of humic substances extracted from rivers, streams, lakes, wetlands, and groundwaters throughout the United States and Canada is reported. Despite the diversity of the samples, only small variations were observed in this humic carboxyl content. The dissociation behavior of two combined fulvic/humic acid extracts was studied and it was found that the dissociation of the humics varied in a predictable manner with pH. Using a carboxyl content of 10 μeq/ mg humic organic carbon, and mass action quotient calculated from sample pH, the ionic balances of three highly colored Nova Scotia rivers were estimated.     

A derived probability distribution approach to stormwater quality modeling

The closed-form analytical stormwater quality models are developed for simulating urban catchment pollutant buildup and washoff processes. By integrating the rainfall–runoff transformation with pollutant buildup and washoff functions, stormwater quality measures, such as the cumulative distribution functions (CDFs) of pollutant loads, the expected value of pollutant event mean concentrations (EMCs) and the average annual pollutant load can be derived. This paper presents methodologies and major procedures for the development of urban stormwater quality models based on derived probability distribution theory. In order to investigate the spatial variation in model parameters and its impact on stormwater pollutant buildup and washoff processes as well as pollutant loads to receiving waters, an extended form of the original rainfall–runoff transformation which is based on lumped runoff coefficient approach is proposed to differentiate runoff generation mechanisms between the impervious and pervious areas of the catchment. In addition, as a contrast to the aggregated pollutant buildup models formulated with a single lumped buildup parameter, the disaggregated form of the pollutant buildup model is proposed by introducing a number of physically-based parameters associated with pollutant buildup and washoff processes into the pollutant load models. The results from the case study indicate that analytical urban stormwater management model are capable of providing results in good agreement with the field measurements, and can be employed as alternatives to continuous simulation models in the evaluation of long-term stormwater quality measures.