Eclipse reappearances of Io: Time-resolved spectroscopy (1.9-4.2 μm)

We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO₂ frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO₂ induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO₂ bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν₁ + ν₃]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO₂ bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm⁻¹) 4ν₁ band of SO₂ frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO₂ bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO₂ in the vertical column above Io’s surface was ∼4 × 10⁻⁵ g cm⁻².     

Partitioning of metals (Fe,Pb, Cu,Zn) in urban run‐off from the Kaikorai Valley,Dunedin, New Zealand

Urban run‐off from a catchment in Dunedin, New Zealand was sampled and chemically characterised (iron (Fe), lead (Pb), copper (Cu), zinc (Zn) in total and <0.4 (im fractions, suspended solids, nitrogen (N), phosphorus (P), dissolved organic carbon, major ions, pH) during base flows, and storm flows from five rainfall events. Fe and Pb were found to be predominantly particle‐associated (>0.4 μm) and their concentrations increased significantly at the beginning of storm run‐off. In contrast, the majority of Cu and Zn was found in the <0.4μm fraction before rainfall events but during the initial period of storm flows a significant proportion of Cu and Zn was also present in the >0.4 μm fraction. The results indicate that Cu and Zn may be more bio‐available, and more difficult to remove by storm‐water treatment, than Pb. The pH level and the concentration of major ions (Ca⁺², Na⁺, Mg⁺², K⁺), dissolved reactive phosphorus, and nitrate generally decreased during storm flows as a result of dilution by rainwater. Concentrations of total N and P often increased during the initial period of storm run‐off, which was likely because of wash‐off of particulate plant material.     

A method for the calculation of anaerobic oxidation of methane rates across regional scales: an example from the Belt Seas and The Sound (North Sea–Baltic Sea transition)

Estimating the amount of methane in the seafloor globally as well as the flux of methane from sediments toward the ocean–atmosphere system are important considerations in both geological and climate sciences. Nevertheless, global estimates of methane inventories and rates of methane production and consumption through anaerobic oxidation in marine sediments are very poorly constrained. Tools for regionally assessing methane formation and consumption rates would greatly increase our understanding of the spatial heterogeneity of the methane cycle as well as help constrain the global methane budget. In this article, an algorithm for calculating methane consumption rates in the inner shelf is applied to the gas-rich sediments of the Belt Seas and The Sound (North Sea–Baltic Sea transition). It is based on the depth of free gas determined by hydroacoustic techniques and the local methane solubility concentration. Due to the continuous nature of shipboard hydroacoustic measurements, this algorithm captures spatial heterogeneities in methane fluxes better than geochemical analyses of point sources such as observational/sampling stations. The sensibility of the algorithm with respect to the resolution of the free gas depth measurements (2 m vs. 50 cm) is proven of minor importance (a discrepancy of <10%) for a small part of the study area. The algorithm-derived anaerobic methane oxidation rates compare well with previous measured and modeling studies. Finally, regional results reveal that contemporary anaerobic methane oxidation in worldwide inner-shelf sediments may be an order of magnitude lower (ca. 0.24 Tmol year^–1) than previous estimates (4.6 Tmol year^–1). These algorithms ultimately help improve regional estimates of anaerobic oxidation of methane rates.     

A survey of the occurrence of Bacillus anthracis in North American soils over two long-range transects and within post-Katrina New Orleans

Soil samples were collected along a north–south transect extending from Manitoba, Canada, to the US–Mexico border near El Paso, Texas in 2004 (104 samples), a group of sites within New Orleans, Louisiana following Hurricane Katrina in 2005 (19 samples), and a Gulf Coast transect extending from Sulphur, Louisiana, to DeFuniak Springs, Florida, in 2007 (38 samples). Samples were collected from the top 40 cm of soil and were screened for the presence of total Bacillus species and Bacillus anthracis (anthrax), specifically using multiplex-polymerase chain reaction (PCR). Using an assay with a sensitivity of 170 equivalent colony-forming units (CFU) g⁻¹ field moist soil, the prevalence rate of Bacillus sp./B. anthracis in the north–south transect and the 2005 New Orleans post-Katrina sample set were 20/5% and 26/26%, respectively. Prevalence in the 2007 Gulf Coast sample set using an assay with a sensitivity of 4 CFU g⁻¹ of soil was 63/0%. Individual transect-set data indicate a positive relation between occurrences of species and soil moisture or soil constituents (i.e., Zn and Cu content). The 2005 New Orleans post-Katrina data indicated that B. anthracis is readily detectable in Gulf Coast soils following flood events. The data also indicated that occurrence, as it relates to soil chemistry, may be confounded by flood-induced dissemination of germinated cells and the mixing of soil constituents for short temporal periods following an event.     

Accumulation of short-chain fatty acids in an aquitard linked to anaerobic biodegradation of petroleum hydrocarbons

Investigation of a 17 m vertical profile of a silt and clay aquitard at a natural gas well site in Alberta, Canada revealed a contaminant plume of gas condensate, along with high concentrations of acetate, propionate and butyrate. The pattern of the distribution of these short-chain fatty acids in groundwater and sediment samples suggested that they have been produced by microorganisms in a process associated with degradation of the condensate hydrocarbons. It is suggested that, in certain zones, under water-saturated and/or anaerobic conditions, these acids were actively consumed by SO₄-reducing bacteria. Analyses of DNA extracts by denaturing gel gradient electrophoresis (DGGE) indicated that, compared to sediment samples collected from outside the condensate plume, contaminated samples tended to have fewer, but more strongly developed bands of DNA, which typically had closest affinities to known anaerobes, including species of Fe-reducing Geobacter, and SO₄-reducing Desulfosporosinus.     

Hydrocarbons on Saturn's satellites Iapetus and Phoebe

Material of low geometric albedo (pV?0.1) is found on many objects in the outer Solar System, but its distribution in the saturnian satellite system is of special interest because of its juxtaposition with high-albedo ice. In the absence of clear, diagnostic spectral features, the composition of this low-albedo (or “dark”) material is generally inferred to be carbon-rich, but the form(s) of the carbon is unknown. Near-infrared spectra of the low-albedo hemisphere of Saturn's satellite Iapetus were obtained with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft at the fly-by of that satellite of 31 December 2004, yielding a maximum spatial resolution on the satellite's surface of ∼65 km. The spectral region 3-3.6 μm reveals a broad absorption band, centered at 3.29 μm, and concentrated in a region comprising about 15% of the low-albedo surface area. This is identified as the CH stretching mode vibration in polycyclic aromatic hydrocarbon (PAH) molecules. Two weaker bands attributed to CH₂ stretching modes in aliphatic hydrocarbons are found in association with the aromatic band. The bands most likely arise from aromatic and aliphatic units in complex macromolecular carbonaceous material with a kerogen- or coal-like structure, similar to that in carbonaceous meteorites. VIMS spectra of Phoebe, encountered by Cassini on 11 June 2004, also show the aromatic hydrocarbon band, although somewhat weaker than on Iapetus. The origin of the PAH molecular material on these two satellites is unknown, but PAHs are found in carbonaceous meteorites, cometary dust particles, circumstellar dust, and interstellar dust.     

Compositional mapping of Saturn's satellite Dione with Cassini VIMS and implications of dark material in the Saturn system

Cassini VIMS has obtained spatially resolved imaging spectroscopy data on numerous satellites of Saturn. A very close fly-by of Dione provided key information for solving the riddle of the origin of the dark material in the Saturn system. The Dione VIMS data show a pattern of bombardment of fine, sub-0.5-μm diameter particles impacting the satellite from the trailing side direction. Multiple lines of evidence point to an external origin for the dark material on Dione, including the global spatial pattern of dark material, local patterns including crater and cliff walls shielding implantation on slopes facing away from the trailing side, exposing clean ice, and slopes facing the trailing direction which show higher abundances of dark material. Multiple spectral features of the dark material match those seen on Phoebe, Iapetus, Hyperion, Epimetheus and the F-ring, implying the material has a common composition throughout the Saturn system. However, the exact composition of the dark material remains a mystery, except that bound water and, tentatively, ammonia are detected, and there is evidence both for and against cyanide compounds. Exact identification of composition requires additional laboratory work. A blue scattering peak with a strong UV-visible absorption is observed in spectra of all satellites which contain dark material, and the cause is Rayleigh scattering, again pointing to a common origin. The Rayleigh scattering effect is confirmed with laboratory experiments using ice and 0.2-μm diameter carbon grains when the carbon abundance is less than about 2% by weight. Rayleigh scattering in solids is also confirmed in naturally occurring terrestrial rocks, and in previously published reflectance studies. The spatial pattern, Rayleigh scattering effect, and spectral properties argue that the dark material is only a thin coating on Dione's surface, and by extension is only a thin coating on Phoebe, Hyperion, and Iapetus, although the dark material abundance appears higher on Iapetus, and may be locally thick. As previously concluded for Phoebe, the dark material appears to be external to the Saturn system and may be cometary in origin. We also report a possible detection of material around Dione which may indicate Dione is active and contributes material to the E-ring, but this observation must be confirmed.     

The nucleus of comet P/Schwassmann-Wachmann 1

The thermal flux in the 20-μm Q filter band of comet P/Schwassmann-Wachmann 1 was measured some 77 days after the most recent previous eruption, and when the visual magnitude was about 17.6. Considerations of the eruptive history of the comet, and in particular its tendency to fade to a minimum threshold brightness level between eruptions, suggest that the measurement refers to an essentially bare nucleus. Using the standard photometric/radiometric technique for calculating the diameters and geometric albedos of asteroids and planetary satellites, and the assumption that the bare nucleus is measured, we find that the diameter of the nucleus is 40±5 km, and the geometric albedo is 0.13±0.04.     

Transpressive duplex and flower structure: Dent Fault System, NW England

Revised mapping along the Dent Fault (northwest England) has improved the resolution of folds and faults formed during Variscan (late Carboniferous) sinistral transpression. A NNE-trending east-down monocline, comprising the Fell End Syncline and Taythes Anticline, was forced in Carboniferous cover above a reactivated precursor to the Dent Fault within the Lower Palaeozoic basement. The Taythes Anticline is periclinal due to interference with earlier Acadian folds. The steep limb of the monocline was eventually cut by the west-dipping Dent Fault. The hangingwall of the Dent Fault was dissected by sub-vertical or east dipping faults, together forming a positive flower structure in cross-section and a contractional duplex in plan view. The footwall to the Dent Fault preserves evidence of mostly dip-slip displacements, whereas strike-slip was preferentially partitioned into the hangingwall faults. This pattern of displacement partitioning may be typical of transpressive structures in general. The faults of the Taythes duplex formed in a restraining overlap zone between the Dent Fault and the Rawthey Fault to the west. The orientations of the duplex faults were a response to kinematic boundary conditions rather than to the regional stress field directly. Kinematic constraints provided by the Dent and neighbouring Variscan faults yield a NNW–SSE regional shortening direction in this part of the Variscan foreland.     

Modelling the movement of pollutants in the UK shelf seas

The EUROSPILL oil and chemical spill model has been extended to include the transport due to residual currents in the UK shelf seas. Wind-driven circulation patterns for the winter and summer have been derived, and the annual mean (long-term) flow pattern estimated. Current speeds during the winter are typically of the order of 0.05–0.10 m s⁻¹, the summer values show a similar spatial pattern but are considerably weaker. Trajectories over a period of 100 days are presented for a selection of release points arranged on a regular latitude/longitude grid. Estimates of patch size after 300 days are given for releases from sites of heavy shipping and offshore exploration. Use of the method for accident simulation is demonstrated by considering the likely spread of Lindane spilled in the English Channel during March 1989.